RESUMO
Inspired by hook-and-loop fasteners, we designed a hydrogel network containing α-zirconium phosphate (ZrP) two-dimensional nanosheets with a high density of surface hydroxyl groups serving as nanopatches with numerous "hooks," while polymer chains with plentiful amine functional groups serve as "loops." Our multiscale molecular simulations confirm that both the high density of hydroxyl groups on nanosheets and the large number of amine functional groups on polymer chains are essential to achieve reversible interactions at the molecular scale, functioning as nano hook-and-loop fasteners to dissipate energy. As a result, the synthesized hydrogel possesses superior stretchability (>2100% strain), resilience to compression (>90% strain), and durability. Remarkably, the hydrogel can sustain >5000 cycles of compression with torsion in a solution mimicking synovial fluid, thus promising for potential biomedical applications such as artificial articular cartilage. This hook-and-loop model can be adopted and generalized to design a wide range of multifunctional materials with exceptional mechanical properties.
Assuntos
Hidrogéis , Polímeros , PressãoRESUMO
Superhydrophobic methylated silica with a core-shell structure was successfully fabricated by a sol-gel process. First, a pristine silica gel with an average particle size of ca. 110 nm was prepared, using tetraethylorthosilicate (TEOS) as a precursor, ethanol as a solvent, and NH4OH as a catalyst. Then, the superhydrophobic methylated silica sol was prepared by introducing methyltrimethoxysilane (MTMS), to graft the surface of the pristine silica gel with methyl groups. The structure and morphology of the methylated silica sol were characterized by Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FE-SEM), and transmission electron microscope (TEM). The characterization results showed that methyl groups were successfully grafted onto the surface of the pristine silica, and the diameter of the methylated silica was increased by 5-10 nm. Various superhydrophobic surfaces on glass, polyethylene terephthalate (PET) fabric, cotton, open-cell polyurethane (PU) foam, and polypropylene (PP) filter cloth were successfully constructed by coating the above substrates with the methylated silica sol and reached with a maximum static water contact angle and slide angle of 161° and 3°, respectively. In particular, the superhydrophobic PP filter cloth exhibited promising application in oil-water separation. The separation efficiency of different oil-water mixtures was higher than 96% and could be repeated at least 15 times.
RESUMO
Large-scale biomimetic organic/inorganic hybrid nanocoatings with a nacre-like microstructure were prepared via a facile coassembly process. Different from conventional polymer nanocomposites, these nanocoatings contain a high concentration of nanosheets, which can be well aligned along the substrate surface. Moreover, the nanosheets and polymer matrix can be chemically co-cross-linked. As a result, the nanocoatings exhibit exceptional mechanical properties (high stiffness and strength), barrier properties (to both oxygen and water vapor), and flame retardancy, but they are also highly transparent (maintaining more than 85% of their original transmittance to visible light). The nanocoatings can be applied to various substrates and regular or irregular surfaces (for example, films and foams). Because of their excellent performance and high versatility, these nanocoatings are expected to find widespread application.
RESUMO
Solid acids have received considerable attention as alternatives to traditional corrosive and hazardous homogeneous acids because of their advantages in practical applications, including their low corrosion of equipment and high catalytic activity and recyclability. In this work, a strong solid acid was prepared by anchoring thiol group terminated chains on layered α-zirconium phosphate (ZrP) single-layer nanosheets, followed by oxidation of thiol groups to form sulfonic acid groups. The obtained solid acids were thoroughly characterized and the results proved that sulfonic acid group terminated chains were successfully grafted onto the ZrP nanosheets with a high loading density. Such a strong solid acid based on inorganic nanosheets can be well-dispersed in polar solvents, leading to high accessibility to the acid functional groups. Meanwhile, it can be easily separated from the dispersion system by centrifugation or filtration. The strong solid acid can serve as an effective heterogeneous catalyst for various reactions, including the Bayer-Villiger oxidation of cyclohexanone to ε-caprolactone in the absence of organic solvents.