Hydrothermal carbonization of Typha australis: Influence of stirring rate.

According to existing literature, there are no conclusive results on the impact of stirring on hydrothermal carbonization (HTC); some studies report a significant impact on the product's properties, while others indicate no influence. This study investigates the influence of stirring rate on several responses and properties of HTC products, including solid mass yield, solid carbon fraction, surface area, surface functional groups, morphology, and the fate of inorganic elements during HTC. Waste biomass was introduced as a feedstock to a 2 L HTC reactor, where the effects of temperature (180-250 °C), residence time (4-12 h), biomass to water (B/W) ratio (1-10%), and stirring rate (0-130 rpm) were investigated. The findings of this study conclusively indicated that the stirring rate does not influence any of the studied responses or properties of hydrochar under the selected experimental conditions used in this study. Nevertheless, the results indicated that a low-stirring rate (5 RPM) is enough to slightly enhanced the heating-up phase of the HTC reactor. For future research, it is recommended to examine the impact of stirring rate on the HTC of other types of biomass using the methodology developed in this study.

Evaluating river driftwood as a feedstock for biochar production.

Driftwood in river catchments might pose a hazard for the safety of infrastructures, such as dams and river dwellers, and thus is often removed. Génissiat dam in France presents a case study where annually approximately 1300 tons of driftwood are removed to prevent driftwood sinking and to protect the dam infrastructure. Collected river driftwood is rarely studied for utilization purposes and is commonly combusted or landfilled. However, driftwood can be valorized for biochar production through pyrolysis or hydrothermal carbonization (HTC). This study follows a novel approach in characterizing river driftwood by identifying the different common genera present at Génissiat dam on the upper Rhône, France. Moreover, the research provides for the first time a comprehensive analysis of river driftwood different physico-chemical properties, such as moisture content, major elemental composition (CHNSO), HHV, and macromolecular composition (cellulose, hemicellulose, lignin, and extractives). The study shows that the transportation of driftwood through rivers can enhance its properties by reducing the bark content resulting in lower ash content. Results indicate that driftwood can be mixed and further processed as a feedstock regardless of their genera and type for biochar production by pyrolysis or hydrothermal carbonization.

Beneficial role of biochar addition on the anaerobic digestion of food waste: A systematic and critical review of the operational parameters and mechanisms.

The generation of huge amounts of food waste due to the increasing population is a serious global issue. The inadequate management of food waste and lack of proper handling approaches have created adverse negative impacts on the environment and the society. The use of traditional disposal (i.e. landfilling) and treatment (i.e. incineration and composting) methods are not considered to be efficient for managing food waste. Thus, anaerobic digestion (AD) has proven to be promising and cost-effective, as an alternative technology, for digesting and converting food waste into renewable energy and useful chemicals. However, mono-digestion of food waste suffers from process inhibition and instability which limit its efficiency. Adding biochar that has high buffering capacity and ensures optimum nutrient balance was shown to enhance biogas/methane production yields. This review reports on the physicochemical characteristics of food waste, the existing problems of food waste treatment in AD as well as the role of biochar amendments on the optimization of critical process parameters and its action mechanisms in AD, which could be a promising means of improving the AD performance. Also, this review provides insights regarding the selection of the desired/appropriate biochar characteristics, i.e. depending on the source of the feedstock and the pyrolysis temperature, and its role in enhancing biogas production and preventing the problem of process instability in the AD system. Finally, this review paper highlights the economic and environmental challenges as well as the future perspectives concerning the application of biochar amendments in AD.

Assessing the suitability of recovering shrub biowaste involved in wildland fires in the South of Europe through torrefaction mobile units.

