Phosphate adsorption characteristics of CeO2-loaded, Eucommia ulmoides leaf residue biochar.

In this study, a Ce-loading biochar (Ce-BC) was synthesized by the optimal modification method of pre-pyrolysis impregnation, a pyrolysis temperature at 600 °C, and a CeCl3 concentration of 1.00 mol L-1 for efficient adsorption phosphorus (P) from wastewater. The results revealed that Ce-BC could achieve a maximum P removal rate of 100% under specific conditions: an adsorbent concentration of 2.00 g L-1, an initial solution pH of 3.00, an adsorption temperature of 25 °C, and an initial P concentration of 20.00 mg L-1. The adsorption process followed the quasi-secondary kinetic model, suggesting the Ce-BC was particularly effective in acidic environments. Meanwhile, Ce-BC has a strong resistance to anion interference and good cycling performance (the P adsorption capacity of Ce-BC was 59.77% of its initial value after four cycles). Field emission scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) indicated that Ce-BC contained a porous structure and rich functional groups (hydroxyl and carboxyl), and compounds of CeO2 and MgCeO3 were formed. The Ce loading favored the exchange with P through ligands, inner-sphere complexation, ion exchange, and electrostatic interaction to form inner-sphere complex-cerium P (CePO4), and the surface complex of Ce-O-P replaced O-H. In addition, the Ce-BC adsorption columns substantially affected P removal in actual wastewater. Overall, Ce-BC is a promising material for the treating P-containing acidic wastewater.

Effective Non-Radiative Interfacial Recombination Suppression Scenario Using Air Annealing for Antimony Triselenide Thin-Film Solar Cells.

Antimony triselenide (Sb2Se3) has become a very promising candidate for next-generation thin-film solar cells due to the merits of their low-cost, low-toxic and excellent optoelectronic properties. Despite Sb2Se3 thin-film photovoltaic technology having undergone rapid development over the past few years, insufficient doping concentration and severe recombination have been the most challenging limitations hindering further breakthroughs for the Sb2Se3 solar cells. Post-annealing treatment of the Sb2Se3/CdS heterojunction was demonstrated to be very helpful in improving the device performance previously. In this work, post-annealing treatments were applied to the Sb2Se3/CdS heterojunction under a vacuum and in the air, respectively. It was found that compared to the vacuum annealing scenario, the air-annealed device presented notable enhancements in open-circuit voltage. Ultimately a competitive power conversion efficiency of 7.62% was achieved for the champion device via air annealing. Key photovoltaic parameters of the Sb2Se3 solar cells were measured and the effects of post-annealing treatments using different scenarios on the devices were discussed.

Norfloxacin adsorption by urban green waste biochar: characterization, kinetics, and mechanisms.

Biochar, as a potential adsorbent, has been widely employed to remove pollutants from sewage. In this study, a lignin-based biochar (CB-800) was prepared by a simple high-temperature pyrolysis using urban green waste (Cinnamomum camphora leaves) as a feedstock to remove norfloxacin (NOR) from water. Batch adsorption test results indicated that CB-800 had a strong removal capacity for NOR at a wide range of pH values. The maximum adsorption achieved in the study was 50.90 ± 0.64 mg/g at 298 K. The pseudo-first and second-order kinetic models and the Dubinin-Radushkevich isotherm fitted the experimental data well, indicating that NOR adsorption by CB-800 was a complex process involving both physi-sorption and chemi-sorption. The physical properties of CB-800 were characterized by SEM and BET. The mesoporous structures were formed hierarchically on the surface of CB-800 (with an average pore size of 2.760 nm), and the spatial structure of NOR molecules was more easily adsorbed by mesoporous structures. Combined with Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis, it was showed that the main NOR adsorption mechanisms by CB-800 included ion exchange, π-electron coordination, hydrogen bonding, and electrostatic adsorption. Meanwhile, the reduction of C = O and pyridine nitrogen, and the presence of C-F2, also indicated the occurrence of substitution, addition, and redox. This study not only determined the reaction mechanism between biochar and NOR, but also provides guidance to waste managers for the removal of NOR from water by biochar. It is envisaged that the results will broaden the utilization of urban green waste.

