Catalyst-Free Extraction of U(VI) in Solution by Tribocatalysis.

Extraction of U(VI) in water is of great significance in energy and environmental fields. However, the traditional methods usually fail due to the indispensable extra addition of catalyst, adsorbent, precipitant, or sacrificial agents, which may lead to enhanced extraction costs and secondary pollution. Here, a new efficient uranium extraction strategy is proposed based on triboelectricity without adding a catalyst or other additives. It is found only under the friction between the microbubbles (generated under ultrasonication) and the water flow, that reactive oxygen species (ROS) can largely be generated, which thus contributes to the solidification of U(VI) from water. In addition, the magnetic field can affect the phase of the product. Under mechanical stirring, the product contains (UO2)O2·2H2O, while which contains UO2(OH)2 and (UO2)O2·4H2O under the magnetic stirring. Quenching experiments are also carried out to explore the influence of environmental factors. Most importantly, it shows great potential in the extraction of U(VI) from seawater. This work proposes a catalyst-free and light-free strategy toward the solidification of U(VI) from water, which avoids the secondary pollution of the catalyst to the environment and is low-cost, and has great potential in the real application.

Boosted charge transfer in a naturally formed Ca(Al2Si2O8)/Fe2O3 heterojunction for piezocatalytical formation of H2O2 and solidification of U(VI).

Energy and environmental issues make the generation of H2O2 and the separation of U(VI) from water very important topics. In this work, we disclosed a low-cost, high-efficiency method for separating U(VI) from water based on the naturally formed catalyst (red volcanic stone powders, RVSP) of Ca(Al2Si2O8)/Fe2O3 heterojunction through a piezocatalytic pathway induced by ultrasonication. The charges were found to be elevatedly separated due to the formation of the heterojunction. It is found that under ultrasonication, charges were effectively separated and then reacted with water to form H2O2 with a high yield of 196.7 µmol·g-1 in 4 h, which further solidifies U(VI) to form a solid of UO2O2. The removal rate of U(VI) in water reached 96 % (50 ppm) within 150 min. Furthermore, the results calculated by VASP show that the cyclic variation of the conduction bands under a cyclic force field facilitates the charge separation, and thus may promote piezocatalysis. Most importantly, the application study in real seawater indicates that U(VI) piezocatalysis based on natural minerals has great potential. This work presents a comprehensive investigation of U(VI) piezocatalysis by Ca(Al2Si2O8)/Fe2O3 and provides a new idea for piezocatalytic extraction of uranium.

Facet-dependent U(VI) removal of hematite with confined ferrous ions.

The presence of ferrous minerals has been demonstrated to have a significant impact on the destiny, migration, and availability of uranyl (U(VI)) in natural surroundings. The iron oxide/Fe(II) system is a multifaceted iron reduction system anchored to surfaces, encompassing various forms of iron and ferrous ions. Several studies have investigated the effectiveness of adsorbed ferrous iron on iron-based minerals to facilitate the reduction of heavy metal ions and radioactive nuclides. A range of techniques for characterization, including X-ray photoelectron spectroscopy (XPS) and Mössbauer spectroscopy, were employed to explore the process of U(VI) adsorption and deposition, focusing on the limited region containing ferrous iron on the exposed crystalline surface of hematite. In this specific investigation, two kinds of hematite nanocrystals primarily exposing {001} and {012} crystal facets, referred to as HNPs and HNCs, were synthesized. Their ability to remove U(VI) was examined. Ferrous ions (Fe(II)) adsorbed onto the surface of hematite nanocrystals significantly enhanced the efficiency of U(VI) remediation. Furthermore, the HNCs/Fe(II) system showed better U(VI) reduction ability than the HNPs/Fe(II) system. Remarkably, HNCs produced and consumed more electrons and hydroxyl radicals, indicating a more intense response. This finding serves to highlight the significance of their role in interfacial effects and in predicting the spatial distribution of U(VI) in aqueous systems.

Insights into the highly efficient SPR enhanced photodegradation of tetracycline by Bi/Bi2MoO6 composites.

A Bi/Bi2MoO6 nanocomposite is fabricated utilizing a simple one-pot solvothermal method, which shows great photodegradation ability to tetracycline (TC). The effect of Bi0 nanoparticles on the photodegradation of TC was investigated, and it is ascribed to the surface plasmonic resonance (SPR) effect. The light energy could be strongly absorbed by the Bi0 nanoparticles, and then transferred to the adjacent Bi2MoO6, to enhance the photocatalytic performance. The results of the sacrifice experiment and quantitative analysis of active radicals showed that the photoelectrons could react with soluble O2 and ·OH to form ·O2-, which finally dominates in the process of photocatalytic degradation of TC. This work proposed a way to construct a highly efficient photocatalyst based on SPR effect, which has great application potential in environmental treatment.

Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction.

In this work, a CdS/BiVO4 step-scheme (S-scheme) heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI) photoextraction. Characterizations such as transient absorption spectroscopy and Tafel test together confirmed the formation of S-scheme heterojunctions, which allows CdS/BiVO4 to avoid photocorrosion while retaining the strong reducing capacity of CdS and the oxidizing capacity of BiVO4. Experimental results such as radical quenching experiments and electron spin resonance show that U(VI) is rapidly oxidized by photoholes/•OH to insoluble UO2(OH)2 after being reduced to U(IV) by photoelectrons/•O2 -, which precisely avoids the depletion of electron sacrificial agents. The rapid recombination of electron-hole pairs triggered by the S-scheme heterojunction is found to release large amounts of heat and accelerate the photocatalysis. This work offers a new enhanced strategy for photocatalytic uranium extraction and presents a direction for the design and development of new photocatalysts.

In situ relative self-dependent calibration of electron cyclotron emission imaging via shape matching.

Electron Cyclotron Emission Imaging (ECEI) is a diagnostic system which measures 2-D electron temperature profiles with high spatial-temporal resolution. Usually only the normalized electron temperature fluctuations are utilized to investigate the magnetohydrodynamics modes due to the difficulties of ECEI calibration. In this paper, we developed a self-dependent calibration method for 24 × 16 channel high-resolution ECEI on the Experimental Advanced Superconducting Tokamak. The technique of shape matching is applied to solve for the matrix of the calibration coefficients. The calibrated area is further expanded to an occupation ratio of 88% observation area by utilizing the features of sawtooth crash. The result is self-consistent and consistent with calibrated 1D ECE measurement.

Re(CO)5Br-catalyzed coupling of epoxides with CO2 affording cyclic carbonates under solvent-free conditions.

In the presence of a catalytic amount of Re(CO)(5)Br, the coupling of epoxides with supercritical CO(2) without an organic solvent at 110 degrees C has afforded cyclic carbonates in good to excellent yields.