A comprehensive perspective on potentially hazardous elements (PHEs) bound with particulate matters in ambient air of landfill sites: a systematic review and probabilistic risk assessment.

Air pollution from Potentially Hazardous Elements bound with particulate matter (PHEs bound PM) in landfill air is a significant concern for human health. To date, no comprehensive research has focused on the health risks of PHEs bound to PM in landfill air. This systematic review aimed to examine PHEs, including Lead (Pb), Cadmium (Cd), Chromium (Cr), Arsenic (As), Nickel (Ni), and Zinc (Zn) bound with PM in landfill air and assess the health risk for workers and waste management personnel. The systematically search was made in different electronic databases. After the screening, 18 most relevant studied focused on PHEs bound PM in landfill air were selected. The data extraction analysis indicated that mean concentrations of Pb, Cd, Cr, As, Ni, and Zn in landfill air were 0.3037, 0.0941, 0.4093, 0.0221, 0.2768, and 0.7622 µg/m3, respectively. Except for Pb, the concentrations of other PHEs bound to PM exceeded USEPA air quality standards. In addition, Non-carcinogenic risks from Cd, Cr, and Ni exposure exceeded permissible limits (HQ > 1), while As had an HQ value of 0.401. Carcinogenic risks from As, Cd, Ni, and Pb exposure were 1.31 × 10-5, 5.10 × 10-4, 3.51 × 10-5, and 2.03 × 10-6, respectively. Notably, the lifetime carcinogenic risk for workers exposed to Cr in polluted air (6.17 × 10-3) exceeded permissible limits (10-4 to 10-6). In conclusion, given the high carcinogenic and non-carcinogenic risks of some PHEs bound PM in landfills, it is necessary to conduct more research on the health effects of interaction with these PHEs bound PM on communities and the environment in different countries. Also, it is necessary to evaluate the role of different landfill operational activities on atmospheric dispersion of PHEs bound PM) in landfill air.

Potentially toxic elements (PTEs) in coastal sediments of Bandar Abbas city, North of Persian Gulf: An ecological risk assessment.

The concentration of potentially toxic elements (PTEs; Lead (Pb), Nickel (Ni), and Cadmium (Cd) Pb, Ni, and Cd), using flame atomic absorption spectrometry (FAAS) was measured in fifty surface coastal sediment samples collected from 5 points coastal sediment of Bandar Abbas city, Iran besides the potential ecological risk index (RI) estimated the environmental health risk. The rank order of PTEs was Pb (52.090 ± 4.113 mg/kg dry weight) > Ni (34.940 ± 8.344 mg/kg dry weight) > Cd (2.944 ± 0.013 mg/kg dry weight). RI due to PTEs in sediments for A, B, C, D, and E points were 187.655, 190.542, 191.079, 189.496, and 192.053, respectively. RI for sampling points A to E was at moderate risk (150 ≤ RI < 300). Therefore, it is recommended to carry out control programs to reduce the amount of PTEs in the coastal sediment of the Persian Gulf.

Steroid hormones in surface water resources in China: systematic review and meta-analysis and probabilistic ecological risk assessment.

A Search was conducted in international databases including Scopus, PubMed, Embase, and Web of Science from 10 January 2005 to 15 January 2023. The risk quotient (RQ) of Estrone (E1), 17ß-E2 (E2), and Estriol (E3) on the surface water resources of China was calculated by Monte Carlo Simulation (MCS) technique. The rank order of steroid hormones based on pooled (weighted average) concentration in surface water was E3 (2.15 ng/l) > E2 (2.01 ng/l) > E1 (1.385 ng/l). The concentration of E1 in Dianchi lake (236.50.00 ng/l), 17ß-E2 in Licun river (78.50 ng/l), and E3 in Dianchi lake (103.1 ng/l) were higher than in other surface water resources in China. RQ related to E1, 17ß-E2 and E3 in 68.00%, 88.89% and 3.92% of surface water resources were high ecological risk, respectively. Therefore, carrying out source control plans for steroid hormones in surface water sources should be conducted continuously.

The concentration of Potentially Toxic elements (PTEs) in the muscle of crabs: a global systematic review, meta-analysis, and health risk assessment.

