Band-Gap Energy and Electronic d-d Transitions of NiWO4 Studied under High-Pressure Conditions.

We report an extensive study of the optical and structural properties of NiWO4 combining experiments and density functional theory calculations. We have obtained accurate information on the pressure effect on the crystal structure determining the equation of state and compressibility tensor. We have also determined the pressure dependence of the band gap finding that it decreases under compression because of the contribution of Ni 3d states to the top of the valence band. We report on the sub-band-gap optical spectrum of NiWO4 showing that the five bands observed at 0.95, 1.48, 1.70, 2.40, and 2.70 eV correspond to crystal-field transitions within the 3d8 (t2g6eg2) configuration of Ni2+. Their assignment, which remained controversial until now, has been resolved mainly by their pressure shifts. In addition to the transition energies, their pressure derivatives are different in each band, allowing a clear band assignment. To conclude, we report resistivity and Hall-effect measurements showing that NiWO4 is a p-type semiconductor with a resistivity that decreases as pressure increases.

Long-term analysis of glaciers and glacier lakes in the Central and Eastern Himalaya.

Himalayan glaciers represent both an important source of water and a major suite of geohazards for inhabitants of their downstream regions. Recent climate change has intersected with local topographic, geomorphic, and glaciological factors to drive complex patterns of glacier thinning, retreat, velocity change, and lake development. In this study, we analyze the long-term variations in surface elevation change and velocity of the glaciers in the Central and Eastern Himalaya using existing and newly generated datasets spanning 1975 to 2018. We have used modelled (e.g., debris and ice thickness) and remote sensing datasets (e.g., Corona, Hexagon, and Landsat images) to investigate the impact of debris cover and the evolution of proglacial lakes on the glacier response in the region. We found that lake-terminating glaciers (lake TGs) have significantly higher thinning, velocity, and deceleration over time than land-terminating glaciers (land TGs). Lakes have shown an overall growth of 98 % in area and 40 % in number during 1975-2017. New proglacial lakes will likely continue to develop, and existing ones will keep expanding, influencing the frontal changes and dynamics of the lake-terminating glaciers. Debris-covered glaciers have undergone similar thinning compared to clean-ice glaciers, both for lake and land TGs; however, variations exist across the ablation zones between clean and debris-covered glaciers which this study further explores using a data-driven approach. Overall, the proglacial lakes development, changes in debris coverage, and topography significantly affect the glacier responses in the regions.

On periodic growth and shrinkage of glaciers in the Warwan sub-basin, western Himalaya, between 1990 and 2020.

Knowledge about glacier extent, dynamics, and characteristics are important for climate change attribution and prediction. Understanding on long-term dynamics and glacier inventory is crucial, particularly for the melt-dominated and latitudinally-diverse western Himalayan glacier basins. In this study, a temporal inventory is prepared for Warwan-sub basin (WSB), utilizing satellite imageries since the 1993 (Landsat TM: 1993; ETM+: 2001, 2008; OLI: 2020) and elevation model (SRTM DEM: 2000). The base inventory was generated for the year 2001 and systematically adjusted to the glacier situations in 1993, 2008, and 2020. Results indicate that in the year 2001, WSB in the western Himalaya included 84 glaciers (> 0.02 km2) covering an area of 187.9 ± 5.8 km2. The mapping (2001) further revealed a supraglacial debris cover of 15% of the glacierized area (28.2 ± 0.9 km2). Overall, the debris cover increased by 6% between 1993 and 2020. Temporal analyses clearly suggest a period of gain in the glacierized area (2001-2008) interspersed by the two phases of decline (1993-2001 and 2008-2020). Results specify a stronger decline in the glacierized area during 1993 to 2001 (197.03 ± 6.1 to 187.9 ± 5.8 km2) than between 2008 and 2020 (188.4 ± 5.9 to 182.8 ± 5.66 km2). Remarkably, the glacierized area increased from 187.9 ± 5.8 to 188.4 ± 5.8 km2 during 2001 to 2008. In view of widespread recession of regional glaciers, the gain in the area between 2001 and 2008 represents a peculiar characteristic of WSB that needs further detailed investigation. Further analyses suggest that low-altitude, east-facing, debris-free, steep-sloped, and small glaciers experienced greater loss in the area than large, debris-covered, north-facing, gently sloped, and high-altitude glaciers. Overall, the study at the sub-basin scale reveals inherent glacier dynamics with periodic increase and decrease in the glacierized area and a notable influence of non-climatic factors in regulating spatial heterogeneity and the rate of glacier changes.

