Micro and nano plastics in fruits and vegetables: A review.

Plastics are becoming common environmental pollutants. Plants behave as access routes for plastics in the trophic chain since they can adsorb particles through their roots or on their surfaces. In this review, various methods for sample preparation and analytical methods for plastic isolation and identification from vegetables, fruits, and their seedlings were discussed. The effects that plastic particles have on them were also addressed. All of the studies offer convincing proof that micro and nano plastics already exist in fruits and vegetables, or can easily enter into their seedlings and have a variety of effects. Since most studies have been conducted under strictly controlled conditions using standard plastics, more tests under more environmentally realistic conditions are required to ensure that literature studies are applicable. Also, more fruits and vegetables need to be tested to identify the number of plastics currently there that, when consumed, could harm human health.

The influence of climate changes on heavy metals accumulation in Alosa immaculata from the Danube River Basin.

This research report provides a comprehensive overview of the historical trends in heavy metal concentrations in the Pontic shad (Alosa immaculata) populations from both the Danube River and the Black Sea, while also exploring the potential influence of global warming on metal accumulation. Through bibliometric modeling analysis, it reveals significant limitations in existing international research, particularly the lack of comprehensive data on the impact of hydroclimatic changes on heavy metal accumulation in Alosa immaculata. Recognizing the critical importance of studies on heavy metal bioaccumulation in Danube shad, this research underscores their significance in defining tolerance thresholds, quantifying the impact of toxic elements along the aquatic food chain, and enhancing the economic sustainability of ichthyofauna monitoring efforts. Furthermore, these studies contribute invaluable insights into the complex dynamics of aquatic ecosystems, offering essential decision-making support for optimizing commercial fishing management practices on the Danube and ensuring robust support systems for industrial fishing endeavors.

Human health risk assessment of potentially toxic elements and microplastics accumulation in products from the Danube River Basin fish market.

The present study aimed to quantify the concentration levels of potentially toxic elements (PTEs) such as aluminum, arsenic, cadmium, chromium, copper, nickel, lead, zinc, and mercury, as well as microplastics occurrence in various tissues of fish and seafood species, commercialized in the Lower Danube River Basin. A health risk assessment analysis was performed based on the PTEs concentration levels in the muscle tissue. Estimated daily intake (EDI), target hazard quotient (THQ), hazard index (HI), and target cancer risk (TR) of PTEs were calculated. It was observed that the species within the seafood category registered the highest levels of PTEs. For instance, in the muscle tissue of bivalve Mytilus galloprovincialis (from the Black Sea), the highest value was observed in the case of Zn (37.693 mg/kg), and the presence of polystyrene polymer was identified. The values associated with EDI, THQ, HI, and TR of PTE exposure were significantly lower than 1.

Effects of cooking methods and co-ingested foods on mercury bioaccessibility in pontic shad (Alosa immaculata).

Human mercury (Hg) exposure is mostly caused by eating fish. However, there are major differences between the measured and predicted mercury concentration on Hg bioavailability. This study investigated the effects of cooking (steaming, baking, frying, marinating, and smoking) and selected components' co-ingestion on Hg bioaccessibility. Baking and frying reduced Hg bioaccessibility compared to the raw sample. The bioaccessible Hg fraction in fish was assessed through in vitro digestion method. Hg bioaccessibility varied from 4.31 to nearly 24.95% and the Hg recovery rate varied from 63.44 to 78.74%. Co-ingested garlic and broccoli with pontic shad had a positive effect on decreasing fish Hg bioaccessibility. The antioxidant activity of co-ingested food items was also calculated and correlated with mercury bioaccessibility. These results highlighted a possible positive role of plant-based foods and other food processing techniques in the bioaccessibility reduction of other chemical contaminants found in food sources.

A New Composite Material with Environmental Implications for Sustainable Agriculture.