The concentration of PTEs in the muscle of crabs, was meta-analyzed using a random-effects model based on countries' subgroups. The non-carcinogenic and carcinogenic risks related to the ingestion of PTEs via the consumption of crab fish were estimated. The meta-analysis included one hundred and eight papers with 109 data reports. The rank order of PTEs based on pooled (mean) concentration in the muscle of crabs was Ni (4.490 mg/kg-ww) > Pb (1.891 mg/kg-ww) >As (1.601 mg/kg-ww) > Cd (1.101 mg/kg-ww). The results showed that adults and children consumers in many countries are at risk of non-carcinogenicity due to ingestion of Ni, Pb, As, and Cd and carcinogenicity risk due to As. Therefore, the bioaccumulation of PTEs in the muscle of crabs can be considered a global health risk. Hence, to decrease the health risk of PTEs in the muscle of crabs, continuous monitoring and reducing the emission of PTEs in aquatic environments are recommended.

Process optimization and enhancement of pesticide adsorption by porous adsorbents by regression analysis and parametric modelling.

In the present study, the adsorptive removal of organophosphate diazinon pesticide using porous pumice adsorbent was experimentally investigated in a batch system, modelled and optimized upon response surface methodology (RSM) and artificial neural network-genetic algorithm (ANN-GA), fitted to isotherm, kinetic and thermodynamic models. The quantification of adsorbent elements was determined using EDX. XRD analysis was utilized to study the crystalline properties of adsorbent. The FT-IR spectra were taken from adsorbent before and after adsorption to study the presence and changes in functional groups. The constituted composition of the adsorbent was determined by XRF. Also, the ionic strength and adsorbent reusability were explored. The influences of operational parameters like pH, initial pesticide concentration, adsorbent dosage and contact time were investigated systematically. ANN-GA and RSM techniques were used to identify the optimal process variables that result in the highest removal. Based on the RSM approach, the optimization conditions for maximum removal efficiency is obtained at pH = 3, adsorbent dosage = 4 g/L, contact time = 30 min, and initial pesticide concentration = 6.2 mg/L. To accurately identify the parameters of nonlinear isotherm and kinetic models, a hybrid evolutionary differential evolution optimization (DEO) is applied. Results indicated that the equilibrium adsorption data were best fitted with Langmuir and Temkin isotherms and kinetic data were well described by pseudo-first and second-order kinetic models. The thermodynamic parameters such as entropy, enthalpy and Gibbs energy were evaluated to study the effect of temperature on pesticide adsorption.

The concentration of potentially hazardous elements (PHEs) in the muscle of blue crabs (Callinectes sapidus) and associated health risk.

In this study, the concentration of potentially hazardous elements (PHEs) in the muscle of Blue crabs (Callinectes sapidus) from the Strait of Hormuz was analyzed and following the health risk in the consumers by uncertainty and sensitivity analysis in the Monte Carlo simulation (MCS) technique was estimated. Fifty-eight blue card samples (male blue crabs = 33 samples; female blue crabs = 25 samples) were collected in the Strait of Hormuz from May to September 2020 for analysis of Nickel (Ni), Lead (Pb), Cadmium (Cd), and Iron (Fe) using Flame Absorption Spectrometer (FAAS). The order of PHEs in the in muscle male blue crabs was Fe (414.37 ± 288.07 µg/kg.ww) > Pb (238.78 ± 87.83 µg/kg.ww) > Ni (92.57 ± 39.72 µg/kg.ww) > Cd (52.73 ± 18.39 µg/kg.ww) and in female blue crabs Fe (461.16 ± 320.56 µg/kg.ww) > Pb (230.79 ± 125.59 µg/kg.ww) > Ni (84.13 ± 46.07 µg/kg.ww) > Cd (67.412 ± 43.93 µg/kg.ww). The concentration of PHEs muscle of male blue crabs and female blue crabs was not significantly different (P-value > 0.05). Uncertainty of non-carcinogenic risk revealed that P95% of total target hazard quotient (TTHQ) in the adult and children consumers due to ingestion male blue crabs was 5.30E-3 and 1.08E-3, respectively, and P95% of TTHQ in the adult and children due to ingestion female blue crabs was 7.05E-3 and 1.20E-3, respectively. P95% of TTHQ in both adult and children consumers was lower than one value. Therefore, consumers are at the acceptable range of the non-carcinogenic risk due to ingestion muscle of male and female blue crabs in Bandar Abbas. Although the non-carcinogenic risk of blue crab was in the safe range, due to the increase in its consumption and the increase of pollution sources in the Persian Gulf, it is recommended to monitor PHEs in Blue's muscle crabs.

