Reinforcement of single-walled carbon nanotubes on polydimethylsiloxane membranes for CO2, O2, and N2 permeability/selectivity.

In this study, PDMS incorporated with SWCNTs have been fabricated via solution casting method for industrial applications and characterized by the analyses of SEM, FTIR, TGA, AFM, and MST. The modified membranes were further analyzed for CO2, O2, and N2 gas permeability. The strategic membranes have five different weight ratios (0.013, 0.025, 0.038, 0.050, 0.063) compared to neat PDMS membranes. The even distribution of SWCNTs in PDMS provided results that showed improvement in thermal stability. However, mechanical strength has been weakened with increased concentration of nanofiller because of the increase in the number of SWCNTs by increases that imperfections become more severe. The designed polymeric membranes with good thermal stability and adequate mechanical strength can be used for the selectivity and permeability of CO2, O2, and N2 gases. The effect of the PDMS-SWCNTs on gas permeability has been studied. 0.063 wt.% SWCNTs presented the maximum permeability of CO2 gas while maximum O2 and N2 gas permeability have been obtained by 0.013 wt.% SWCNTs. The ideal selectivity of mixed (50:50) gas conditions has been tested. The maximum CO2/N2 ideal selectivity was obtained by 0.050 and 0.063 wt.% SWCNTs while maximum O2/N2 ideal selectivity obtained by 0.050 wt.% SWCNTs. Therefore, the fabrication of this novel SWCNTs-PDMS membrane may lead to separating the industrial exhaust and be used as a potential membrane for environmental remediation in the future.

Synergistic effect of GO/ZnO loading on the performance of cellulose acetate/chitosan blended reverse osmosis membranes for NOM rejection.

Declining freshwater resources along with their pollution are threatening the life existence on earth. To meet the freshwater demand, one of the most appropriate and possible ways which has been adopted all over the world is to reuse wastewater by removing its impurities. Among many water pollutants, natural organic matter (NOM) is found to be responsible as major precursor for the formation of other pollutants. Removal of NOM from wastewater is being done by using membrane filtration systems incorporated with certain nanofillers to increase membranes efficiency and permeability. In this study, novel nanocomposite reverse osmosis (RO) membranes were prepared using cellulose acetate and chitosan in N,N-Dimethyl formamide. Graphene oxide (GO) nanosheets and zinc oxide (ZnO) in different concentration were loaded to modify the membranes for tuning their RO performance. The confirmation of the functional groups is demonstrated by Fourier transform infrared spectroscopy which revealed the specific peaks indicating the formation of the nano-composite membranes. The surface morphology was studied by scanning electronic microscopy which shows a gradual transformation of the membrane surface from voids-free to macro-voids filled surface up to threshold concentration of GO and ZnO. The thermal properties of GO based membranes were analyzed using thermogravimetric analysis and differential scanning calorimetry. The uniform interaction of the GO and ZnO with polymers induced the remarkable thermal properties of the synthesized membranes. Permeate flux and contact angle measurements were considered to estimate their water content (96%) capacity and NOM rejection (96%) using 0.1 ppm humic acid solution. The permeate flux, NOM rejection and the water content changed directly with GO and inversely with ZnO wt% in the membranes up to GO5 (GO:0.14: ZnO:0.03) whereas the contact angle exhibited the inverse relationship with GO and ZnO concentration in casting solution of the synthesized membranes. Hence it can be concluded that prepared RO membranes are suitable for NOM rejection and recommended for water treatment.

Novel antibacterial polyurethane and cellulose acetate mixed matrix membrane modified with functionalized TiO2 nanoparticles for water treatment applications.