Enhancement of Fenton processes at initial circumneutral pH for the degradation of norfloxacin with Fe@FeS core-shell nanowires.

The disadvantages of narrow working pH range (2.5-4.0), accumulation of iron sludge and incomplete degradation have hindered the practical application of the traditional homogeneous Fenton technique. In this research, Fe@FeS core-shell nanowires were synthesised and the innovative Fe@FeS/Fe2+/H2O2 system was adopted for norfloxacin (NOR) degradation at an initial circumneutral pH. More than 95% NOR has been removed in the Fe@FeS/Fe2+/H2O2 system within 30 min at pH 7. After investigating the concentration change of total iron, Fe2+ and H2O2 during the degradation process, NOR degradation in the Fe@FeS/Fe2+/H2O2 system might be attributed to the combined effect of homogeneous Fenton reaction and heterogeneous Fenton process. Besides that, the added Fe@FeS has accelerated Fe3+/Fe2+ redox cycle with extremely high degree. The generated reactive ●OH has been identified by electron paramagnetic resonance spectrometer results, possible degradation intermediates have also been proposed according to Gas chromatography-mass spectrometry analysis results. Moreover, Fe@FeS core-shell nanowires showed excellent reusability, it is a promising heterogeneous Fenton catalyst that is applicable for practical application.

[Anti-interference hemoglobin analysis system by high performance liquid chromatography].

High performance liquid chromatography (HPLC) is currently the mainstream technology for detecting hemoglobin. Glycated hemoglobin (HbA1c) is a gold indicator for diagnosing diabetes, however, the accuracy of HbA1c test is affected by thalassemia factor hemoglobin F (HbF)/hemoglobin A2 (HbA2) and variant hemoglobin during HPLC analysis. In this study, a new anti-interference hemoglobin analysis system of HPLC is proposed. In this system, the high-pressure three-gradient elution method was improved, and the particle size and sieve plate aperture in the high-pressure chromatography column and the structure of the double-plunger reciprocating series high-pressure pump were optimized. The system could diagnose both HbA1c and thalassemia factor HbF/HbA2 and variant hemoglobin, and the performance of the system was anti-interference and stable. It is expected to achieve industrialization. In this study, the HbA1c and thalassemia factor HbF/HbA2 detection performance was compared between this system and the world's first-line brand products such as Tosoh G8, Bio-Rad Ⅶ and D10 glycosylated hemoglobin analysis system. The results showed that the linear correlation between this system and the world-class system was good. The system is the first domestic hemoglobin analysis system by HPLC for screening of HbA1c and thalassemia factor HbF/HbA2 rapidly and accurately.

High-efficiency degradation of p-arsanilic acid and arsenic immobilization with iron encapsulated B/N-doped carbon nanotubes at natural solution pH.

p-arsanilic acid (p-ASA) is still widely applied as feed additive in many countries. Accompanied with chemical reactions in the environment, p-ASA will release more toxic inorganic arsenic. In order to safely and efficiently treat p-ASA flow washing into the environment, iron encapsulated B/N-doped carbon nanotubes (Fe@C-NB) were fabricated and used as the catalyst for the degradation of p-ASA. The calcination temperature and the dose of the iron salt have significant effects on the structure and properties of the catalysts. We have produced a series of catalysts of the same type to facilitate the degradation of p-ASA. Under optimal conditions of material (Fe@C-NB) syntheses, both 95% degradation of p-ASA and 86% total arsenic immobilization can be obtained with oxidant (Peroxymonosulfate, PMS) and catalyst (Fe@C-NB) treatment after 60 min. The effects of oxidant types (peroxydisulfate (PDS), PMS, hydrogen peroxide (H2O2)), amount, initial solution pH, inorganic anion, and other reaction conditions were studied in the p-ASA removal. In this Fenton-like reaction, the Fe@C-NB exhibits high efficiency and excellent stability without complex preparation methods; besides, the advantages of short reaction time and natural reaction conditions in Fe@C-NB/PMS system will promote the practical application of Fenton-like.

Fabrication of sustainable manganese ferrite modified biochar from vinasse for enhanced adsorption of fluoroquinolone antibiotics: Effects and mechanisms.

