Peroxymonosulfate activated by composite ceramic membrane for the removal of pharmaceuticals and personal care products (PPCPs) mixture: Insights of catalytic and noncatalytic oxidation.

A composite manganese-based catalytic ceramic membrane (Mn-CCM) was developed by a solid-state sintering method, and its effectiveness toward activation of peroxymonosulfate (PMS) for the degradation of 11 pharmaceutical and personal care products (PPCPs) mixture was tested. The optimized Mn-CCMs/PMS system showed remarkable degradation efficiencies for PPCPs mixture with total removal >90% in ultrapure water, river water and natural organic matter (NOM) solution. The Mn-CCMs/PMS system showed the contribution of different phenomena in PPCPs removal in the order of catalytic oxidation (54.7%, Mn-CCMs/PMS) > noncatalytic oxidation (42.3%, PMS oxidation) > adsorption (3.0%, by Mn-CCMs). The singlet oxygen (1O2) was the dominant reactive oxygen specie for the degradation of PPCPs in all water matrices proved by the quenching experiments and electro-paramagnetic resonance (EPR) spectroscopy. The extraordinary stability of Mn-CCMs for the activation of PMS has been noted in terms of repeatability experiments for PPCPs degradation with fewer leaching of Mn (1.9 to 3.6 µg/L). Mineralization was achieved in the range of 28-65% for different water matrices. The toxicity of the PPCPs mixture was reduced by 85.9%. The Mn-CCMs/PMS system showed a reduction (25-100%) in precursors of different carbon- and nitrogen-based disinfection by-products. This study found the Mn-CCMs/PMS system as a feasible purification unit for removing trace concentrations of PPCPs (ng/L) in real drinking water matrices.

Unraveling dissolved organic matter in drinking water through integrated ozonation/ceramic membrane and biological activated carbon process using FT-ICR MS.

The performance of an integrated process comprising coagulation, ozonation, and catalytic ceramic membrane filtration (CMF) followed by treatment with biological active carbon (BAC) was evaluated in a pilot-scale (96 m3/d) experiment to understand the biostability and quality of the finished water. The fate of dissolved organic matter (DOM) at the molecular level was explored using Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Biostable finished water with an assimilable organic carbon (AOC) concentration of 30.2-45.4 µg/L was obtained by the integrated process, and the high hydraulic retention time (HRT) (≥ 45 min) of the BAC filter was necessary to provide biostable finished water. The coagulation/O3/CMF unit efficiently transformed nitrogen-containing polyaromatic hydrocarbons (PAH) with aromaticity and large molecular weight (Mw) (500-1000 Da) into CHO-type highly unsaturated phenolic compounds (HuPh) with less aromaticity and medium Mw (300-500 Da), which were effectively removed by subsequent BAC filtering. The main reaction was oxygen addition, followed by deamination and dealkylation of the coagulation/O3/CMF unit and decarboxylation of the BAC filter. Principal component analysis revealed that N-containing and large-Mw PAH are potential AOC precursors, and the chemical characteristics of CHO-type and medium-Mw HuPh make them AOC candidates (correlation coefficients > 0.96). This study provides insights into the management of drinking water biostability and its suitability for the practical application of the integrated coagulation/O3/CMF-BAC process in drinking water treatment plants.

Ceramic nanofiber membrane anchoring nanosized Mn2O3 catalytic ozonation of sulfamethoxazole in water.

Catalytic ceramic nanofiber membranes (Mn@CNMs) were prepared by anchoring Mn2O3 nanoparticles on the pits of attapulgite (APT) nanofibers via an impregnation and in-situ precipitation method. An integrated catalytic ozonation/membrane filtration process applying Mn@CNM was employed to degrade sulfamethoxazole (SMX) and the removal achieved up to 81.3% during a 7-h continuous filtration. The reactive oxygen species (ROS) quenching and radical detection experiments were conducted to determine the contribution of 1O2, ·OH and O2·- towards the catalytic degradation of SMX. Moreover, Mn@CNM exhibited wide applicability for real water matrix and the total removal of various kinds of emerging contaminants in real hospital wastewater reached up to 98.5%. The excellent performances of Mn@CNM were attributed to the nano-confinement effect in the membrane layer. First, anchoring Mn2O3 nanoparticles on the pits of the APT surface suppressed the growth and aggregation of nanosized Mn2O3, providing abundant reactive sites for catalytic ozonation. Second, the interlaced APT nanofibers formed nano-sized network structures, where ROS and SMX were confined in close vicinity and ROS have more chances to attack SMX. This work provides a promising strategy for the preparation of catalytic ceramic membrane with high catalytic efficiency for degradation of emerging contaminants in water.

Modeling field scale nitrogen non-point source pollution (NPS) fate and transport: Influences from land management practices and climate.

The use of nitrogen (N) fertilizer marked the start of modern agriculture that boosted food production to help alleviate food shortages across the globe but at the cost of severe environmental issues and critical stress to the agroecosystem. This paper was aimed at determining the fate and transport of nitrite and ammonia under future climate projections by adapting the recommended land management practices that are supposed to reduce nitrate N in surface water to state government target. To accomplish these objectives, a fully-distributed physical-based hydrologic model, MIKE SHE, and a hydrodynamic river model, MIKE 11, were coupled with MIKE ECO-Lab to simulate the fate and transport of different forms of N in the agro-ecosystem in the Upper Sangamon River Basin (USRB). Twelve (12) combinations of land management and climate projections were simulated to evaluate the N fate and transport in the USRB from 2020 to 2050. Under the current land management, the nitrate concentration in surface water was expected to exceed the EPA limit of 10 ppm up to 2.5% of the days in the simulation period. Regulating the fertilizer application rates to approximately 50% of the current rate will ensure this limit will not be exceeded in the future. Implementing cover cropping alone can potentially decrease nitrate N concentrations by 33% in surface water under dry climate and in the saturated zone under future projections. By combining the cover cropping and regulated application rate management, the nitrate N concentration in the saturated zone was expected to decrease by 67% compared with historic baseline. The modeling framework developed and used in this study can help evaluate the effectiveness of different management schemes aimed at reducing future nutrient load in our surface water and groundwater.

Field scale nitrogen load in surface runoff: Impacts of management practices and changing climate.

The use of Nitrogen (N) fertilizer boosted crop production to accommodate 7 billion people on Earth in the 20th century but with the consequence of exacerbating N losses from agricultural landscapes. Land management practices that can prevent high N load are constantly being sought for mitigation and conservation purposes. This study was aimed at evaluating the impacts of different land management practices under projected climate scenarios on surface runoff linked N load at the field scale level. A framework to analyze changes in N load at a high spatiotemporal resolution under high greenhouse emission climate projections was developed using the Pesticide Root Zone Model (PRZM) for the Willow Creek Watershed in the Fort Cobb Experimental Watershed in Oklahoma. Specifically, 12 combinations of land management and climate scenarios were evaluated based on their N load via surface runoff from 2020 to 2070. Results showed that crop rotation practices lowered both the N load and the probability of high N load events. Spring application reduced the negative effects in summer and fall from other land management practices but at the risk of increased probability of generating high N load in April and May. The fertilizer application rate was found to be the most critical factor that affected the amount and the probability of high N load events. By adopting a target application management approach, the monthly maximum N can be decreased by 13% while the annual mean N load by 6%. The model framework and analysis method developed in this research can be used to analyze tradeoffs between environmental welfare and economic benefits of N fertilizer at the field scale level.