Protocol for the estimation of drinking water quality index (DWQI) in water resources: Artificial neural network (ANFIS) and Arc-Gis.

Drinking water sources may be polluted by various pollutants depending on geological conditions and agricultural, industrial, and other human activities. Ensuring the safety of drinking water is, therefore, of a great importance. The purpose of this study was to assess the quality of drinking groundwater in Bardaskan villages and to determine the water quality index. Water samples were taken from 30 villages and eighteen parameters including calcium hardness (CaH), total hardness (TH), turbidity, pH, temperature, total dissolved solids (TDS), electrical conductivity (EC), alkalinity (ALK), magnesium (Mg2+), calcium (Ca2+), potassium (K+), sodium (Na+), sulphate (SO4 2-), bicarbonate (HCO3 -), fluoride (F-), nitrate (NO3 -), nitrite (NO2 -) and chloride (Cl-) were analyzed for the purpose for this study. The water quality index of groundwater has been estimated by using the ANFIS. The spatial locations are shown using GPS. The results of this study showed that water hardness, electrical conductivity, sodium and sulfate in 66, 13, 45 and 12.5% of the studied villages were higher than the Iranian drinking water standards, respectively. Based on the Drinking Water Quality Index (DWQI), water quality in 3.3, 60, 23.3 and 13.3% of villages was excellent, good, poor and very poor, respectively. •Groundwater is one of the sources of drinking water in arid and semi-arid regions such as Bardaskan villages, which monitor the quality of these resources in planning for improving the quality of water resources.•The DWQI can clearly provide information associated with the status of water quality resources in Bardaskan villages.•The results of this study clearly indicated that with appropriate selection of input variables, ANFIS as a soft computing approach can estimate water quality indices properly and reliably.•Some parameters were in the undesirable level is some villages. Therefore, the government should try to improve the chemical and physical quality of drinking water in these areas with the necessary strategies.

Medical waste generation and management in medical clinics in South of Iran.

Medical wastes account for around 1-2% of urban wastes, which are very important in terms of health. In this regard, they are very important and can jeopardize human health. The aim of this study was to determine the qualitative and quantitative characteristics of the wastes in medical clinics in the south of Iran and in order to present suitable management solutions. First, 14 medical clinics were chosen and 24 samples were taken from each clinic (two samples per month) with a total 336 samples. Considering the special properties and the risk potential, the wastes generated in medical clinics were categorized as infections and special waste groups. In terms of properties, they were classified as pseudo-household, infectious, sharp, pharmaceutical, and paper wastes. Once the samples were collected, they were weighed and the results were analyzed by SPSS. The results indicated that in terms of quantity, the waste generated in the first and second groups was 8550.377 and 8053.71 kg/year, respectively. Furthermore, most of the wastes generated in the first and second groups accounted for pseudo-household (80.7%) and infectious (72.77%) wastes, respectively. Due to presence of the specialty of pathology laboratory in the second group, the quantity of infectious waste has increased. Therefore, for proper management of medical wastes in the studied clinics, the clinics of the studied study should implement and apply the rules of waste management properly. Furthermore, training physicians and employees in clinics about reducing, recycling, and collecting wastes in a separate form in clinics should be done in priority. •In this study, the classification of Basel convention and World Health Organization was considered as the basis of waste classification.•The results indicated that in the first group of the studied clinics, the order of the waste quantity was as follows: pseudo-household > infectious > sharp > paper.•Due to large amounts of hazardous infectious wastes in the second group of the studied medical clinics, it necessitates proper management of collection and disposal of these wastes.•Results can be used to improve the management of waste generation practices in medical clinics with high risk and special wastes potential.