An effective adsorbent towards fluoroquinolone antibiotics was synthesized via a facile two-step approach, the co-precipitation of Fe, Mn with vinasse wastes and then pyrolysis under controlled conditions which denoted as FMB. Its adsorption behavior was examined based on a batch adsorption experiment of fluoroquinolone antibiotics pefloxacin (PEF) and ciprofloxacin (CIP). Experimental factors, such as pH, adsorbent dose, ionic strength, contact time and temperature have done a great deal to influence the adsorption of PEF and CIP. The FMB demonstrated excellent performance in reusability tests towards to both PEF and CIP, which showed that the recycling efficiency of PEF and CIP could remain ~55% and ~80% after five recycle cycles, respectively. The dominated adsorption mechanisms included pore filling effect, π-π stacking interaction, π-π EDA, hydrogen bonding and hydrophobicity. Overall, this work presented FMB was recognized as an effective, environmental-friendly and magnetically separable adsorbent for alleviating fluoroquinolone antibiotics contamination from water.

Enhanced degradation of 1-naphthol in landfill leachate using Arthrobacter sp.

Arthrobacter sp. named as JY5-1 isolated from contaminated soil of a coking plant can degrade 1-naphthol as the sole carbon source. Through identification of species, analysis of the optimal degradation condition and kinetic equation, the degradation characteristic of Arthrobacter sp. JY5-1 was obtained. Later, the acclimated strain was added into the bio-reactor to observe treatment performance of landfill leachate. The results showed that the optimal conditions for strain JY5-1 biodegradation in the study were pH 7.0 and 30oC. The bio-reactor operation experiment declared that Arthrobacter sp. JY5-1 had a strengthened effect on COD removal of landfill leachate. Moreover, the efficiency of COD removal could be high and stable when JY5-1 was accumulated as a biofilm together with active sludge. These results demonstrate that adding 1-naphthol-degrading strain JY5-1 is a feasible technique for the enhanced treatment of sanitary landfill leachate, providing theoretical support for engineering utilization.

Enhancement of Fenton processes at initial circumneutral pH for the degradation of norfloxacin with Fe@Fe2O3 core-shell nanomaterials.

The degradation of norfloxacin by Fenton reagent with core-shell Fe@Fe2O3 nanomaterials was studied under neutral conditions in a closed batch system. Norfloxacin was significantly degraded (90%) in the Fenton system with Fe@Fe2O3 in 30 min at the initial pH 7.0, but slightly degraded in Fenton system without Fe@Fe2O3 under the same experimental conditions. The intermediate products were investigated by gas chromatography-mass spectrometry, and the possible Fenton oxidation pathway of norfloxacin in the presence of Fe@Fe2O3 nanowires was proposed. Electron spin resonance spectroscopy was used to identify and characterize the free radicals generated, and the mechanism for norfloxacin degradation was also revealed. Finally, the reusability and the stability of Fe@Fe2O3 nanomaterials were studied using x-ray diffraction and scanning electron microscope, which indicated that Fe@Fe2O3 is a stable catalyst and can be used repetitively in environmental pollution control.

Aromatic organoarsenic compounds (AOCs) occurrence and remediation methods.

Many researchers at home and abroad have made a body of researches and have gained great achievements on the environmental occurrence, fate, and toxicity of inorganic arsenic. But there is less research on the use of aromatic organoarsenic compounds (AOCs), which are common feed additives for livestock in the poultry industry. In this review, we outline the current state of knowledge acquired on the occurrence and remediation of AOCs, respectively. We also identify knowledge gaps and research needs, including the elucidation of the environmental fate of AOCs, metabolic pathway, the impact of metabolic modification on toxicity, and advanced analytical or repaired methods that allows for monitoring, identification or removal of the degradation products.

The study of a pilot-scale aerobic/Fenton/anoxic/aerobic process system for the treatment of landfill leachate.

