Kondo effect and spin-orbit coupling in graphene quantum dots.

The Kondo effect is a cornerstone in the study of strongly correlated fermions. The coherent exchange coupling of conduction electrons to local magnetic moments gives rise to a Kondo cloud that screens the impurity spin. Here we report on the interplay between spin-orbit interaction and the Kondo effect, that can lead to a underscreened Kondo effects in quantum dots in bilayer graphene. More generally, we introduce a different experimental platform for studying Kondo physics. In contrast to carbon nanotubes, where nanotube chirality determines spin-orbit coupling breaking the SU(4) symmetry of the electronic states relevant for the Kondo effect, we study a planar carbon material where a small spin-orbit coupling of nominally flat graphene is enhanced by zero-point out-of-plane phonons. The resulting two-electron triplet ground state in bilayer graphene dots provides a route to exploring the Kondo effect with a small spin-orbit interaction.

Coherent Jetting from a Gate-Defined Channel in Bilayer Graphene.

Graphene has evolved as a platform for quantum transport that can compete with the best and cleanest semiconductor systems. Here, we report on the observation of distinct electronic jets emanating from a narrow split-gate-defined channel in bilayer graphene. We find that these jets, which are visible via their interference patterns, occur predominantly with an angle of 60° between each other. This observation is related to the trigonal warping in the band structure of bilayer graphene, which, in conjunction with electron injection through a constriction, leads to a valley-dependent selection of momenta. This experimental observation of electron jetting has consequences for carrier transport in two-dimensional materials with a trigonally warped band structure in general, as well as for devices relying on ballistic and valley-selective transport.

Tunable Valley Splitting due to Topological Orbital Magnetic Moment in Bilayer Graphene Quantum Point Contacts.

In multivalley semiconductors, the valley degree of freedom can be potentially used to store, manipulate, and read quantum information, but its control remains challenging. The valleys in bilayer graphene can be addressed by a perpendicular magnetic field which couples by the valley g factor g_{v}. However, control over g_{v} has not been demonstrated yet. We experimentally determine the energy spectrum of a quantum point contact realized by a suitable gate geometry in bilayer graphene. Using finite bias spectroscopy, we measure the energy scales arising from the lateral confinement as well as the Zeeman splitting and find a spin g factor g_{s}∼2. g_{v} can be tuned by a factor of 3 using vertical electric fields, g_{v}∼40-120. The results are quantitatively explained by a calculation considering topological magnetic moment and its dependence on confinement and the vertical displacement field.

Benzalkonium Chloride Induces a VBNC State in Listeria monocytogenes.

The objective of our study was to investigate the effects of benzalkonium chloride (BC) adaptation of L. monocytogenes on the susceptibility to antimicrobial agents and on the viable but non culturable (VBNC) state of the bacterial cells. We adapted L. monocytogenes SLCC2540 to BC by applying BC below minimum inhibitory concentration (MIC) to above minimum bactericidal concentration (MBC). The culturable fractions and the susceptibility of adapted and parental cells to BC were assessed. In addition, cell membrane permeability and glucose uptake were analyzed by multi parametric flow cytometry using the fluorescent agents SYTO9, propidium iodide, and 2-deoxy-2-[(7-nitro-2,1,3-benzoxadiazol-4-yl)amino]-D-glucose (2-NBDG). Adapted cells displayed a two-fold MIC increase of BC and reduced antibiotic susceptibility. At high BC concentrations, the decrease in the number of colony forming units was significantly lower in the population of adapted cells compared to parental cells. At the same time, the number of metabolically active cells with intact membranes was significantly higher than the number of culturable cells. Growth-independent viability assays revealed an adapted subpopulation after BC application that was not culturable, indicating increased abundance of viable but nonculturable (VBNC) cells. Moreover, adapted cells can outcompete non-adapted cells under sublethal concentrations of disinfectants, which may lead to novel public health risks.

Gap Opening in Twisted Double Bilayer Graphene by Crystal Fields.

Crystal fields occur due to a potential difference between chemically different atomic species. In van der Waals heterostructures such fields are naturally present perpendicular to the planes. It has been realized recently that twisted graphene multilayers provide powerful playgrounds to engineer electronic properties by the number of layers, the twist angle, applied electric biases, electronic interactions, and elastic relaxations, but crystal fields have not received the attention they deserve. Here, we show that the band structure of large-angle twisted double bilayer graphene is strongly modified by crystal fields. In particular, we experimentally demonstrate that twisted double bilayer graphene, encapsulated between hBN layers, exhibits an intrinsic band gap. By the application of an external field, the gaps in the individual bilayers can be closed, allowing to determine the crystal fields. We find that crystal fields point from the outer to the inner layers with strengths in the bottom/top bilayer [Formula: see text] = 0.13 V/nm ≈ [Formula: see text] = 0.12 V/nm. We show both by means of first-principles calculations and low energy models that crystal fields open a band gap in the ground state. Our results put forward a physical scenario in which a crystal field effect in carbon substantially impacts the low energy properties of twisted double bilayer graphene, suggesting that such contributions must be taken into account in other regimes to faithfully predict the electronic properties of twisted graphene multilayers.