The experimental data of investigating the efficiency of zinc oxide nanoparticles technology under ultraviolet radiation (UV/ZnO) to remove Acid - 32 - Cyanine 5R from aqueous solutions.

The aim of this data was to evaluate the efficiency of zinc oxide nanoparticles plus ultraviolet radiation (UV/ZnO) technology to remove Acid - 32 - Cyanine 5R. The effect of optimal parameters including initial pH (5,10), contact time (2-20 min), initial dye concentration (0.5-2 mg/L), and zinc oxide dosage (0.1 and 0.2 g/L) was investigated. The data showed that under alkaline conditions (pH = 10) and 0.2 g/L of ZnO nanoparticles, the maximum dye removal efficiency was observed under UV/ZnO process conditions. Furthermore, with the increase in Acid - 32 - Cyanine 5R dye concentration, the removal efficiency of the dye diminished, while with prolongation of the radiation time, the removal efficiency increased. In the presence of ultraviolet radiation, there is a need to longer time and higher radiation intensity for complete removal of the dye. However, in the presence of ZnO nanoparticles alone, around 5-10% of the dye is removed. The highest removal efficiency of Acid - 32 dye was through radiation by ultraviolet lamp 150 W at an initial dye concentration of 1 mg/L, in pH 5 and 10, respectively, at 98.5% and 99% respectively. On the other hand, through hybrid use of UV/ZnO, within a shorter time, complete removal (100%) is achieved. Generally, use of UV/ZnO process can be utilized as a suitable method for dye wastewaters treatment.

Adsorptive removal of noxious cadmium from aqueous solutions using poly urea-formaldehyde: A novel polymer adsorbent.

Cadmium is a heavy metal toxic that enters water resources through industrial, household, agricultural waste and non-sanitary landfill of urban and industrial wastes. Pollution of water resources by cadmium increases incidence of diseases including Itai-Itai, kidney disorders, cancer, chromosome effects and kidney tubular damages in low exposures. The aim of this study is to study the efficiency of a new poly urea-formaldehyde adsorbent in the removal cadmium ions from aqueous solutions. The effect of different variables such as initial pH, contact time, initial concentration of cadmium and test of real wastewater samples were evaluated. In addition, laboratory data of cadmium adsorption by urea-formaldehyde adsorbent were matched to Langmuir, Freundlich and Temkin isotherm models. The results of the study showed that maximum adsorption capacity obtained by Langmuir model was 76.3 mg/g at pH = 5.5. Laboratory adsorption data matched mostly by Freundlich isotherm model (R2 =0.999) which indicates that adsorption of cadmium ions on heterogenic surfaces of poly urea-formaldehyde happens by chemical adsorption mechanism. Generally, the results of the study showed that new poly urea-formaldehyde adsorbent can be efficiently used to remove highly concentrated cadmium ions from aqueous solutions.

Data on evaluation of AQI for different season in Kerman, Iran, 2015.

The purpose of this data, was to evaluate the air quality index of Kerman city in different season of 2015. The data showed that the PM10 and O3 were highest in the winter season and PM2.5, CO, SO2 and NO2 in the spring season as the air quality indexes. The highest number of unhealthy days was observed in spring in relation to PM2.5 and PM10 pollutants. The data showed that 33 and 9 days of the spring season had unfavorable conditions in relation PM2.5 and PM10 pollutants respectively. Therefore, the pollutant responsible for air pollution in Kerman was PM2.5. By comparing the air quality index in different seasons of 2015 in terms of different pollutants, it was found that in most of the seasons, Kerman has a desirable air quality index.

Data on assessing fluoride risk in bottled waters in Iran.

The general goal of this data was to determine the concentration of fluoride and assess its risk in waters bottled in Iran. Seventy-one samples of different brands of bottled water were collected. Then, the fluoride concentration was measured through standard method for water and wastewater experiments. The non-carcinogenicity risk of fluoride for different groups of infants, children, teenagers, and adults was calculated by proper formula. The data presented here indicated that the mean concentration of fluoride in bottled waters was 0.272 mg/L, which is lower than the minimum world health organization (WHO) guideline. Further, the mean hazard quotient (HQ) values for fluoride across the groups of infants, children, teenagers, and adults with respective values of 0.0363, 0.2568, 0.1813, and 0.1452 were observed in 0, 1, 1, and 0 cases of HQ>1. Generally, in most of the tested brands, HQ value was less than 1, and this value was above 1 in only one brand of bottled water.

