Electrically controllable broadband reflective linear cross-polarization conversion based on liquid crystals.

This paper presents an electrically controllable reflective broadband linear polarization (LP) converter based on liquid crystals (LCs) for cross-polarization conversion (CPC) in the terahertz frequency range. The proposed structure achieves a high polarization conversion ratio (PCR) exceeding 0.9 within the frequency range of 236.8 - 269.6 GHz. A vital feature of this design is the dynamic control of polarization conversion by re-orienting the nematic liquid crystal molecules through voltage bias switching between 'on' and 'off' states, allowing for precise manipulation of cross-polarized and co-polarized reflected waves. Experimental results validate the simulation outcomes, demonstrating excellent agreement. In contrast to conventional reflective polarization converters with fixed frequency responses, the proposed electrically controllable polarization conversion offers significant potential in imaging and optical communications.

Manipulation of sub-terahertz waves using digital coding metasurfaces based on liquid crystals.

This paper presents a novel sub-terahertz liquid crystal (LC) phase shifter based on digital coding metasurfaces. The proposed structure consists of metal gratings and resonant structures. They are both immersed in LC. The metal gratings function as reflective surfaces for electromagnetic waves and electrodes for controlling the LC layer. The proposed structure changes the state of the phase shifter by switching the voltage on every grating. It allows the deflection of LC molecules within a subregion of the metasurface structure. Four switchable coding states of the phase shifter are obtained experimentally. The phase of the reflected wave varies by 0°, 102°, 166°, and 233° at 120 GHz. Due to the presence of the transverse control electric field, modulation speed is approximately doubled compared to the free relaxation state. This work provides a novel idea for wavefront modulation of phase.

Rapid terahertz wave manipulation in a liquid-crystal-integrated metasurface structure.

A terahertz phase shifter based on liquid-crystal-integrated metasurface is proposed, which contains a three-slotted array structure and comb grating. The orientation of the liquid crystal molecules can be completely controlled by the direction of the electric field. From the acquired experimental results, it was demonstrated that the phase shift exceeds 300° in the range of 378.6 - 390.8 GHz, whereas the maximum phase shift reaches 374.1° at 383.1 GHz. The molecular reorientation transient process induced by the external electric field in the liquid crystal was measured and analyzed. Based on the molecular reorientation mechanism, which can be divided into three processes, a rapid modulation mechanism was demonstrated. From the performance of the proposed device, an actively controllable phase delay and reflectance with a cycle switching time of approximately 0.3 s was achieved, which is remarkably faster than the usual cycle time that exceeds 8 s. Our work provides useful ideas for improving the response speed of LC-based terahertz devices, which is considered of great significance for several applications, in terms of terahertz reconfigurable devices.

Electrically active control of terahertz waves in a hybrid metasurface-grating structure with a liquid crystal.

A reflective terahertz phase shifter for wide-range dynamic and continuous phase modulation is proposed. By injecting a tunable liquid crystal between the slotted metasurface and the grating microstructure, the phases of reflected waves can be modulated with different electrically driven methods. Numerical simulations show that the proposed terahertz phase shifter has a phase difference of more than 360° between unbiased and biased states. Furthermore, an array of 35×35 patch elements was designed and fabricated. The performance of the phase shifter provides more than 360° between 379.6 and 391.8 GHz, where the maximum phase shift reaches 422.4° at 385.9 GHz. Moreover, the fully electrically controlled phase modulation of more than 180° is achieved between 382.0 and 394.1 GHz, with a maximum phase modulation of 248.4° at 383.3 GHz. This work may provide a reflective terahertz phase modulator for beam steering.

Liquid crystal-based wide-angle metasurface absorber with large frequency tunability and low voltage.

A tunable metasurface absorber (MA) based on polymer network liquid crystal is introduced in this paper. Despite the well-designed unit cell patterns, the proposed MA can achieve both large frequency tunability and wide-angle stability. Compared with traditional liquid crystal-based metasurfaces, the measured results suggest that the recovery time of the proposed structure was reduced by half. By applying an external voltage on the top electrode of the liquid crystal layer from 0 to a saturation voltage of 10 V, the absorption peak of the MA can be tuned from 112.7 GHz to 102.2 GHz, with a maximum frequency tunability of 9.3%, which is significantly higher than other proposed liquid crystal-based metasurfaces. Moreover, the proposed tunable absorber can maintain absorption greater than 90% with incident angles reaching up to 60° for both transverse electric and transverse magnetic polarizations. This design provides an efficient way for developing low-power consumption terahertz devices with large frequency tunability and wide-angle stability.

Preparation of Eu0.075Tb0.925-Metal Organic Framework as a Fluorescent Probe and Application in the Detection of Fe3+ and Cr2O72.

