Miniature Optical Fiber Fabry-Perot Interferometer Based on a Single-Crystal Metal-Organic Framework for the Detection and Quantification of Benzene and Ethanol at Low Concentrations in Nitrogen Gas.

This study reports for the first time, to the best of our knowledge, a real-time detection of ultralow-concentration chemical gases using fiber-optic technology, combining a miniaturized Fabry-Perot interferometer (FPI) with metal-organic frameworks (MOFs). The sensor consists of a short and thick-walled silica capillary segment spliced to a lead-in single-mode fiber (SMF), housing a tiny single crystal of HKUST-1 MOF, imparting chemoselectivity features. Ethanol and benzene gases were tested, resulting in a shift in the FPI interference signal. The sensor demonstrated high sensitivity, detecting ethanol gas concentrations (EGCs) with a sensitivity of 0.428 nm/ppm between 24.9 and 40.11 ppm and benzene gas concentrations (BGCs) with a sensitivity of 0.15 nm/ppm between 99 and 124 ppm. The selectivity study involved a combination of three ultralow concentrations of ethanol, benzene, and toluene gases, revealing an enhancement factor of 436% for benzene and 140% for toluene, attributed to the improved miscibility of these conjugated ring molecules with the alkane chains of the ethanol-modified HKUST-1. Experimental tests confirmed the sensor's viability, demonstrating significantly improved response time and spectral characteristics through crystal polishing, indicating its potential for quantifying and detecting chemical gases at ultralow concentrations. This technology may prevent energy resource losses, and the sensor's small size and robust construction make it applicable in confined and hazardous locations.

Calculations of adsorption-dependent refractive indices of metal-organic frameworks for gas sensing applications.

Detection of volatile organic compounds (VOCs) is one of the most challenging tasks in modelling breath analyzers because of their low concentrations (parts-per-billion (ppb) to parts-per-million (ppm)) in breath and the high humidity levels in exhaled breaths. The refractive index is one of the crucial optical properties of metal-organic frameworks (MOFs), which is changeable via the variation of gas species and concentrations that can be utilized as gas detectors. Herein, for the first time, we used Lorentz-Lorentz, Maxwell-Ga, and Bruggeman effective medium approximation (EMA) equations to compute the percentage change in the index of refraction (Δn%) of ZIF-7, ZIF-8, ZIF-90, MIL-101(Cr) and HKUST-1 upon exposure to ethanol at various partial pressures. We also determined the enhancement factors of the mentioned MOFs to assess the storage capability of MOFs and the biosensors' selectivity through guest-host interactions, especially, at low guest concentrations.