1.
Carbohydr Res
; 331(2): 209-12, 2001 Mar 22.
Artigo
em Inglês
| MEDLINE
| ID: mdl-11322735
RESUMO
This paper describes a straightforward strategy for the synthesis of new nitrogen chelates by employing the chirality of readily available sugars. Thus, diimino and diamino ligands can be attained easily by using the methyl-4,6-O-benzylidene-2,3-diazo-2,3-dideoxy-alpha-D-mannopyranoside skeleton. The coordinating ability of one ligand has also been assessed by preparing a square-planar palladium complex [PdCl2(N,N-chelate)].