Efficient removal of hexavalent chromium from water by Bacillus sp. Y2-7 with production of extracellular polymeric substances.

Bioremediation is an environmentally friendly technology for the treatment of chromium-contaminated sites. Here, a hexavalent chromium [Cr(VI)]-resistant strain was isolated from oil-contaminated soil and designated as Bacillus sp. Y2-7 based on 16S rDNA sequence characterization. The effects of various factors including inoculation dose, pH value, glucose concentration, and temperature on Cr(VI) removal rates were then evaluated. Based on the response surface methodology, optimal Cr(VI) removal efficiency (above 90%) could be achieved at an initial Cr(VI) concentration of 155.0 mg·L-1, glucose concentration of 11.479 g·L-1, and pH of 7.1. The potential removal mechanisms of Cr(VI) by strain Y2-7 were also supposed. The contents of polysaccharide and protein in extracellular polymer (EPS) of strain Y2-7 decreased slowly after cultured with Cr(VI) of 15 mg·L-1 from 1 to 7 days. We thus inferred that EPS bonded with Cr(VI) and underwent morphological changes in water. Molecular operating environment (MOE) analysis suggested that macromolecular protein complexes in Bacillus sp. Y2-7 and hexavalent chromium could establish hydrogen bonds. Collectively, our findings indicate that Bacillus sp. Y2-7 is an excellent bacterial candidate for chromium bioremediation.

Tungsten-oxygen bond pre-introduced VO2(B) nanoribbons enable fast and stable zinc ion storage ability.

The tunnel structure of the bronze phase vanadium dioxide (VO2(B)) can be used as the zinc ion storage active sites. However, the intense charge repulsion of divalent Zn2+ causes a sluggish reaction kinetics in the tunnel VO2(B). Here, a tungsten-oxygen bond pre-introduced (TOBI) approach is proposed to modulate the tunnel structure of VO2(B). The VO2(B) cathodes with TOBI of 0.5 at% to 3.0 at% have been controllably synthesized by a simple hydrothermal method. The results from structural analysis uncover that the pre-introduced W6+ replaces the V4+ in VO2(B) to form WO6 octahedra. Benefiting from the rapid diffusion kinetics, enhanced structural stability and improved conductivity enabled by the TOBI, the optimal VO2(B) nanoribbons with 1.5 at% shows a high reversible capacity of 265 mAh g-1, a high rate-performance of up-to 10 A g-1 and a long cycling stability of 2000 cycles. Moreover, a pseudo-capacitive dominated Zn2+ intercalation/de-intercalation behavior is solidly determined by the electrochemical kinetics testing and structural characterizations. This TOBI method is referential for developing other multivalent ion battery cathodes with outstanding performances.