Sewage sludge, also referred to as biosolids, consists of the by-products of wastewater treatment, which are a mixture of the water and organic and inorganic materials eliminated from wastewater sourced from domestic sewage industries during physical, biological, and/or chemical treatments. Biosolids are nutrient-rich organic materials resulting from the treatment of domestic wastewater in treatment plants. Sewage sludge can be considered a significant biological resource for sustainable agriculture. A new composite has been made consisting of soil, sewage sludge collected from the Galati Wastewater Treatment Plant, and slag from the Galati Steel Plant. This study aimed to investigate the structural, morphological, and chemical parameters of this composite through FTIR, SEM-EDX analysis, and XRF analysis. The samples had values of potential toxic elements that were within normal limits according to Directive 86/278/CEE, and, in terms of the iron-to-calcium ratio (I/C), all samples were of a low grade. This is the first time that slag has been added in a sewage sludge-soil combination, which can be an effective fertilizer replacement. Sewage sludge contains substantial amounts of organic matter, and slag reduces the contents of potentially toxic elements. In addition to these attributes, they may provide an opportunity for the beneficial re-use of sewage sludge and slag as resources in agriculture.

Dispersive optical solitons and conservation laws of Radhakrishnan-Kundu-Lakshmanan equation with dual-power law nonlinearity.

The current paper implements three elegant approaches to recover a complete spectrum of optical solitons to the Radhakrishnan-Kundu-Lakshmanan equation with dual-power law of nonlinear refractive index. The conservation laws are also recovered by the usage of multipliers approach. The parameter constraints for the existence of such solitons are also enumerated. The numerical simulations of the recovered soliton solutions are also presented.

Assessing and forecasting water quality in the Danube River by using neural network approaches.

The health and quality of the Danube River ecosystems is strongly affected by the nutrients loads (N and P), degree of contamination with hazardous substances or with oxygen depleting substances, microbiological contamination and changes in river flow patterns and sediment transport regimes. Water quality index (WQI) is an important dynamic attribute in the characterization of the Danube River ecosystems health and quality. The WQ index scores do not reflect the actual condition of water quality. We proposed a new forecast scheme for water quality based on the following qualitative classes very good (0-25), good (26-50), poor (51-75), very poor (76-100) and extremely polluted/non-potable (>100). Water quality forecasting by using Artificial Intelligence (AI) is a meaningful method of protecting public health because of its possibility to provide early warning regarding harmful water pollutants. The main objective of the present study is to forecast the WQI time series data based on water physical, chemical and flow status parameters and associated WQ index scores. The Cascade-forward network (CFN) models, along with the Radial Basis Function Network (RBF) as a benchmark model, were developed using data from 2011 to 2017 and WQI forecasts were produced for the period 2018-2019 at all sites. The nineteen input water quality features represent the initial dataset. Moreover, the Random Forest (RF) algorithm refines the initial dataset by selecting eight features considered the most relevant. Both datasets are employed for constructing the predictive models. According to the results of appraisal, the CFN models produced better outcomes (MSE = 0.083/0,319 and R-value 0.940/0.911 in quarter I/quarter IV) than the RBF models. In addition, results show that both the CFN and RBF models could be effective for predicting time series data for water quality when the eight most relevant features are used as input variables. Also, the CFNs provide the most accurate short-term forecasting curves which reproduce the WQI for the first and fourth quarters (the cold season). The second and third quarters presented a slightly lower accuracy. The reported results clearly demonstrate that CFNs successfully forecast the short-term WQI as they may learn historic patterns and determine the nonlinear relationships between the input and output variables.

Regional Regression Correlation Model of Microplastic Water Pollution Control Using Circular Economy Tools.

Water pollution caused by microplastics represents an important challenge for the environment and people's health. The weak international regulations and standards in this domain support increased water pollution with microplastics. The literature is unsuccessful in establishing a common approach regarding this subject. The main objective of this research is to develop a new approach to necessary policies and ways of action to decrease water pollution caused by microplastics. In this context, we quantified the impact of European water pollution caused by microplastics in the circular economy. The main research methods used in the paper are meta-analysis, statistical analysis and an econometric approach. A new econometric model is developed in order to assist the decision makers in increasing efficiency of public policies regarding water pollution elimination. The main result of this study relies on combining, in an integrated way, the Organisation for Economic Co-operation and Development's (OECD) data on microplastic water pollution and identifying relevant policies to combat this type of pollution.

