Assessing the efficiency of a coastal Managed Aquifer Recharge (MAR) system in Cyprus.

Managed Aquifer Recharge (MAR) is becoming an attractive water management option, with more than 223 sites operating in European countries. The quality of the produced water, available for drinking or irrigation processes is strongly depended on the aquifer's hydrogeochemical characteristics and on the MAR system design and operation. The objective of this project is the assessment of the operation efficiency of a MAR system in Cyprus. The coupling of alternative methodologies is used such as water quality monitoring, micro-scale sediment sorption experiments, simulation of groundwater flow and phosphate and copper transport in the subsurface using the FEFLOW model and evaluation of the observed change in the chemical composition of water due to mixing using the geochemical model PHREEQC. The above methodology is tested in the Ezousa MAR project in Cyprus, where treated effluent from the Paphos Waste Water Treatment Plant, is recharged into the aquifer through five sets of artificial ponds along the riverbed. Additionally, groundwater is pumped for irrigation purposes from wells located nearby. A slight attenuation of nutrients is observed, whereas copper in groundwater is overcoming the EPA standards. The FEFLOW simulations reveal no effective mixing in some intermediate infiltration ponds, which is validated by the inverse modeling simulation of the PHREEQC model. Based on the results, better control of the infiltration capacity of some of the ponds and increased travel times are some suggestions that could improve the efficiency of the system.

Seasonal and spatial variation of arsenic in groundwater in a rhyolithic volcanic area of Lesvos Island, Greece.

A survey conducted in water wells located in the rhyolithic volcanic area of Mandamados, Lesvos Island, Greece, indicated that significant seasonal variation of arsenic concentration in groundwater exists mainly in wells near the coastal zone. However, there were differences among those coastal wells with regard to the processes and factors responsible for the observed seasonal variability of the element, although they are all located in a small homogeneous area. These processes and factors include (a) a higher rate of silicate weathering and ion exchange during the dry period followed by the dilution by the recharge water during the wet period, (b) enhanced desorption promoted by higher pH in summer and subsequent dilution of As by rainwater infiltration during the wet period, and (c) reductive dissolution of Mn during the wet period and by desorption under high pH values during the dry period. On the other hand, in wells located in higher-relief regions, the concentration of As in groundwater followed a fairly constant pattern throughout the year, which is probably related to the faster flow of groundwater in this part of the area due to a higher hydraulic gradient. In general, seasonal variation of As in groundwater in the study area was found to be related to geology, recharge rate, topography-distance from coast, and well depth.

Carbon isotope fractionation during diffusion and biodegradation of petroleum hydrocarbons in the unsaturated zone: field experiment at Vaerløse Airbase, Denmark, and modeling.

A field experiment was conducted in Denmark in order to evaluate the fate of 13 volatile organic compounds (VOCs) that were buried as an artificial fuel source in the unsaturated zone. Compound-specific isotope analysis showed distinct phases in the 13C/12C ratio evolution in VOC vapors within 3 m from the source over 114 days. At day 3 and to a lesser extent at day 6, the compounds were depleted in 13C by up to -5.7% per hundred with increasing distance from the source compared to the initial source values. This trend can be explained by faster outward diffusion of the molecules with 12C only compared to molecules with a 13C. Then, the isotope profile leveled out, and several compounds started to become enriched in 13C by up to 9.5% per hundred with increasing distance from the source, due to preferential removal of the molecules with 12C only, through biodegradation. Finally, as the amount of a compound diminished in the source, a 13C enrichment was also observed close to the source. The magnitude of isotope fractionation tended to be larger the smaller the mass of the molecule was. This study demonstrates that, in the unsaturated zone, carbon isotope ratios of hydrocarbons are affected by gas-phase diffusion in addition to biodegradation, which was confirmed using a numerical model. Gas-phase diffusion led to shifts in delta(13)C >1% per hundred during the initial days after the spill, and again during the final stages of source volatilization after >75% of a compound had been removed. In between, diffusion has less of an effect, and thus isotope data can be used as an indicator for hydrocarbon biodegradation.