Temperature and precipitation changes over the glaciated parts of Indian Himalayan Region during 1901-2016.

The existing knowledge on long-term climate trends over glaciated parts of Indian Himalayan Region (IHR) is limited. The present study aims at assessing the long-term (1901-2016) as well as the recent (1990-2016) temperature and precipitation trends over the glaciated parts of western (WH), central (CH) and eastern Himalaya (EH) within the IHR using Climate Research Unit Time Series version 4.01 (CRU TS4.01) data. Mann-Kendall and Sen's slope estimator tests were employed to determine the monotonic trend direction and magnitude of change over time on annual and seasonal basis. The temperature and precipitation trends were quantitatively assessed here in terms of percent change over mean as well as in absolute terms. Results show that annual average temperature remains > 0 °C in WH (2.26 °C) and CH (3.24 °C) but < 0 °C in EH (-0.97 °C). Long-term analysis (1901-2016) reveals the maximum warming in EH (74.67% or 0.93 °C) followed by WH (52.56% or 0.64 °C) and minimum in CH (44.31% or 0.73 °C). The winter warming is notably higher (WH: 1.11 °C, CH: 1.19 °C and EH: 1.41 °C) than the summer (WH: 0.31 °C, CH: 0.26 °C and EH: 0.54 °C). Annual precipitation gradually increases from WH (535.57 mm) to CH (749.91 mm) to EH (1249.49 mm), of which 68%, 76%, and 90% respectively, are summer-induced. Nevertheless, precipitation showed no clear trend in WH (slight increase of 4.53%) and EH (slight decrease of -5.30%), but a clear reduction in CH (-19.25%). Seasonally, precipitation decreased in winter (-4.53%) but increased in summer (10.65%) in WH, clearly decreased in both winter (-24.69%) and summer (-17.01%) in CH, and slightly increased in winter (2.21%) but decreased in summer (-6.80%) in EH. In recent decades (1990-2016), warming trend further accelerated in WH (0.95 °C) and CH (1.01 °C) but decreased in EH (0.60 °C). The overall precipitation trends also changed during 1990-2016 as WH experienced an overall reduction (-5%), CH maintained a declining trend (-13.10%), and EH showed slight increase (1.01%). The study concludes that the climate of glaciated parts has changed significantly, but the trend and magnitude is highly heterogeneous over different regions which likely influenced the glaciated environment.

Revisiting the 24 year (1994-2018) record of glacier mass budget in the Suru sub-basin, western Himalaya: Overall response and controlling factors.

Glacier mass balance time-series measurements have immense importance in comprehending the overall regional hydrology and meteorology of the mountain systems. Such assessments are critical in the Indus River basin (compared to the Ganga and Brahmaputra), which besides having a significant contribution from the glaciers, also exhibits considerable heterogeneity in glacier response. Thus, to quantify this variability in glacier behavior and thereby develop a comprehensive understanding of the past as well as the future evolution of the glaciers, we reconstruct the annual surface mass balance records of 75 glaciers (size >1 km2) in the Suru sub-basin, western Himalaya for the period 1994-2018. We apply a remote sensing-based equilibrium line altitude-mass balance approach, supported by geodetic mass balance estimates (for 18 major glaciers) and limited field measurements. Our findings suggest a persistent negative mass balance of the glaciers (average: -0.69 ± 0.28 m w.e.a-1, cumulative: -16.56 m w.e), varying from -0.46 ± 0.27 (1997) to -0.79 ± 0.28 (2018) m w.e.a-1 during the study period. This overall mass loss coincides with an increased temperature (Tavg increased 0.5 °C; Tmin increased 0.27 °C; Tmax increased 0.06 °C) and reduced precipitation (by 4%) in the valley during 1994-2018, which shows the sensitivity of these glaciers to climate change. Within the Suru sub-basin, smaller, cleaner and high-altitude mountain glaciers of the Ladakh range have experienced greater mass loss (cumulative: -20.88 m w.e) compared to the Greater Himalayan range (cumulative: -13.44 m w.e). We observe latitudinal variability in mass loss in the Western Himalaya, with the highest mass loss rates in the Greater Himalayan Range (>-0.9 m w.e.a-1) and lowest in the Karakoram Range (<-0.1 m w.e.a-1), suggesting a transitional response of the Suru sub-basin glaciers (-0.69 m w.e.a-1). The overall regional picture suggests synchronicity in the mass loss pattern of western Himalayan glaciers, predominantly controlled by the climatic conditions. Meanwhile, the variability in their mass loss rates is attributed to the unique glacier characteristics.