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We developed a novel sticker device that can convert any metal or alloy into the working electrode of a three-electrode system, enabling simple and accurate measurement. The sticker, containing a counter electrode and a stable and accurate liquid junction-type reference electrode, is attached to the metal or alloy; meanwhile the surface exposed from a hole in the device functions as the working electrode. This sticker device was fabricated by screen-printing. The polarization curve of the copper and tin-plated copper measured using the sticker device exhibited approximately the same behavior as that obtained for the conventional three-electrode system. The characteristics of various materials can be easily evaluated using this system by only dropping a small amount of solution.
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A novel paper-based biofuel cell with a series/parallel array structure has been fabricated, in which the cell voltage and output power can easily be adjusted as required by printing. The output of the fabricated 4-series/4-parallel biofuel cell reached 0.97±0.02â mW at 1.4â V, which is the highest output power reported to date for a paper-based biofuel cell. This work contributes to the development of flexible, wearable energy storage device.
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The electrochemical properties of screen-printed diamond electrodes with various insulating polyester (PES) resin binder/boron-doped diamond powder (BDDP) ratios were investigated for high sensitivity electrochemical detection. For PES/BDDP weight ratios in the range of 0.3-0.5, the BDDP-printed electrodes exhibited cyclic voltammetry (CV) characteristics for Fe(CN)6(3-/4-) that are typical of a planar electrode, whereas microelectrode-like characteristics with sigmoidal CV curves were observed for PES/BDDP ratios of 1.0-2.0. Cu elemental mapping images of copper-electrodeposited BDDP-printed electrodes indicated the formation of island structures with conductive BDDP domains surrounded by an insulating PES matrix for large PES/BDDP ratios. The electrochemical detection of ascorbic acid (AA) and 8-hydroxy-2'-deoxyguanosine (8-OHdG) was also investigated using polycrystalline BDD thin-film and BDDP-printed electrodes (PES/BDDP ratio = 0.3 and 1.0). As a result, the signal-to-background (S/B) ratios for the voltammetric detection of AA and 8-OHdG were in the order BDDP-printed electrode (PES/BDDP = 1.0) > BDDP-printed electrode (PES/BDDP = 0.3) > polycrystalline BDD thin film electrode, based on the large faradaic current with respect to the background current. Therefore, the BDDP-printed electrode with a large insulating binder/BDDP ratio has the potential for use as a disposable electrode for electrochemical detection. The electrode is cheaper, lighter and more sensitive than conventional BDD electrodes.
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An instantly usable screen-printed paper-based Ag/AgCl electrode was fabricated for use as a cost-effective disposable reference electrode. The reference electrode showed potential stability for approximately 75 h. The setup time, which is less than 1 min, is much shorter than those for similar previously reported electrodes.
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The ATP-induced behavior of the unicellular flagellate alga Chlamydomonas reinhardtii was recorded as changes in the redox currents for a coexisting redox marker. The ATP concentration was estimated using the presented compact electrochemical system, which is based on monitoring of the motility of the flagellates.
Assuntos
Trifosfato de Adenosina/análise , Técnicas Biossensoriais/métodos , Ensaios de Migração Celular/métodos , Chlamydomonas reinhardtii/fisiologia , Técnicas Eletroquímicas/métodos , Movimento Celular , Chlamydomonas reinhardtii/química , Clorófitas/química , Flagelos , Monitorização Fisiológica , Oxirredução , Volvox/fisiologiaRESUMO
We demonstrate a flexible paper-based biofuel cell using porous carbon inks for high power output. The power density of the fabricated biofuel cell reached 0.12 mW cm(-2) (at 0.4 V), which is the highest output power reported to date, to the best of our knowledge.
Assuntos
Fontes de Energia Bioelétrica , Carbono/química , Papel , Impressão , Soluções Tampão , Eletrodos , Glucose/química , PorosidadeRESUMO
Wavelet transformation was applied as a noise elimination method of an amperometric algal biosensor. The drift of the baseline current was clearly removed by using the wavelet transformation. The S/N ratio, calculated by the power spectrum density, is about 3-times larger than that calculated by the current response. The response to a herbicide, atrazine, calculated from the power spectrum density in high-noise circumstance, was the same as that calculated from the current response in a low-noise circumstance.