Luminescent Ln-MOFs (Eu0.075Tb0.925-MOF) were successfully synthesised through the solvothermal reaction of Tb(NO3)3·6H2O, Eu(NO3)3·6H2O, and the ligand pyromellitic acid. The product was characterised by X-ray diffraction (XRD), TG analysis, EM, X-ray photoelectron spectroscopy (XPS), and luminescence properties, and results show that the synthesised material Eu0.075Tb0.925-MOF has a selective ratio-based fluorescence response to Fe3+ or Cr2O72-. On the basis of the internal filtering effect, the fluorescence detection experiment shows that as the concentration of Fe3+ or Cr2O72- increases, the intensity of the characteristic emission peak at 544 nm of Tb3+ decreases, and the intensity of the characteristic emission peak at 653 nm of Eu3+ increases in Eu0.075Tb0.925-MOF. The fluorescence intensity ratio (I653/I544) has a good linear relationship with the target concentration. The detection linear range for Fe3+ or Cr2O72- is 10-100 µM/L, and the detection limits are 2.71 × 10-7 and 8.72 × 10-7 M, respectively. Compared with the sensor material with a single fluorescence emission, the synthesised material has a higher anti-interference ability. The synthesised Eu0.075Tb0.925-MOF can be used as a highly selective and recyclable sensing material for Fe3+ or Cr2O72-. This material should be an excellent candidate for multifunctional sensors.

A procedure and device for determining complex material permittivity using the free-space resonance method.

The essential technologies of the complex permittivity of microwave dielectric materials are systematically designed, and the complex permittivity of materials is tested nondestructively by the free-space resonance method. A testing system was built by using a mobile surveying platform, and the complex dielectric constant of the material in the X band was nondestructively tested by using the algorithm of variable physical cavity length and constant physical cavity length. Focusing on the impact of variable physical cavity length on the test results, the cavity calibration technology is proposed to reduce the influence on the complex dielectric constant test of materials. The free-space resonance method was used to test the complex permittivity of polytetrafluoroethylene, glass steel plate (fiber reinforced plastics), and corundum plate. The results show that the test results of complex permittivity obtained by the two algorithms are consistent, and the error of complex permittivity is less than 5%.

Submillisecond-Response Polymer Network Liquid Crystal Phase Modulators.

A submillisecond-response and light scattering-free polymer-network liquid crystal (PNLC) for infrared spatial light modulators is demonstrated. Our new liquid crystal host exhibits a higher birefringence, comparable dielectric anisotropy, and slightly lower visco-elastic constant than a commonly employed commercial material, HTG-135200. Moreover, the electro-optical performance of our PNLCs with different monomer concentrations, cell gaps, and liquid crystal (LC) hosts is compared and discussed from four aspects: operating voltage, hysteresis, relaxation time, and light scattering loss. The temperature effect on hysteresis is also analyzed. Potential applications of PNLCs for laser beam steering and spatial light modulators especially in the infrared region are foreseeable.

Coumarin-Modified Graphene Quantum Dots as a Sensing Platform for Multicomponent Detection and Its Applications in Fruits and Living Cells.

In this work, coumarin derivatives (C) are used to enhance the fluorescence of graphene quantum dots (GQDs) by covalently linking the carboxyl groups on the edge of the GQD sheet. The as-synthesized coumarin-modified graphene quantum dots (C-GQDs) have a uniform particle size with an average diameter of 3.6 nm. Simultaneously, the C-GQDs have strong fluorescence emission, excellent photostability, and high fluorescence quantum yield. C-GQDs and CN- can form a C-GQDs+CN- system due to deprotonation and/or intermolecular interactions. The introduced hydroquinone (HQ) is oxidized to benzoquinone (BQ), and the interaction between BQ and the C-GQDs+CN- system could lead to fluorescence enhancement of C-GQDs. Meanwhile, the redox reaction between BQ and ascorbic acid (AA) can be used for quantitative detection of AA with CN- and HQ being used as substrates. Based on the above mechanism, C-GQDs are developed as a multicomponent detection and sensing platform, and the detection limits for CN-, HQ, and AA were 4.7, 2.2, and 2.2 nM, respectively. More importantly, satisfactory results were obtained when the platform was used to detect CN-, HQ, and AA in living cells and fresh fruits.

Two-dimensional liquid crystal polarization grating via linearly polarized light modified multi-beam polarization interferometry.

Holographic lithography is widely used as an effective approach for two-dimensional (2D) photonic crystal fabrication. However, for the fabrication of 2D polarization structures based on photoaligned liquid crystals (LCs), holographic lithography method is limited. The fabrication requires full coverage of light intensity, 2D chiral distribution and continuously varying polarization direction, which could be hardly guaranteed by multi-beam interference of circularly polarized light (CPL). Herein, we introduce a linearly polarized light (LPL) into a three-CPL interference configuration to improve the interference field and fulfill the critical requirement. The introduced LPL intensity is chosen to be 1/5 of the CPL to guarantee both full coverage of light intensity and well photoalignment defined LC directors. Moreover, the introduction of the weak LPL into multiple CPL interference is shown to give little disturbance to the desired diffraction properties.