Bacterial contamination is one of the leading causes of water pollution. Antibacterial polyurethane/cellulose acetate membranes modified by functionalized TiO2 nanoparticles were processed and studied. TiO2 nanoparticles were prepared and ultraviolet (UV) irradiated to activate their photocatalytic activity against Escherichia coli (E. Coil) and Methicillin-resistant Staphylococcus aureus (MRSA) bacteria. Functionalized TiO2 nanoparticles were incorporated in flat-sheet mixed matrix membranes (MMMs). These membranes were characterized for their different properties such as morphology, thermal stability, mechanical strength, surface wettability, water retention, salt rejection, water flux, and their antibacterial performance against E. Coil and MRSA was also tested. The activity of nanoparticles against MRSA and E. coli was analyzed using three different concentrations, 0.5 wt%, 1.0 wt% and 1.5 wt% of nanoparticles and 0.5 wt% of TiO2 nanoparticles showed maximum growth of bacteria. The maximum inhibition was observed in membranes with maximum nanoparticles when compared with other membranes. All these characteristics were strongly affected by increasing the concentration of TiO2 nanoparticles in the prepared membranes and the duration of their UV exposure. Hence, it was proved from this analysis that these TiO2 modified membranes exhibit substantial antibacterial properties. The results are supporting the utilization of these materials for water purification purposes.

Development and characterization of chitosan and acrylic acid-based novel biodegradable polymeric films for soil conditioning.

In this study, biodegradable polymeric films (BPFs) based on chitosan and acrylic acid cross-linked with 3-aminopropyl triethoxysilane (APTES) were developed for water retention and soil-conditioning applications in areas sufferings from water scarcity. A series of BPFs were prepared by varying the amount of silica nanoparticles (SiNPs) (0.67% to 2.6%) and a correlation of the optimum amount of SiNPs with thermal stability, morphology, swellability (at various pH), degradability, and anti-microbial activity were deduced. The obtained results showed that the NP 8 (containing 2.51% of SiNPs) exhibited the maximum absorption capacity (1815%) in distilled water, whereas NP6 (including 1.88% of SiNPs) expressed the maximum thermal stability (T50% at 375.61 °C). The microscopic images further strengthen this observation because the maximum number of micro-porous cavities was shown on the surface of NP8. The time-dependent swelling response in distilled water accomplished that hydrophilicity (percentage swelling) of films was enhanced with an increase in the concentration of SiNPs. All BPFs samples exhibited inhibitory response against both gram-positive (for Staphylococcus aureus was 2.9 cm for NP6) and gram-negative (for Escherichia coli was 0.9 cm for NP8) bacteria. The biodegradation test inferred that the degradation of BPFs in soil did not affect the soil fertility as nano-silica is proven as growth-promoting miniatures. It can be concluded that these BPFs may be efficiently employed in the agriculture sector for water retention and as a soil conditioner.

Idiosyncratic cellulose acetate nanocomposite membranes: synthesis and performance control study for desalination.

In order to enhance the characteristic performance of cellulose acetate (CA) membranes, a novel nanofiller synergy is adopted herein for desalination purpose. Activated zinc oxide and aero-silica synergy in seven different ratio based combinations were introduced into CA matrix adopting solution mixing technique. The functionalized nanofillers loading impact on membranes surface texture, crystalline structural difference, functional groups presence, thermal decomposition and phase transition temperatures were scrutinized. The sole membranes were practically employed to determine salts (NaCl and MgCl2) rejection tested by dead-end filtration system. Time dependent flux rate and fouling study were performed to decide the reuseability of nanocomposite membranes. The results validate a remarkable improvement by idiosyncratically synthesized nanocomposite membranes.

Carbon Nanotube Reinforced High Density Polyethylene Materials for Offshore Sheathing Applications.

