RESUMO
In recent years, it was found that current passing through chiral molecules exhibits spin preference, an effect known as Chiral Induced Spin Selectivity (CISS). The effect also enables the reduction of scattering and therefore enhances delocalization. As a result, the delocalization of an exciton generated in the dots is not symmetric and relates to the electronic and hole excited spins. In this work utilizing fast spectroscopy on hybrid multilayered QDs with a chiral polypeptide linker system, we probed the interdot chiral coupling on a short time scale. Surprisingly, we found strong coherent coupling and delocalization despite having long 4-nm chiral linkers. We ascribe the results to asymmetric delocalization that is controlled by the electron spin. The effect is not measured when using shorter nonchiral linkers. As the system mimics light-harvesting antennas, the results may shed light on a mechanism of fast and efficient energy transfer in these systems.
RESUMO
The control of complex devices on the nanoscale is challenging. The development of nanoparticles, such as quantum dots, that serve as "artificial atoms" enables the manipulation of energy levels at the nanoscale. Using quantum dots and wet chemistry, multilayer structures with unique coupling properties can be realized. The coupling of such quantum dots is essential for several applications, such as parallel computing. Earlier work showed enhancement of the delocalization using covalent bonds and short linkers. Here, we demonstrate a way to achieve better coupling using helical chiral molecules that exhibit long spin-wave function delocalization. The delocalization is controlled by manipulation of the spin state using polarized light.