Several types of shrubs and oak inducing high wildland fire risk in the South of Europe were evaluated for their potential valorization through torrefaction. Biomasses were firstly characterized in terms of macromolecular and elemental composition. Lab-scale TGA-GC/MS torrefaction experiments allowed the in-depth study of the solid mass transformation and the production profile of 23 volatile species (200 to 300 °C at 3 °C·min-1 and 300 °C for 30 min). The proportion of the torrefied products (solid, CO, CO2, water and volatile species) was evaluated through mass balance in a lab-scale furnace under typical torrefaction conditions (300 °C, 40 min). The results show a similar characterization and behavior in torrefaction for oak and shrublands, and slightly different characteristics for fern. However, fern may grow separately from shrublands and is considered to present a low fire risk. This suggests that the in-situ direct valorization of these biomasses through torrefaction mobile units seems promising. However, other properties, such as density, flowability and grindability need to be studied to confirm the feasibility of the process. Regarding torrefaction products, a higher carbon content and an interesting increase in heating value were measured for the torrefied solid, which makes it suitable for energetic valorization, among other uses. The composition of permanent gases was evaluated and found in agreement with previous studies. Finally, the volatile species released were studied in function of the torrefaction temperature, in view of their possible valorization as green chemicals.

Performance of a compost and biochar packed biofilter for gas-phase hydrogen sulfide removal.

The main aim of this study was to evaluate the performance of an aerobic biofilter packed with compost for the removal of gas-phase hydrogen sulfide (H2S). After 52 d of operation, the biofilter was re-packed by replacing a certain portion (25%, v/v) of the existing compost with biochar and its performance was tested. The steady and transient performance of the biofilter was evaluated by varying the H2S concentrations from 0.1 to 2.9 g m-3 at an empty bed residence time (EBRT) of 119 and 80 s, respectively. The maximum elimination capacity (ECmax) of the compost and compost + biochar biofilter were ∼19 and 33 g m-3 h-1, respectively, with >99% removal efficiency at an EBRT of 119 s. The compost biofilter showed a quick response to shock loads and the critical load to the biofilter during the shock loading step was ∼81 g m-3 h-1.

Comparison of steam gasification reactivity of algal and lignocellulosic biomass: influence of inorganic elements.

This study aims at comparing the steam gasification behaviour of two species of algal biomass (Chlamydomonas reinhardtii and Arthrospira platensis) and three species of lignocellulosic biomass (miscanthus, beech and wheat straw). Isothermal experiments were carried out in a thermobalance under chemical regime. Samples had very different contents in inorganic elements, which resulted in different reactivities, with about a factor of 5 between samples. For biomasses with ratio between potassium content and phosphorus and silicon content K/(Si+P) higher than one, the reaction rate was constant during most of the reaction and then slightly increased at high conversion. On the contrary, for biomasses with ratio K/(Si+P) lower than one, the reaction rate decreased along conversion. A simple kinetic model was proposed to predict these behaviours.

Kinetic modelling of steam gasification of various woody biomass chars: influence of inorganic elements.

A study was performed on the influence of wood variability on char steam gasification kinetics. Isothermal experiments were carried out in a thermobalance in chemical regime on various wood chars produced under the same conditions. The samples exhibited large differences of average reaction rate. These differences were linked neither with the biomass species nor age and may be related to the biomass inorganic elements. A modelling approach was developed to give a quantitative insight to these observations. The grain model was used on one biomass of reference for temperatures between 750 and 900 °C and steam partial pressures between 0 and 0.27 bar. The model was applied to the other samples through the addition of an integral parameter specific to each sample. A satisfactory correlation was found between this parameter and the ratio potassium/silicium. This result highlighted the catalytic effect of potassium and inhibitor effect of silicium on the reaction.

[Thermoconversion of carbonaceous materials to produce synthetic fuels: the biomass case]. / ThermoConversion de matériaux carbonés pour produire des carburants de synthèse: cas de la biomasse.

In the present energy context, there is a growing interest for the fuel production from biomass. While the first generation of biofuels has shown its limits, a second generation appears that is based on the valorisation of the unused resources of lignocellulosic biomass. This could significantly increase the biofuels potential in France. Up to 40 % of the total needs of transport fuel could be covered. Among the processes under development, the Biomass to Liquid (BtL) process seems as an interesting route, able to be shortly implemented at an industrial scale. This process consists in producing liquid fuel (such as Diesel Fischer-Trospch) through a synthetic gas obtained by biomass gasification However R&D work is still needed to solve the remaining key issues of the process. These studies are performed in several laboratories in Europe, especially in Germany and in the Nordic countries, and also more recently in France, notably in the Commissariat à l'Energie Atomique.