Zn-Induced Synthesis of Porous Fe-N,S-C Electrocatalyst with Iron-Based Active Sites Containing Sulfides, Oxides and Nitrides for Efficient Oxygen Reduction and Zinc-Air Batteries.

There is an urgent need to design and synthesize non-noble metal electrocatalysts (NNMEs) for the replacement of platinum-based electrocatalysts to enhance the sluggish oxygen reduction reaction (ORR) for Zn-air batteries and fuel cells. Herein, Fe-N,S-C materials were fabricated through two steps: first, reprecipitating hemin by adjusting the pH and, then, decorating it with melamine and cysteine in the presence of Zn2+. The resulting Fe-N,S-C-950 (Zn) was prepared after pyrolysis at 950 °C. Using this method, abundant iron-based active species with good dispersion were obtained. The fabrication of more micropores in Fe-N,S-C-950 (Zn) plays a positive role in the improvement of ORR activity. On comparison, Fe-N,S-C-950 (Zn) outperforms Fe-N,S-C-950 and Fe-N-C-950 (Zn) with respect to the ORR due to its larger specific surface area, porous structure, multiple iron-based active sites and N- and S-doped C. Fe-N,S-C-950 (Zn) achieves outstanding ORR performances, including a half-wave potential (E1/2) of 0.844 V and 0.715 V versus a reversible hydrogen electrode (RHE) in 0.1 M KOH and 0.1 M HClO4 solution, respectively. In addition, Fe-N,S-C-950 (Zn) shows an outstanding Zn-air battery performance with an open-circuit voltage (OCV) of 1.450 V and a peak power density of 121.9 mW cm-2, which is higher than that of 20 wt% Pt/C. As a result, the as-prepared electrocatalyst in this work shows the development of the Zn-assisted strategy combined with the assembly of porphyrins as NNMEs for the enhancement of the ORR in both alkaline and acidic solutions.

Outdoor thermal comfort during winter in China's cold regions: A comparative study.

Due to limits to standard methods for surveying outdoor thermal comfort (OTC), it is difficult to compare thermal benchmarks and thermal index calibrations among studies and climatic regions. Using uniform standard meteorological measurements and questionnaire surveys, our study conducted an OTC study in urban parks in Beijing, Xi'an and Hami; representative of cities in China's cold regions. The Universal Thermal Climate Index (UTCI) was used as the thermal comfort index, and differences in residents' thermal perceptions and outdoor thermal benchmarks among these cities were compared. Results showed that: 1) air temperature (Ta) and globe temperature (Tg) were two primary factors affecting residents' thermal sensations in the three cities during winter. Residents' thermal sensation in Beijing and Hami was negatively correlated with wind speed (Va). Residents in Xi'an and Hami preferred a higher relative humidity (RH). Residents in Beijing and Hami preferred a lower Va to improve OTC related to local climatic characteristics. 2) Xi'an residents had the highest neutral UTCI (NUTCI) (17.3 °C), followed by Beijing (17.0 °C) and Hami (6.4 °C). Xi'an residents had slightly wider neutral UTCI range (NUTCIR) (7.9-26.7 °C) compared to Beijing (8.7-25.4 °C), while Hami residents had the narrowest NUTCIR (1.5-11.3 °C). The "no thermal stress" range in the three cities was 6.1-26.0 °C in Beijing, 6.7-25.5 °C in Xi'an, and -2.2-12.2 °C in Hami. 3) Calibrated thermal indices, based on the ASHRAE 7-point scale, were gained to judge the thermal qualities of an environment for all three cities.

Summertime physiological and thermal responses among activity levels in campus outdoor spaces in a humid subtropical city.

We identified physiological and thermal responses to different activity levels on a campus during summertime in Xi'an, a humid subtropical city in China. Physiological responses and thermal comfort of 54 healthy college students while undertaking different physical activities (light, moderate and vigorous intensities) in six campus open spaces were investigated using meteorological measures, longitudinal questionnaire surveys and physiological parameters. Physiological Equivalent Temperature (PET) and Universal Thermal Climate Index (UTCI) were chosen as the thermal indices, while blood pressure (BP), heart rate (HR) and skin temperature (ST) were selected as physiological evaluation measures. Results demonstrated that: 1) Types and proportions of thermal symptoms were positively related to outdoor spatial characteristics and physical activity levels. The proportion of thermal discomfort increased 33, 50 and 83% as activity intensities increased from light through moderate to vigorous. 2) BP and HR reflected human activity levels. HR clearly represented metabolic trends. 3) ST accurately represented physiological responses among spaces across activity levels. However, mean skin temperature (MST) was poorly related to thermal sensation vote (TSV). 4) As activity intensity ranged from light through moderate to vigorous, neutral UTCI declined by 27.6 °C, 25.6 °C, 22.0 °C, and neutral PET declined by 26.1 °C, 22.1 °C, 11.9 °C. 5) Outdoor spaces shaded by trees or pavilions were more comfortable for outdoor activities than these with low or middle SVF during summer.