Data on quality indices of groundwater resource for agricultural use in the Jolfa, East Azerbaijan, Iran.

The aim of this study was to evaluate the groundwater quality Indices of Groundwater resource for Agricultural Use in jolfa city (Iran) during one decade (2003-2013). Data showed in the first and end year of the study period, the Mean±SD of Sodium Adsorption Ratio (SAR) and Sodium Percentage (Na%) indices 5455.77±3878.02, 3638.69±3565.19 and 51.49±15.65, 41.58±17.69, respectively. The data indicate that the, in terms of sodium percentage and sodium adsorption ratio, the water quality in this area is not suitable for irrigation.

Data on investigating the quantitative and qualitative status of effluent in a petrochemical complex in Iran.

The aim of this data was investigating the quantity and quality of the produced effluent by different petrochemical industry units in Iran and comparison of effluent with the present standards. In the present data, 5 effluent channel of the complex with interval of 12 h (in two shifts) were sampled and 28 physical and chemical parameters were analyzed according to the standard methods. These parameters are pH, Temperature, DO, Conductivity, Color, TDS, TSS, TP, PO43-, Oil, BOD5, COD, Turbidity, TKN, Fe, Ca2+, Mg2+, Cl-, SO42-, Si4+, CO32-, HCO3, NO2-, NO3-, NH3, Na, K+, Mn2+. Then, the average of each parameter was obtained for each channel, and finally, values of these parameters were compared with the standard set by Iranian Environmental Protection Agency for discharge to surface water resources. Gathered Data showed that many of these parameters, including Oil, BOD5, COD, Turbidity, PO43-, SO42-, TSS, in effluent of industrials are higher than the permitted amount. Therefore, regarding discharge of the to the surface water (seawater) and in accordance with Environment Protection Agency standards for effluent disposal, it should be purified to about 90% prior to discharge. Due to high concentration of solutes in petrochemical wastewater, it is not possible to use it for agricultural purpose. In this data, due to ethical considerations, we did not mention the name of petrochemical complex.

Experimental data of designing an optimal system for storage, collection and transfer of household waste in the GIS environment: A case study of Tehran, district 22, Iran.

This study was conducted to correctly manage the system of storage, collection and transfer of wastes in district 22, Tehran. After reviewing existing methods, an optimal system was designed in the GIS environment and appropriate solutions were suggested. Analytical Hierarchy Process (AHP) method was used. After extracting result criteria, these criteria were provided to 15 experts and managers by means of a Delphi questionnaire. Screening of the criteria was done using the criterion importance graph; a necessary condition to apply criteria and sub-criteria, is having at least half the numerical value of each vertical and horizontal vector. The results of the study showed that the most important criterion associated with the selection of waste transfer station is "distance from residential houses" with a final weight of 0.341. "Suitable traffic conditions" and "lack of noise pollution" are the next important criteria with weights of 0.259 and 0.118, respectively. Finally, "non-destruction of recreational facilities" was chosen as the least important (weight of 0.03). Transfer in this district is also 100% mechanized. At the district level, there are 10 garbage trucks, of which 7 collect during night and 3 during day. Given per capita of the district, it takes about 10 min to collect each ton of waste. In general, in order to investigate and plan specific methods in the study district, using Geographic Information System, the location of reservoirs in residential and commercial districts has been determined and suggested with a coefficient of 0.75.

Experimental data on the adsorption of Reactive Red 198 from aqueous solution using Fe3O4 nanoparticles: Optimization by response surface methodology with central composite design.

The aim of this study was to evaluate the efficiency of Fe3O4 nanoparticles for Reactive Red 198 adsorption. The adsorbents were characterized by SEM and XRD. In this dataset, the influence of Reactive Red 198 dye concentration, solution pH, adsorbent dosage, and contact time on Reactive Red 198 dye adsorption by Fe3O4 nanoparticles was tested by central composite design (CCD) under response surface methodology (RSM). The Fe3O4 nanoparticles adsorbent was prepared by chemical co-precipitation. The process efficiency was achieved in optimal conditions including pH=7, adsorbent dosage equal to 0.5 g/L, initial dye concentration of 100 mg/L, contact time equal to 30 min, 88%. Overall, the data offer a facile adsorbent to remove Reactive Red 198 dye from aqueous solutions.