In this study, a combined aerobic-Fenton-anoxic/aerobic system was designed for the remediation of raw landfill leachate in a pilot-scale experiment. This system included (i) a granular sludge biological oxidation procedure that achieves the accumulation of nitrite nitrogen ([Formula: see text]) under aerobic conditions; (ii) a Fenton process that improves the biodegradability of the biotreated leachate and (iii) an activated sludge biological oxidation component under anoxic and aerobic conditions. Additionally, a shortcut nitrification and denitrification pathway was achieved. The effects of free ammonia, temperature and pH on nitrite accumulation were discussed. The change in the biochemical oxygen demand/chemical oxygen demand ratio of the effluent after shortcut nitrification was also analysed. The microbial community in the reactor were also investigated. The problem of the lack of carbon source in the denitrification process can be solved by the Fenton reagent method. Moreover, it was beneficial to achieving nitrogen removal as well as the more extensive removal of organic matter. The treatment strategy employed in this study exhibited good results and provided the potential practical application for treating landfill leachate.

Structure and dysprosium dopant engineering of gadolinium oxide nanoparticles for enhanced dual-modal magnetic resonance and fluorescence imaging.

We report a class of multi-functional core-shell nanoarchitectures, consisting of silica nanospheres as the core and Gd2O3:Dy3+ nanocrystals as the ultra-thin shell, that enable unique multi-color living cell imaging and remarkable in vivo magnetic resonance imaging. These types of targeted cell imaging nanoarchitectures can be used as a variety of fluorescence nanoprobes due to the multi-color emissions of the Gd2O3:Dy3+ nanophosphor. We also proposed a strategy of modulating core-shell structure design to achieve an enhanced magnetic resonance contrast ability of Gd2O3 nanoagents, and the classical Solomon-Bloembergen-Morgan theory was applied to explicate the mechanism underlying the enhancement. The as-synthesized ligand-free nanomaterial possesses a suitable particle size for cellular uptake as well as avoiding penetrating the blood-brain barrier with good water-solubility, stability, dispersibility and uniformity. The extremely low cytotoxicity and favorable biocompatibility obtained from in vitro and in vivo bioassays of the as-designed nanoparticles indicate their excellent potential as a candidate for functioning as a targeted nanoprobe.

High sensitivity of gold nanoparticles co-doped with Gd2O3 mesoporous silica nanocomposite to nasopharyngeal carcinoma cells.

Nanoprobes for combined optical and magnetic resonance imaging have tremendous potential in early cancer diagnosis. Gold nanoparticles (AuNPs) co-doped with Gd2O3 mesoporous silica nanocomposite (Au/Gd@MCM-41) can produce pronounced contrast enhancement for T1 weighted image in magnetic resonance imaging (MRI). Here, we show the remarkably high sensitivity of Au/Gd@MCM-41 to the human poorly differentiated nasopharyngeal carcinoma (NPC) cell line (CNE-2) using fluorescence lifetime imaging (FLIM). The upconversion luminescences from CNE-2 and the normal nasopharyngeal (NP) cells (NP69) after uptake of Au/Gd@MCM-41 show the characteristic of two-photon-induced-radiative recombination of the AuNPs. The presence of the Gd3+ ion induces a much shorter luminescence lifetime in CNE-2 cells. The interaction between AuNPs and Gd3+ ion clearly enhances the optical sensitivity of Au/Gd@MCM-41 to CNE-2. Furthermore, the difference in the autofluorescence between CNE-2 and NP69 cells can be efficiently demonstrated by the emission lifetimes of Au/Gd@MCM-41 through the Forster energy transfers from the endogenous fluorophores to AuNPs. The results suggest that Au/Gd@MCM-41 may impart high optical resolution for the FLIM imaging that differentiates normal and high-grade precancers.

Hydrothermal synthesis of core-shell structured TbPO4:Ce(3+)@TbPO4:Gd(3+) nanocomposites for magnetic resonance and optical imaging.

