Correlated response in a driven flow of self-organizing particles around a slit in porous media by interacting lattice gas.

The flow of immiscible particles (A, B) through a porous medium with a vertical slit is studied by an interacting lattice-gas computer simulation on a discrete lattice. The source of the particles is connected to the bottom and particles are driven upward by concentration gradient and a pressure bias against gravity. Distribution of flowing particles around the slit is examined as a function of the slit width and bias at high and low porosity at a steady state. At the low bias, a sharp change in the densities (high in slit to low in adjacent porous media) of both constituents occurs as expected. Onset of an undershooting in the density and mobility of particle profiles appears at the interface of slit and the porous medium on increasing the bias, an unexpected correlated response. The competition between the faster flow in the slit and slower motion of the particles in the surrounding porous medium induces stronger correlations at higher bias; as a result, a well-defined density profile emerges with higher density in the porous matrix away from the slit interface. The range of correlation and therefore the response increases on increasing the bias. Lowering the porosity to near the percolation threshold leads to the onset of oscillation in the density profile and broadening of the mobility profile, a distinct difference from the response at high porosity.

Decreased stability of methane hydrates in marine sediments owing to phase-boundary roughness.

Below water depths of about 300 metres, pressure and temperature conditions cause methane to form ice-like crystals of methane hydrate. Marine deposits of methane hydrate are estimated to be large, amassing about 10,000 gigatonnes of carbon, and are thought to be important to global change and seafloor stability, as well as representing a potentially exploitable energy resource. The extent of these deposits can usually be inferred from seismic imaging, in which the base of the methane hydrate stability zone is frequently identifiable as a smooth reflector that runs parallel to the sea floor. Here, using high-resolution seismic sections of seafloor sediments in the Cascadia margin off the coast of Vancouver Island, Canada, we observe lateral variations in the base of the hydrate stability zone, including gas-rich vertical intrusions into the hydrate stability zone. We suggest that these vertical intrusions are associated with upward flow of warmer fluids. Therefore, where seafloor fluid expulsion and methane hydrate deposits coincide, the base of the hydrate stability zone might exhibit significant roughness and increased surface area. Increased area implies that significantly more methane hydrate lies close to being unstable and hence closer to dissociation in the event of a lowering of pressure due to sea-level fall.