Utilizing Undissolved Portion (UNP) of Cement Kiln Dust as a Versatile Multicomponent Catalyst for Bioethylene Production from Bioethanol: An Innovative Approach to Address the Energy Crisis.

This study focuses on upcycling cement kiln dust (CKD) as an industrial waste by utilizing the undissolved portion (UNP) as a multicomponent catalyst for bioethylene production from bioethanol, offering an environmentally sustainable solution. To maximize UNP utilization, CKD was dissolved in nitric acid, followed by calcination at 500 °C for 3 h in an oxygen atmosphere. Various characterization techniques confirmed that UNP comprises five different compounds with nanocrystalline particles exhibiting an average crystal size of 47.53 nm. The UNP catalyst exhibited a promising bioethylene yield (77.1%) and selectivity (92%) at 400 °C, showcasing its effectiveness in converting bioethanol to bioethylene with outstanding properties. This exceptional performance can be attributed to its distinctive structural characteristics, including a high surface area and multiple-strength acidic sites that facilitate the reaction mechanism. Moreover, the UNP catalyst displayed remarkable stability and durability, positioning it as a strong candidate for industrial applications in bioethylene production. This research underscores the importance of waste reduction in the cement industry and offers a sustainable path toward a greener future.

Mg-O-F Nanocomposite Catalysts Defend against Global Warming via the Efficient, Dynamic, and Rapid Capture of CO2 at Different Temperatures under Ambient Pressure.

The utilization of Mg-O-F prepared from Mg(OH)2 mixed with different wt % of F in the form of (NH4F·HF), calcined at 400 and 500 °C, for efficient capture of CO2 is studied herein in a dynamic mode. Two different temperatures were applied using a slow rate of 20 mL·min-1 (100%) of CO2 passing through each sample for only 1 h. Using the thermogravimetry (TG)-temperature-programed desorption (TPD) technique, the captured amounts of CO2 at 5 °C were determined to be in the range of (39.6-103.9) and (28.9-82.1) mgCO2 ·g-1 for samples of Mg(OH)2 mixed with 20-50% F and calcined at 400 and 500 °C, respectively, whereas, at 30 °C, the capacity of CO2 captured is slightly decreased to be in the range of (32.2-89.4) and (20.9-55.5) mgCO2 ·g-1, respectively. The thermal decomposition of all prepared mixtures herein was examined by TG analysis. The obtained samples calcined at 400 and 500 °C were characterized by X-ray diffraction and surface area and porosity measurements. The total number of surface basic sites and their distribution over all samples was demonstrated using TG- and differential scanning calorimetry-TPD techniques using pyrrole as a probe molecule. Values of (ΔH) enthalpy changes corresponding to the desorption steps of CO2 were calculated for the most active adsorbent in this study, that is, Mg(OH)2 + 20% F, at 400 and 500 °C. This study's findings will inspire the simple preparation and economical design of nanocomposite CO2 sorbents for climate change mitigation under ambient conditions.

Assessment of Lewis-Acidic Surface Sites Using Tetrahydrofuran as a Suitable and Smart Probe Molecule.

Measuring the Lewis-acidic surface sites in catalysis is problematic when the material's surface area is very low (SBET ≤1 m2 ⋅ g-1 ). For the first time, a quantitative assessment of total acidic surface sites of very small surface area catalysts (MoO3 as pure and mixed with 5-30 % CdO (wt/wt), as well as CdO for comparison) was performed using a smart new probe molecule, tetrahydrofuran (THF). The results were nearly identical compared to using another commonly used probe molecule, pyridine. This audition is based on the limited values of the surface area of these samples that likely require a relatively moderate basic molecule as THF with pKb =16.08, rather than strong basic molecules such as NH3 (pKb =4.75) or pyridine (pKb =8.77). We propose mechanisms for the interaction of vapour phase molecules of THF with the Lewis-cationic Mo and Cd atoms of these catalysts. Besides, dehydration of isopropyl alcohol was used as a probe reaction to investigate the catalytic activity of these catalysts to further support our findings in the case of THF in a temperature range of 175-300 °C. A good agreement between the obtained data of sample MoO3 -10 % CdO, which is characterised by the highest surface area value, the population of Lewis-acidic sites and % selectivity of propylene at all the applied reaction temperatures was found.

Adsorptive removal of some Cl-VOC's as dangerous environmental pollutants using feather-like γ-Al2O3 derived from aluminium waste with life cycle analysis.

Herein, we designed a cost-effective preparation method of nanocomposite γ-Al2O3 derived from Al-waste. The produced material has a feather-like morphology, and its adsorption of some chlorinated volatile organic compounds (Cl-VOC's) such as benzyl chloride, chloroform and carbon tetrachloride (C7H7Cl, CHCl3 and CCl4) was investigated due to their potential carcinogenic effect on humans. It showed a characteristic efficiency towards the adsorptive removal of these compounds over a long period, i.e., eight continuous weeks, at ambient temperature and atmospheric pressure. After 8-weeks, the adsorbed amounts of these compounds were determined as: 325.3 mg C7H7Cl, 247.6 mg CHCl3 and 253.3 mg CCl4 per g of γ-Al2O3, respectively. CCl4 was also found to be dissociatively adsorbed on the surface of γ-Al2O3, whereas CHCl3 and C7H7Cl were found to be associatively adsorbed. The prepared γ-Al2O3 has a relatively high surface area (i.e., 192.2 m2. g-1) and mesoporosity with different pore diameters in the range of 25-47 Å. Furthermore, environmental impacts of the nanocomposite γ-Al2O3 preparation were evaluated using life cycle assessment. For prepartion of adsorbent utilising 1 kg of scrap aluminium wire, it was observed that potential energy demand was 288 MJ, climate change potential was 19 kg CO2 equivalent, acidification potential was 0.115 kg SO2 equivalent and eutrophication potential was 0.018 kg PO43- equivalent.

Surface hydrophobicity and acidity effect on alumina catalyst in catalytic methanol dehydration reaction.

BACKGROUND: Methanol to dimethyl ether (MTD) is considered one of the main routes for the production of clean bio-fuel. The effect of copper loading on the catalytic performance of different phases of alumina that formed by calcination at two different temperatures was examined for the dehydration of methanol to dimethyl ether (DME). RESULTS: A range of Cu loadings of (1, 2, 4, 6, 10 and 15% Cu wt/wt) on Al2O3 calcined at 350 and 550 °C were prepared and characterized by TGA, XRD, BET, NH3-TPD, TEM, H2-TPR, SEM, EDX, XPS and DRIFT-Pyridine techniques. The prepared catalysts were used in a fixed bed reactor under reaction conditions in which the temperature ranged from 180-300 °C with weight hourly space velocity (WHSV) = 12.1 h-1. It was observed that all catalysts calcined at 550 °C (γ-Al2O3 support phase) exhibited higher activity than those calcined at 350 °C (γ-AlOOH), and this is due to the phase support change. Furthermore, the optimum Cu loading was found to be 6% Cu/γ-Al2O3 with this catalyst also showing a high degree of stability under steady state conditions and this is attributed to the enhancement in surface acidity and hydrophobicity. CONCLUSION: The addition of copper to the support improved the catalyst properties and activity. For all the copper modified catalysts, the optimum catalyst with high degree of activity and stability was 6% copper loaded on gamma alumina. © 2017 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.