Multi-modal imaging based on multifunctional nanoparticles provides deep, non-invasive and highly sensitive imaging and is a promising alternative approach that can improve the sensitivity of early cancer diagnosis. In this study, two nanoparticles, TbPO4:Ce(3+) and TbPO4:Ce(3+)@TbPO4:Gd(3+), were synthesized via the citric-acid-mediated hydrothermal route, and then systematically characterized by means of microstructure, photoluminescence, magnetic resonance imaging (MRI), biocompatibility, and bioimaging. The results of energy dispersive X-ray spectroscopy (EDS) and electron energy loss spectroscopy (EELS) line scans indicated that TbPO4:Gd(3+) nanoshells about 5 nm in thickness were successfully coated on the TbPO4:Ce(3+) nanocores. X-ray diffraction (XRD) and Fourier transforms of high-resolution transmission electron microscopy (TEM) images indicated that the core-shell nanocomposites had a single crystal structure. The photoluminescence of the TbPO4:Ce(3+)@TbPO4:Gd(3+) and TbPO4:Ce(3+) nanoparticles was greatly intensified by 200 times and 100 times, respectively, compared with pure TbPO4 nanoparticles. In vitro cytotoxicity tests based on the methyl thiazolyl tetrazolium (MTT) assay demonstrated that the monodispersed nanoparticles of TbPO4:Ce(3+)@TbPO4:Gd(3+) had low toxicity. The intracellular luminescence of the nanoparticles after being internalized by HeLa cells was also observed using confocal fluorescence microscopes. MRI showed that the nanoshells of Gd-doped TbPO4 possessed a longitudinal relaxivity of 4.067 s(-1) mM(-1), which is comparable to that of the commercial MRI contrast Gd-TDPA. As a result, the core-shell structured TbPO4:Ce(3+)@TbPO4:Gd(3+) nanoparticles can potentially serve as multifunctional nanoprobes for both optical biolabels and MRI contrast agents.

Evaluation of breast cancer chemotherapy efficacy with multifractal spectrum analysis of magnetic resonance image.

Multifractal spectrum analysis of dynamic contrast enhanced (DCE) breast MR images was used to establish a new quantitative analysis method for solid tumor blood perfusion and to explore its applicability in evaluating efficacy of breast cancer chemotherapy. Five randomly selected patients suffering from newly diagnosed malignant breast nodule lesions were enrolled in this study, and four of them were treated with neoadjuvant chemotherapy. Their DCE breast MR images were collected before and after treatment. Chemotherapeutic efficacy was analyzed using international response evaluation criteria for solid tumors (RECIST). Sandbox method for statistical number density was employed to measure and calculate multifractal spectra of DCE breast MR images with spatiotemporal characteristics. Multifractal spectral data of malignant lesions before and after chemotherapy were compared. Multifractal spectra of malignant lesions show an asymmetric bell-shape. Chemotherapy efficacy was assessed to be partial remission (PR) for three patients and their multifractal spectral width significantly increased after chemotherapy while to be stable disease (SD) for other patient and of her changed slightly. Multifractal spectral width correlates with blood-supply condition of tumor lesion before and after chemotherapy, providing a potential suitable characteristic parameter for evaluating chemotherapeutic efficacy quantitatively.

An evaluation of the effectiveness of novel industrial by-products and organic wastes on heavy metal immobilization in Pb-Zn mine tailings.

The in situ immobilization of heavy metals using various easily obtainable amendments is a cost-effective and practical method in the remediation of contaminated sites. In this study, two novel industrial waste materials (sweet sorghum vinasse and medicinal herb residues), spent mushroom compost and municipal solid wastes were used as amendments to assess their potential value for the in situ immobilization of heavy metals in tailings from a Pb-Zn mine in South China. Our results demonstrate that all three freely-available organic wastes decrease the deionized water (DW)- and diethylene-triamine-pentaacetic acid (DTPA)-extractable metal concentrations, enhance the enzyme activity, reduce the metal concentration in plant tissues, and could be used for the remediation of these Pb-Zn mine tailings metals by immobilization. The municipal solid waste failed to reduce the metal concentration in tailings and plant tissues and therefore would not be a suitable immobilizing agent. The potential value of these materials as immobilizers of heavy metals and their remediation efficacy deserve further studies in large-scale field trials.

Ligand-free gadolinium oxide for in vivo T1-weighted magnetic resonance imaging.

