1.
J Org Chem
; 70(6): 2097-108, 2005 Mar 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-15760193
RESUMO
[structure: see text] The total synthesis of (+)-zoapatanol utilizing an intramolecular Horner-Wadsworth-Emmons olefination and an enantioselective Sharpless dihydroxylation as the key steps has been achieved. An advanced oxepene intermediate has been obtained by applying a ring-closing metathesis to an unsaturated enol ether.