Determination of nitrate concentration and its risk assessment in bottled water in Iran.

Bottled water is one of the sources of drinking water in many arid and semi-arid countries, including Iran. The greatest concern is the health effects of exposure to excessive nitrate concentrations in drinking water due to the development of methemoglobinemia in children. Therefore, the present study was aimed at determining the concentration of nitrate and its risk assessment in drinking water bottled in Iran. 71 different bottled water brands were identified in this study. The nitrate concentration in water samples was then measured using an Ion Chromatography No. 4110 in accordance Standard Methods for the Examination of Water and Wastewater. The hazard quotient (HQ) of nitrate was calculated using the formula based on input variables including nitrate concentration, water per capita, body weight and reference dose. The results showed that the concentration of nitrate in bottled water was in the range of 0.146-50.1 mg/L (average 10.55 mg/L) in one of which, the concentration of nitrate was higher than the WHO guideline. The mean EDI values for nitrate in different groups of infants, children, teenagers and adults were 0.0795, 0.5633, 0.3976 and 0.3186 mg/kg, respectively. The mean HQ values for nitrate in different groups of infants, children, teenagers and adults were 0.0528, 0.3737, 0.2638 and 0.2114, respectively. In general, the hazard quotient (HQ>1) for the population consuming bottled water, appropriate strategies should be considered in order to reduce the concentration of nitrate in bottled water.

Experimental dataset on adsorption of Arsenic from aqueous solution using Chitosan extracted from shrimp waste; optimization by response surface methodology with central composite design.

The aim of data was to evaluate the efficiency of chitosan extracted from shrimp waste for Arsenic adsorption and optimization by response surface methodology (RSM) with central composite design (CCD). The data showed that, with increasing contact time, the amount of adsorption increased and the optimal contact time was about 60 min. With increasing pH decreased adsorption, although this reduction was not significant. The optimum pH was obtained at 4.41. The average amount of adsorbent capacity was also about 1.3 mg/g. Overall, chitosan extracted from shrimp waste could be considered as an efficient material for the adsorption of Arsenic from aqueous solution.

Dataset on comparing the corrosion indices of alum and ferric chloride coagulants with phosphate dose elevation.

The aim of this data was to assess and compare the corrosion indices of alum and ferric chloride coagulants in conventional coagulation process of water with elevation of phosphate dose. After preparing synthetic water samples, jar experiments were performed with elevation of different phosphate doses using alum and ferric chloride coagulants. Then, corrosion indices of Ryznar and Langelier of water samples were calculated. The results indicated that the values of Ryznar and Langelier index in the experimental samples were 7 and less than zero, and the water conditions were under saturated. The corrosion and precipitation indices indicated that the water samples can be considered as corrosive waters.

Dataset on investigating an optimal household waste management in GIS environment and quantitative and qualitative analysis in Bumehen city, Tehran, Iran.

The present data was carried out based on macro policies of the municipality in order to optimize the waste collection and transportation system in the city of Bumehen. The data of this research, the average weights, time taken for collection and transportation of municipal solid waste (MSW) was measured and each of these criteria was calculated and evaluated from environmental and time perspectives under the current management system. Then, data collection, identification of the general characteristics of the region and the type of waste management were conducted using field studies and GIS software was later used to generate maps of classes, route type, per capita waste generation. In the next steps and based on information such as density, population, waste generation capacity, available routes and existing route types, number, type and capacity of tanks, the site of temporary transfer stations was determined and the appropriate routes were designed for the garbage trucks. The data showed that distance from urban space, as a physical criterion, and noise pollution, as an environmental criterion, in the selection of urban waste transfer station of a relative weight of 0.594 is the most important indicator for the construction of a waste transfer station. Also, the qualitative analysis of the dry wastes of the city of Bumehen showed that plastics, cardboard and paper were 8.6%, 8.6% and 8.3% respectively, of the highest amount of waste the city Bumehen formed.