Emergence and Evolution of Crystallization in TiO2 Thin Films: A Structural and Morphological Study.

Among all transition metal oxides, titanium dioxide (TiO2) is one of the most intensively investigated materials due to its large range of applications, both in the amorphous and crystalline forms. We have produced amorphous TiO2 thin films by means of room temperature ion-plasma assisted e-beam deposition, and we have heat-treated the samples to study the onset of crystallization. Herein, we have detailed the earliest stage and the evolution of crystallization, as a function of both the annealing temperature, in the range 250-1000 °C, and the TiO2 thickness, varying between 5 and 200 nm. We have explored the structural and morphological properties of the as grown and heat-treated samples with Atomic Force Microscopy, Scanning Electron Microscopy, X-ray Diffractometry, and Raman spectroscopy. We have observed an increasing crystallization onset temperature as the film thickness is reduced, as well as remarkable differences in the crystallization evolution, depending on the film thickness. Moreover, we have shown a strong cross-talking among the complementary techniques used displaying that also surface imaging can provide distinctive information on material crystallization. Finally, we have also explored the phonon lifetime as a function of the TiO2 thickness and annealing temperature, both ultimately affecting the degree of crystallinity.

Left/right asymmetry of the dipole field due to reflection from a periodic multilayer of a topological insulator and a columnar thin film.

The problem of a vertical electric dipole radiating above a periodic multilayer whose unit cell comprises a layer of a topological insulator (TI) and a columnar thin film (CTF) was solved in order to investigate the left/right asymmetry of the total electric field in the far zone in the half-space containing the dipole. Occurring in a wide range of the polar observation angle, the left/right asymmetry of Eϕ is due to both the CTFs and the TI layers. Occurring in a narrow range of the polar observation angle, the left/right asymmetry of Eθ is entirely due to the TI layers. For presently available values of the magnitude of the surface admittance γTI of TIs, significant left/right asymmetry occurs if the number of unit cells in the periodic TI/CTF multilayer is high enough.

Enhanced left/right asymmetry in reflection and transmission due to a periodic multilayer of a topological insulator and an anisotropic dielectric material.

Very weak left/right asymmetry in reflection and transmission is offered by a layer of a topological insulator on top of a layer of an anisotropic dielectric material, but it can be enhanced very significantly by using a periodic multilayer of both types of materials. This is an attractive prospect for realizing one-way terahertz devices, because both types of materials can be grown using standard physical-vapor-deposition techniques.

Simulation and analysis of prismatic bioinspired compound lenses for solar cells: II. Multifrequency analysis.

Multifrequency numerical simulations of the light-coupling efficiency of a prismatic bioinspired compound lens (BCL) of silicon atop a thick silicon substrate were carried out within the framework of geometrical optics. Comparison was made with untextured and groove-textured silicon substrates as well as with untextured silicon substrates with a double-layer anti-reflection (DLAR) coating. Taking into account the broadband nature and the sea-level spectral irradiance of the insolation flux, and averaging over all admissible directions and both linear polarization states of the incident light, we found that the light-coupling efficiency can be almost doubled with respect to the untextured silicon substrate and enhanced by about a third with respect to a DLAR-coated untextured silicon substrate, by adopting a DLAR-coated silicon BCL.

Simulation and analysis of prismatic bioinspired compound lenses for solar cells.

Inspired by the apposition compound eyes of many dipterans, we formulated a fractal scheme to design prismatic lenses to improve the performance of silicon solar cells. We simulated the absorption of light, both directly illuminating and diffuse, using the geometrical-optics approximation. We found that properly designed bioinspired compound lenses (BCLs) can significantly improve the light-harvesting capabilities of silicon solar cells. The degree of improvement will depend on the material chosen to make the BCLs as well as the operating conditions.