CuNi sulphidation maximizes MOR activity by expanding the accessibility of active sites!

Sulphidation of a CuNi alloy of Cu : Ni ratio 81 : 19 led to an exponential activity enhancement in the alkaline methanol oxidation reaction (MOR) by four fold due to an order of magnitude increase in the number of active Cu and Ni sites and improved charge transfer properties.

A tri-functional self-supported electrocatalyst featuring mostly NiTeO3 perovskite for H2 production via methanol-water co-electrolysis.

A self-supported NiTeO3 perovskite is made by deploying an extended hydrothermal tellurization strategy with a restricted Te content, which was found to be exceptionally active towards the oxidation of water and methanol and the reduction of water in 1.0 M KOH where it delivered -10 mA cm-2 at just -1.54 V for a full cell featuring MOR‖HER.

Equivalence of nonequilibrium ensembles: Two-dimensional turbulence with a dual cascade.

We examine the conjecture of equivalence of nonequilibrium ensembles for turbulent flows in two dimensions in a dual-cascade setup. We construct a formally time-reversible Navier-Stokes equation in two dimensions by imposing global constraints of energy and enstrophy conservation. A comparative study of the statistical properties of its solutions with those obtained from the standard Navier-Stokes equations clearly shows that a formally time-reversible system is able to reproduce the features of a two-dimensional turbulent flow. Statistical quantities based on one- and two-point measurements show an excellent agreement between the two systems for the inverse- and direct-cascade regions. Moreover, we find that the conjecture holds very well for two-dimensional turbulent flows with both conserved energy and enstrophy at finite Reynolds number.