Recycling micro polypropylene in modified hot asphalt mixture.

One of the objectives of the circular economy is solving the world's plastic pollution crisis and recycling of materials by ensuring less waste. The motivation of this study was to demonstrate the possibility of recycling two types of wastes with a high risk of pollution, such as plastic based polypropylene and abrasive blasting grit wastes in asphalt roads. The effects of adding together polypropylene based microplastics and grit waste in asphalt mixture for wear layer performance have been shown in this study. The morphology and elemental composition of the hot asphalt mixture samples before and after freeze-thaw cycle were examined by SEM-EDX and the performance of the modified asphalt mixture was determined with laboratory tests including Marshall stability, flow rate, solid-liquid report, apparent density, and water absorption. A hot asphalt mixture suitable for making wear layer in road construction, containing aggregates, filler, bitumen, abrasive blasting grit waste and polypropylene based microplastics is also disclosed. In the recipe of modified hot asphalt mixtures were added 3 proportions of polypropylene-based microplastics such as 0.1%, 0.3% and 0.6%. An improvement of the mixture performance is shown at the asphalt mixture sample with 0.3% of polypropylene. In addition, polypropylene-based microplastics are bond with aggregates from mixture well, so the polypropylene-modified hot asphalt mixture can effectively decrease the appearance of cracks during sudden temperature changes.

Assessment of NO2 Pollution Level during the COVID-19 Lockdown in a Romanian City.

This study investigates changes in pollution associated with the lockdown period caused by the COVID-19 pandemic in Galati (45.43° N, 28.03° E), a Romanian city located in the southeast of Romania. The study is focused on nitrogen dioxide (NO2), a trace gas which can be related to emissions from industrial activities, heating, and transportation. The investigation is based on in situ observations from local Air Quality Monitoring Stations (AQMS) and mobile remote sensing observations by Differential Optical Absorption Spectroscopy (DOAS) technique. We also show results of the NO2 vertical column measured by TROPOMI (TROPOspheric Monitoring Instrument), a space instrument onboard of satellite mission Sentinel-5P, to complement local ground-based measurements. For in situ observations, the lockdown interval (23 March 2020-15 May 2020) was separated from normal periods. The decrease in local NO2 concentration during lockdown, measured in situ, is rather small, of about 10-40% at the most, is observed only at some stations, and is better seen during workdays than during weekends. We conclude that the decrease in NO2 content over Galati city during lockdown is relatively small and may be attributed to the reduction in local traffic, a consequence of special measures and restrictions imposed during the COVID-19 lockdown by the Romanian authorities.

Evolution of SO2 and NOx Emissions from Several Large Combustion Plants in Europe during 2005-2015.

The aim of this paper is to investigate the evolution of SO2 and NOx emissions of ten very large combustion plants (LCPs >500 MW) located in the European Union (EU) during 2005-2015. The evolution of NOx and SO2 emissions were analyzed against the EU Directives in force during 2005-2015. The investigation was performed using space-borne observations and estimated emissions collected from the EEA (European Environment Agency) inventory of air pollutant emissions. The power plants were chosen according to their capacity and emissions, located in various parts of Europe, to give an overall picture of atmospheric pollution with NOx and SO2 associated with the activity of very large LCPs in Europe. Satellite observations from OMI (Ozone Monitoring Instrument) are compared with calculated emissions in order to assess whether satellite observations can be used to monitor air quality, as a standard procedure, by governmental or nongovernmental institutions. Our results show that both space observations and estimated emissions of NOx and SO2 atmospheric content have a descending trend until 2010, complying with the EU Directives. The financial and economic crisis during 2007-2009 played an important role in reducing emissions.