Regular arrays of C60-based molecular rotors mounted on the surface of tris(o-phenylenedioxy)cyclotriphosphazene nanocrystals.

Dielectric spectroscopy has been used to determine the barriers of rotation of surface-mounted fullerenes (2.3 ± 0.1 and 4.3 ± 0.1 kcal mol-1). In order to achieve this, a C60 derivative equipped with an anchoring group designed to form a surface inclusion with the hexagonal form of tris(o-phenylenedioxy)cyclotriphosphazene (TPP) has been synthesized. Solid-state NMR analysis revealed that approximately 50% of the surface-mounted molecules have a chemical environment different from the others suggesting two distinct insertion modes. These observations correlate with results of DFT calculations.

Stuffed pumpkins: mechanochemical synthesis of host-guest complexes with cucurbit[7]uril.

Solvent-free mechanochemical synthesis (ball-milling) was used to prepare inclusion complexes with cucurbit[7]uril and four model guest molecules (adamantane, adamantyl-1-amine hydrochloride, toluidine hydrochloride, and p-phenylenediamine dihydrochloride). Successful formation of individual inclusions was independently confirmed by one- and two-dimensional solid-state NMR techniques and differential scanning calorimetry. Mechanochemical synthesis represents an alternative path towards new types of cucurbit[n]uril/guest inclusion complexes that are not accessible due to limited solubility of the individual components.