Hydrogeochemical and isotopic evolution of groundwater in shallow and deep aquifers of the Kabul Plain, Afghanistan.

Groundwater from shallow and deep aquifers are widely used for drinking, agricultural and industrial use in Kabul, the capital of Afghanistan. However, unplanned urbanization and rapid population growth has led to the installation of numerous unlicensed wells to meet the public demand. This has caused to extraction of huge amounts of groundwater from the subsurface and further deterioration of groundwater quality. Therefore, understanding the hydrogeochemical characteristics of groundwater in shallow aquifers and deep aquifers is imperative for sustainable management of the groundwater resource in Kabul Plain. Thus, in this study, we used a multi-parameter approach, involving hydrochemical and environmental isotopes to understand the geochemical evolution of entire groundwater system of the Kabul Plain including river and dam water. The results of this study show that shallow and deep aquifers are dominantly of Mg-(Ca)-HCO3 and Na-Cl water type, respectively. We observed that (1) water-rock interaction is the major contributing factor to the chemical compositions of groundwater in the Kabul Plain; (2) groundwater in deep aquifer is mainly influenced by silicate weathering, and dissolution of evaporitic and carbonate minerals and reverse cation exchange; (3) dissolution of carbonates and silicate weathering plays a pivotal role in the groundwater chemistry of shallow aquifer; (4) the stable isotopes of groundwater display that the shallow aquifer is principally recharged by river water and local precipitation; (5) the tritium analysis exhibited that groundwater of shallow aquifer was primarily recharged recently, whereas groundwater of deep aquifer is the mixture of pre 1953 with post 1953 groundwater. This study revealed that there are hydraulic interactions between the two aquifers and the deep aquifer is recharged through shallow aquifer. The findings of this study would be useful for Afghanistan's water authorities to develop an effective strategy for sustainable water resources management in the Kabul Basin.

Identification and apportionment of groundwater nitrate sources in Chakari Plain (Afghanistan).

The Chakari alluvial aquifer is the primary source of water for human, animal, and irrigation applications. In this study, the geochemistry of major ions and stable isotope ratios (δ2H-H2O, δ18O-H2O, δ15N-NO3̄, and δ18O-NO3̄) of groundwater and river water samples from the Chakari Plain were analyzed to better understand characteristics of nitrate. Herein, we employed nitrate isotopic ratios and BSIMM modeling to quantify the proportional contributions of major sources of nitrate pollution in the Chakari Plain. The cross-plot diagram of δ15N-NO3̄ against δ18O-NO3̄ suggests that manure and sewage are the main source of nitrate in the plain. Nitrification is the primary biogeochemical process, whereas denitrification did not have a significant influence on biogeochemical nitrogen dynamics in the plain. The results of this study revealed that the natural attenuation of nitrate in groundwater of Chakari aquifer is negligible. The BSIMM results indicate that nitrate originated mainly from sewage and manure (S&M, 75‰), followed by soil nitrogen (SN, 13‰), and chemical fertilizers (CF, 9.5‰). Large uncertainties were shown in the UI90 values for S&M (0.6) and SN (0.47), whereas moderate uncertainty was exhibited in the UI90 value for CF (0.29). The findings provide useful insights for decision makers to verify groundwater pollution and develop a sustainable groundwater management strategy.

Assessment of groundwater vulnerability in an urban area: a comparative study based on DRASTIC, EBF, and LR models.

The groundwater vulnerability assessment is known as a useful tool for predicting and prevention of groundwater pollution. This study targets the DRASTIC, evidential belief function (EBF), and logistic regression (LR) models to assess vulnerability in Kabul aquifers, Afghanistan Country. The growth of urban sprawl, groundwater overexploitation, and lack of suitable municipal sewage systems as anthropogenic sources have been the main potential to increase groundwater contaminants such as nitrate in the study area. The vulnerability map has been developed based on various effective factors including altitude, slope (percentage rise), aspect, curvature, land-use type, drainage density, distance from river, annual mean precipitation, net recharge, geology/lithology units, the impact of the vadose zone, aquifer media, depth to water (unsaturated zone), saturated zone, drawdown, and hydraulic conductivity. To identify groundwater pollution, the spatial variation of nitrate concentration data in 2018 was considered indication of groundwater pollution. Based on descriptive statistics, the value of 2.65 mg/l (the median of the pixel values of nitrate map) was selected as a threshold to differentiate the occurrence and non-occurrence of pollution. The groundwater quality data were selected and randomly divided into two datasets for training and validation, including 70% and 30%, respectively. The success-rate and prediction-rate curves were computed based on the receiver operating characteristic (ROC) curve and the area under the curve (AUC) to estimate the efficiency of models. The ROC-AUC of success rates for EBF, LR, and DRASTIC models were estimated to be 67%, 66%, and 52%, respectively. Moreover, the ROC-AUC of the prediction rates of the EBF, LR, and DRASTIC models were obtained 61%, 63%, and 55%, respectively. Based on correlation between mean nitrate concentration and the mean vulnerability indexes in each model, the EBF model is the most compatible with the current developed vulnerability zones as the role of mankind in changing the environment in real conditions in comparison to LR and DRASTIC models.