Submillisecond-response polymer network liquid crystals for mid-infrared applications.

We formulated a high birefringence, large dielectric anisotropy, UV stable, and low absorption loss nematic liquid crystal mixture, named UCF-15, for mid-wave infrared (MWIR) applications. To achieve fast response time, we fabricated a polymer network liquid crystal (PNLC) using UCF-15 as host. At 40°C operating temperature, our PNLC shows 2π phase change at λ = 4 µm, submillisecond response time, and over 98% transmittance in the 3.8 to 5.1 µm region. Potential applications of this PNLC phase modulator for high speed laser beam steering, adaptive optics, and optical tweezer are foreseeable.

Photoalignment-induced two-dimensional liquid crystal polarization structure via multi-beam polarization interferometry.

A two-dimensional (2D) pure polarization pattern via four-beam polarization interferometry of circularly polarized beams is demonstrated both theoretically and experimentally. The polarization orientation of the interference pattern is recorded by an azobenzene photoalignment layer and transferred to liquid crystal (LC), enabling the fabrication of a 2D liquid crystal (LC) chiral structure. This structure behaves as a 2D LC polarization grating (LCPG) that can generate multiple polarization-selective diffraction beams of orthogonal polarization states with high efficiency. This 2D LCPG provides an effective way to distribute an optical signal into multiple receivers by both incidence polarization control and external electric field, therefore offering potential applications on multi-channel optical communication and information processing.

Decarboxylative substitution of ß-keto acids to benzylic alcohols catalyzed by molecular iodine.

An efficient method for molecular iodine catalyzed decarboxylative substitution of ß-keto acids with benzylic alcohols under mild conditions has been described and valuable α-functionalized ketones were obtained in good to excellent yields.

A computational method for predicting regulation of human microRNAs on the influenza virus genome.

BACKGROUND: While it has been suggested that host microRNAs (miRNAs) may downregulate viral gene expression as an antiviral defense mechanism, such a mechanism has not been explored in the influenza virus for human flu studies. As it is difficult to conduct related experiments on humans, computational studies can provide some insight. Although many computational tools have been designed for miRNA target prediction, there is a need for cross-species prediction, especially for predicting viral targets of human miRNAs. However, finding putative human miRNAs targeting influenza virus genome is still challenging. RESULTS: We developed machine-learning features and conducted comprehensive data training for predicting interactions between H1N1 genome segments and host miRNA. We defined our seed region as the first ten nucleotides from the 5' end of the miRNA to the 3' end of the miRNA and integrated various features including the number of consecutive matching bases in the seed region of 10 bases, a triplet feature in seed regions, thermodynamic energy, penalty of bulges and wobbles at binding sites, and the secondary structure of viral RNA for the prediction. CONCLUSIONS: Compared to general predictive models, our model fully takes into account the conservation patterns and features of viral RNA secondary structures, and greatly improves the prediction accuracy. Our model identified some key miRNAs including hsa-miR-489, hsa-miR-325, hsa-miR-876-3p and hsa-miR-2117, which target HA, PB2, MP and NS of H1N1, respectively. Our study provided an interesting hypothesis concerning the miRNA-based antiviral defense mechanism against influenza virus in human, i.e., the binding between human miRNA and viral RNAs may not result in gene silencing but rather may block the viral RNA replication.

Preparation and structures of enantiomeric dinuclear zirconium and hafnium complexes containing two homochiral N atoms, and their catalytic property for polymerization of rac-lactide.

The hydroxy- and phenoxy-bridged dinuclear zirconium and hafnium complexes and of an amine-pyridine-bis(phenolate) ligand (H(2)L) were prepared from the reaction of Na(2)L and ZrCl(4) in the presence of 0.5 equiv of water in THF, while the reaction of H(2)L with NaH and then with ZrCl(4) in the freshly distilled THF gave an eight-coordinate bis(homoleptic) mononuclear complex L(2)Zr (). Two homochiral N atoms were created in each complex upon coordination of the unsymmetric tertiary amine ligands to the metal centers. Enantiomeric dinuclear complexes and both undergo spontaneous resolution during crystallization. The molecular structure of each enantiomer of and , as well as the structure of , was determined by X-ray analysis and the circular dichroism spectra of N(R)N(R)- and N(S)N(S)- were studied. The racemates of and catalyzed controlled polymerization of rac-lactide in terms of the linearity of molecular weight versus conversion, forming isotactic-rich polylactide in high yields with a narrow polydispersity.