Evolution of CrCx Ceramic Induced by Laser Direct Energy Deposition Multilayered Gradient Ni204-dr60 Coating.

The manufacturing process for many large components of machines leads to a difference in their properties and performances based on changes in location. Functionally graded materials can meet these requirements and address the issue of generation and expansion of interface cracks. Ni204-dr60 gradient coatings were successfully fabricated using laser direct energy deposition (LDED). Microstructure mechanism evolution and microhardness of the gradient coating were comprehensively investigated. The change in the precipitated phase at the grain boundary and the intergranular zones resulted in a change in microstructural characteristics and also affected the microhardness distribution. The reinforced phase of the Ni204 → dr60 gradient zone from Ni204 to dr60 gradually precipitated and was rich in Mo and Nb phase, lath-shaped CrCx phase, network-shaped CrCx phase, block shape (Ni, Si) (C, B) phase, block CrCx phase, and block Cr (B, C) phase. The gradient coating thus acts as a potential candidate to effectively solve the problem of crack generation at the interface of dr60 and the substrate.

Additive manufacturing landscape and materials perspective in 4D printing.

4D printing is inspired by embedded product designs to produce stimuli-responsive consumables fabricated by available commercial 3D printers. Although significant progress on smart material performance has been made and different studies have focused on new strategies and process improvements in typical additive manufacturing. Herein, the proposed review article discusses material arrangements for 4D printing, highlighting the structural evolvement mechanism, the behavior of deformation, and their prospective implementation with respect. Starting from a generalized idea, and fundamental workflow, together with a graphical manifestation of the 4D printing concept, and 4D printing for shape-memory materials (SMMs), self-fitting wearables based on shape memory alloys (SMAs) are reviewed exclusively. Furthermore, the capabilities of single and multiple materials mechanisms for shape-shifting behavior are summarized. Finally, we explored the future application potential under succeeding context: SMA-based knitted garments, transforming food, and relevant sectors wise development and proceedings with the advancement in smart materials. We determined our review by aiming our future directions such as the "dream it and make it feasible" technology.