Electrochemical dual oxidative C(sp3)-H amination: switchable synthesis of imidazo-fused quinazolinones.

An efficient electrochemical dual C(sp3)-H amination was developed under metal-free and chemical oxidant-free conditions. A series of imidazo[1,5-a]quinazolin-5(4H)-ones and 5-oxo-4,5-dihydroimidazo[1,5-a]quinazoline-3-carbonitriles can be obtained in high yields and the product distribution can be modulated by virtue of this method. The reaction mechanism was investigated and the corresponding intermediates were studied. The reaction features a broad substrate scope, regulation of the product distribution, mild conditions and scalable preparation.

Influence of Corrosion on the Bond-Slip Behaviour between Corroded Bars and Concrete.

Pull-out tests were conducted to investigate the effects of corrosion of both the longitudinal bars and stirrups on the bond slip behaviour of reinforced concrete specimens. The main experimental variables include concrete strength (26.7 MPa, 37.7 MPa and 45.2 MPa) and expected corrosion loss (0%, 4%, 8% and 12%), with a total of 63 specimens fabricated. The results show that the relative bonding strength of specimens under different concrete strengths gradually decreases with increasing corrosion loss, but the higher the concrete strength is, the faster its degradation rate. The influence of stirrup corrosion on the peak slip can be ignored, but it will further aggravate the degradation of the bonding strength of the specimens. This reduction in bonding strength is linearly related to the stirrup corrosion loss. Based on the experimental results of this work and the achievements of other scholars, a modified relative bonding strength degradation model and a bond-slipbond-slip constitutive model of corroded reinforced concrete are presented by accounting for the influence coefficient of concrete strength. The results show that the constitutive model is in good agreement with the relevant experimental results.

Switchable Direct Oxygenative Arylation of C(sp3)-H Bonds via Electrophotocatalysis.

A metal-free electrophotochemical C(sp3)-H arylation was developed under mild conditions. This method enables a switchable synthesis of diaryl alcohols and diaryl alkanes from inactive benzylic carbons. More importantly, a cheap and safe mediator N-chlorosuccinimide (NCS) was developed, which was employed for the hydrogen atom transfer (HAT) process of the benzylic C-H bond. In addition, this active radical was captured and identified by electron paramagnetic resonance (EPR).

The influence of the curing process on the shear thickening performance of RMG and property optimization.

A smart composite with both rate-sensitive and magnetic-sensitive properties was prepared by dispersing carbonyl iron powder (CIP) into a silicon-boron copolymer matrix. In addition to following the common preparation procedure, a curing process used in the rubber industry was considered. Several groups of samples were prepared with and without including this curing process. For the samples that underwent the curing process, the absolute shear thickening effect was reduced by less than half compared to the samples that did not undergo the curing process, however, the relative shear thickening effect was increased by up to 6717.50%. In total, 16 groups of samples were tested under different curing conditions, such as different curing times and curing temperatures, to investigate the performance improvement. The results showed that to obtain a better relative shear thickening effect, a curing time of at least 20 min was needed. When the curing temperature was set to 120 °C, the absolute shear thickening effect was maximized. The influences of pyroboric acid and CIPs on the properties of the materials were also studied. Interestingly, the relative magnetorheological effect did not always increase with increasing CIP content. An increase in the amount of pyroboric acid increased the absolute shear thickening effect and decreased the relative shear thickening effect.