Current knowledge of seepage from oil sands tailings ponds and its environmental influence in northeastern Alberta.

Seepage of oil sand process-affected waters (OSPW) from tailings ponds into surface waters is a common concern in the minable oil sands region of northeast Alberta. Research on seepage has been extensive, but few comprehensive treatments evaluating all aspects relevant to the phenomenon are available. In this work, the current information relevant for understanding the state of seepage from tailings ponds was reviewed. The information suggests the infiltration of OSPW into groundwater occurs near some ponds. OSPW may also be present in sediments beneath the Athabasca River adjacent to one pond, but there are no clear observations of OSPW in the river water. Similarly, most water samples from tributaries also show no evidence of OSPW, but these observations are limited by the lack of systematic, systemic, and repeated surveys, missing baseline data, standard analytical approaches, and reference materials. Waters naturally influenced by bitumen, discharge of saline groundwaters, and dilution also potentially affect the consolidation of information and certainty of any conclusions. Despite these challenges, some data suggest OSPW may be present in two tributaries of the Athabasca River adjacent to tailings ponds: McLean Creek and Lower Beaver River. Irrespective of the possible source(s), constituents of OSPW often affect organisms exposed in laboratories, but research in all but one study suggests the concentrations of organics in the surface water bodies assessed are below the standard toxicological effect thresholds for these compounds. In contrast, many samples of groundwater, irrespective of source, likely affect biota. Biomonitoring of surface waters suggests generic responses to stressors, but the influence of natural phenomena and occasionally nutrient enrichment are often suggested by data. In summary, valuable research has been done on seepage. The data suggest infiltration into groundwater is common, seepage into surface waters is not, and anthropogenic biological impacts are not likely.

Management of severe traumatic brain injury and acute respiratory distress syndrome using pumped extracorporeal carbon dioxide removal device.

The effects of a high carbon dioxide on cerebral perfusion and intracranial pressure are well known. We report the case of a man who presented after with a severe traumatic brain injury including intracranial and extradural haemorrhage. Neuroprotective ventilation was impossible without supramaximal tidal volumes due to a combination of chest trauma and severe bronchospasm. A pump driven Novalung iLA active® system was inserted to achieve both ARDSnet ventilation and a lowering of intracranial pressure. To our knowledge, this is the first time this system has been used to this effect. The patient went on to make a good recovery.

Characterization of Naphthenic Acids and Other Dissolved Organics in Natural Water from the Athabasca Oil Sands Region, Canada.

With growth of the Canadian oil sands industry, concerns have been raised about possible seepage of toxic oil sands process-affected water (OSPW) into the Athabasca River (AR). A sampling campaign in fall 2015 was undertaken to monitor for anthropogenic seepage while also considering natural sources. Naphthenic acids (NAs) and thousands of bitumen-derived organics were characterized in surface water, groundwater, and OSPW using a highly sensitive online solid phase extraction-HPLC-Orbitrap method. Elevated NA concentrations and bitumen-derived organics were detected in McLean Creek (30.1 µg/L) and Beaver Creek (190 µg/L), two tributaries that are physically impacted by tailings structures. This was suggestive of OSPW seepage, but conclusive differentiation of anthropogenic and natural sources remained difficult. High NA concentrations and bitumen-derived organics were also observed in natural water located far north of the industry, including exceedingly high concentrations in AR groundwater (A5w-GW, 2000 µg/L) and elevated concentration in a tributary river (Pierre River, 34.7 µg/L). Despite these evidence for both natural and anthropogenic seepage, no evidence of any bitumen-derived organics was detected at any location in AR mainstem surface water. The chemical significance of any bitumen-derived seepage to the AR was therefore minimal, and focused monitoring in tributaries will be valuable in the future.

Quantitative and qualitative analysis of naphthenic acids in natural waters surrounding the Canadian oil sands industry.

The Canadian oil sands industry stores toxic oil sands process-affected water (OSPW) in large tailings ponds adjacent to the Athabasca River or its tributaries, raising concerns over potential seepage. Naphthenic acids (NAs; C(n)H(2n-Z)O(2)) are toxic components of OSPW, but are also natural components of bitumen and regional groundwaters, and may enter surface waters through anthropogenic or natural sources. This study used a selective high-resolution mass spectrometry method to examine total NA concentrations and NA profiles in OSPW (n = 2), Athabasca River pore water (n = 6, representing groundwater contributions) and surface waters (n = 58) from the Lower Athabasca Region. NA concentrations in surface water (< 2-80.8 µg/L) were 100-fold lower than previously estimated. Principal components analysis (PCA) distinguished sample types based on NA profile, and correlations to water quality variables identified two sources of NAs: natural fatty acids, and bitumen-derived NAs. Analysis of NA data with water quality variables highlighted two tributaries to the Athabasca River-Beaver River and McLean Creek-as possibly receiving OSPW seepage. This study is the first comprehensive analysis of NA profiles in surface waters of the region, and demonstrates the need for highly selective analytical methods for source identification and in monitoring for potential effects of development on ambient water quality.