1.
Chem Commun (Camb)
; 46(5): 788-90, 2010 Feb 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-20087521
RESUMO
The structure-activity relations in the alumina-supported cobalt catalysts are studied at the realistic conditions of Fischer-Tropsch synthesis using in situ time-resolved XRD and catalytic measurements. Cobalt sintering during the first 3-5 h of the reaction and cobalt carbidisation at a longer time on stream (>8 h) coincide with catalyst deactivation.