RESUMO
Cryogenic quantum applications have a demand for an ever-higher number of interconnects and bandwidth. Photonic links are foreseen to offer data transfer with high bandwidth, low heat load, and low noise to enable the next-generation scalable quantum computing systems. However, they require high-speed and energy-efficient modulators operating at cryogenic temperatures for electro-optic signal conversion. Here, plasmonic organic electro-optic modulators operating at 4 K are demonstrated with a >100 GHz bandwidth, drive voltages as low as 96 mV, and a significant reduction in plasmonic propagation losses by over 40% compared to room temperature. Up to 160 Gbit/s and 256 Gbit/s cryogenic electro-optic signal conversion are demonstrated by performing data experiments using a plasmonic Mach-Zehnder modulator at around 1528 nm and a plasmonic ring-resonator modulator at around 1285 nm, respectively. This work shows that plasmonic modulators are ideally suited for future high-speed, scalable, and energy-efficient photonic interconnects in cryogenic environments.
RESUMO
This study demonstrates enhancement of in-device electro-optic activity via a series of theory-inspired organic electro-optic (OEO) chromophores based on strong (diarylamino)phenyl electron donating moieties. These chromophores are tuned to minimize trade-offs between molecular hyperpolarizability and optical loss. Hyper-Rayleigh scattering (HRS) measurements demonstrate that these chromophores, herein described as BAH, show >2-fold improvement in ß versus standard chromophores such as JRD1, and approach that of the recent BTP and BAY chromophore families. Electric field poled bulk devices of neat and binary BAH chromophores exhibited significantly enhanced EO coefficients (r33) and poling efficiencies (r33/Ep) compared with state-of-the-art chromophores such as JRD1. The neat BAH13 devices with charge blocking layers produced very large poling efficiencies of 11.6 ± 0.7 nm2 V-2 and maximum r33 value of 1100 ± 100 pm V-1 at 1310 nm on hafnium dioxide (HfO2). These results were comparable to that of our recently reported BAY1 but with much lower loss (extinction coefficient, k), and greatly exceeding that of other previously reported OEO compounds. 3 : 1 BAH-FD : BAH13 blends showed a poling efficiency of 6.7 ± 0.3 nm2 V-2 and an even greater reduction in k. 1 : 1 BAH-BB : BAH13 showed a higher poling efficiency of 8.4 ± 0.3 nm2 V-2, which is approximately a 2.5-fold enhancement in poling efficiency vs. JRD1. Neat BAH13 was evaluated in plasmonic-organic hybrid (POH) Mach-Zehnder modulators with a phase shifter length of 10 µm and slot widths of 80 and 105 nm. In-device BAH13 achieved a maximum r33 of 208 pm V-1 at 1550 nm, which is â¼1.7 times higher than JRD1 under equivalent conditions.