Gadolinium oxide (Gd2O3), which can be used as a T1-weighted magnetic resonance imaging (MRI) contrast agent, has attracted intense attention in recent years. In this paper, ligand-free monoclinic Gd2O3 nanocrystals of 7.1 nm in diameter are synthesized by a simple and green approach, namely microsecond laser ablation of a gadolinium (Gd) target in deionized water. These nanocrystals obtain high r1 relaxivity of 5.53 s(-1) mM(-1), and their low toxicity was demonstrated by the cell viability of S18 cells and apoptosis in RAW264.7 cells. In vitro and in vivo MR images show these particles to be good T1-weighted MRI contrast agents. Base on the experimental results and theoretical analysis, we suggest that the purity of the Gd2O3 contributes to its high r1 relaxivity value, while the low toxicity is due to its good crystallinity. These findings show that laser ablation in liquid (LAL) is a promising strategy to synthesize ligand-free monoclinic Gd2O3 nanocrystals for use as high efficient T1-weighted MRI contrast agents.

Computerized segmentation and characterization of breast lesions in dynamic contrast-enhanced MR images using fuzzy c-means clustering and snake algorithm.

This paper presents a novel two-step approach that incorporates fuzzy c-means (FCMs) clustering and gradient vector flow (GVF) snake algorithm for lesions contour segmentation on breast magnetic resonance imaging (BMRI). Manual delineation of the lesions by expert MR radiologists was taken as a reference standard in evaluating the computerized segmentation approach. The proposed algorithm was also compared with the FCMs clustering based method. With a database of 60 mass-like lesions (22 benign and 38 malignant cases), the proposed method demonstrated sufficiently good segmentation performance. The morphological and texture features were extracted and used to classify the benign and malignant lesions based on the proposed computerized segmentation contour and radiologists' delineation, respectively. Features extracted by the computerized characterization method were employed to differentiate the lesions with an area under the receiver-operating characteristic curve (AUC) of 0.968, in comparison with an AUC of 0.914 based on the features extracted from radiologists' delineation. The proposed method in current study can assist radiologists to delineate and characterize BMRI lesion, such as quantifying morphological and texture features and improving the objectivity and efficiency of BMRI interpretation with a certain clinical value.

Regulation of Turing patterns in a spatially extended chlorine-iodine-malonic-acid system with a local concentration-dependent diffusivity.

A chlorine-iodine-malonic-acid Turing system involving a local concentration-dependent diffusivity (LCDD) has fundamental significance for physical, chemical, and biological systems with inhomogeneous medium. We investigated such a system by both numerical computation and mathematical analysis. Our research reveals that a variable local diffusivity has an evident effect on regulating the Turing patterns for different modes. An intrinsic square-root law is given by λ ∼ (c(1)+c(2)k)(1/2), which relates the pattern wavelength (λ) with the LCDD coefficient (k). This law indicates that the system pattern has the properties of an equivalent Turing pattern. The current study confirms that, for the Turing system with LCDD, the system pattern form retains the basic characteristics of a traditional Turing pattern in a wide range of LCDD coefficients.

The properties of Gd2O3-assembled silica nanocomposite targeted nanoprobes and their application in MRI.

The feasibility of the gadolinium-doped mesoporous silica nanocomposite Gd(2)O(3)@MCM-41 as a safe, effective MRI nanoprobe has been validated in the current investigation systematically from atomistic and molecular modeling to its synthesis and characterization on in vivo MR imaging and biocompatibility. The first-principles calculation indicates that it is nearly impossible for toxic Gd ions to dissociate freely from silica. The biocompatibility studies confirm that the nanocomposite is lack of any potential toxicity; the biodistribution studies reveal a greater accumulation of the nanocomposite in liver, spleen, lung and tumor than in kidney, heart and brain; the excretion studies show that the nanocomposite can be cleared nearly 50% via the hepatobiliary transport mechanism after 1.5 months of injection. A larger water proton relaxivity r(1) and a better T(1)-weighted phantom MR imaging capability were detected in the nanocomposite than in the commercially available gadolinium diethylenetriaminepentaacetate. The results demonstrate that the nanocomposite is superior to the commercial counterpart in terms of contrast enhancement with a satisfactory biocompatibility, and it has a high potential to be developed into a safe and effective targeted probe for in vivo molecular imaging of cancer.