Multiwall carbon nanotube (CNT)-filled high density polyethylene (HDPE) nanocomposites were prepared by extrusion and considered for their suitability in the offshore sheathing applications. Transmission electron microscopy was conducted to analyse dispersion after bulk extrusion. Monolithic and nanocomposite samples were subjected to accelerated weathering and photodegradation (carbonyl and vinyl indices) characterisations, which consisted of heat, moisture (seawater) and UV light, intended to imitate the offshore conditions. The effects of accelerated weathering on mechanical properties (tensile strength and elastic modulus) of the nanocomposites were analysed. CNT addition in HDPE produced environmentally resilient nanocomposites with improved mechanical properties. The energy utilised to extrude nanocomposites was also less than the energy used to extrude monolithic HDPE samples. The results support the mass substitution of CNT-filled HDPE nanocomposites in high-end offshore applications.

Customizable Ceramic Nanocomposites Using Carbon Nanotubes.

A novel tweakable nanocomposite was prepared by spark plasma sintering followed by systematic oxidation of carbon nanotube (CNT) molecules to produce alumina/carbon nanotube nanocomposites with surface porosities. The mechanical properties (flexural strength and fracture toughness), surface area, and electrical conductivities were characterized and compared. The nanocomposites were extensively analyzed by field emission scanning electron microscopy (FE-SEM) for 2D qualitative surface morphological analysis. Adding CNTs in ceramic matrices and then systematically oxidizing them, without substantial reduction in densification, induces significant capability to achieve desirable/application oriented balance between mechanical, electrical, and catalytic properties of these ceramic nanocomposites. This novel strategy, upon further development, opens new level of opportunities for real-world/industrial applications of these relatively novel engineering materials.

Controlled release of cephradine by biopolymers based target specific crosslinked hydrogels.

The novel silane crosslinked (TEOS) hydrogels based on eco-friendly biodegradable chitosan/guargum were prepared by blending with PEG to develop pH sensitive hydrogels (CGP) and achieved its hydrophilicity and target specificity for controlled release of drug. The crosslinker amount was varied to analyze its effect on the hydrogel properties and were characterized using FTIR, SEM, TGA, swelling studies (water, buffer and ionic solution) and in-vitro release of cephradine (CED). FTIR confirmed the presence of characteristic peaks and crosslinking between the components while SEM images showed the formation of clear micro- and macro-pores. The swelling behavior in water showed that compared to the controlled hydrogel, the crosslinked hydrogels revealed more swelling but a decrease in swelling with further increase in the amount of crosslinker was observed. The hydrogels showed low swelling at basic and neutral pH while maximum swelling was observed at acidic pH. This pH response made these hydrogels an ideal candidate for injectable controlled release. The CED was loaded on hydrogels and its release mechanism was studied in PBS, SGF and SIF which revealed that out of all hydrogels (CGP100, CGP150, CGP200 and CGP250), CGP100 has shown CED release of 85% in 130 min in PBS and 82.4% in SIF.

Co-concentration effect of silane with natural extract on biodegradable polymeric films for food packaging.

Novel biodegradable films were prepared by blending guar gum, chitosan and poly (vinyl alcohol) having mint (ME) and grapefruit peel (GE) extracts and crosslinked with nontoxic tetraethoxysilane (TEOS). The co-concentration effect of TEOS with natural extracts on the films was studied. FTIR analysis confirmed the presence of incorporated components and the developed interactions among the polymer chains. The surface morphology of the films by SEM showed the hydrophilic character due to porous network structure. The films having both ME and GE with maximum amount of crosslinker (100µL), showed maximum swelling (58g/g) and stability while the optical properties showed increased protection against UV light. This film sample showed compact network structure which enhanced the ultimate tensile strength (40.03MPa) and elongation at break (104.8%). ME/GE conferred the antioxidant properties determined by radical scavenging activity and total phenolic contents (TPC) as ME films have greater TPC compared to GE films. The soil burial test exhibited the degradation of films rapidly (6days) confirming their strong microbial activity in soil. The lower water vapour transmission rate and water vapour permeability showed better shelf life; hence, these biodegradable films are environmental friendly and have potential for food and other packaging.

Synergistic Effect of Functionalized Nanokaolin Decorated MWCNTs on the Performance of Cellulose Acetate (CA) Membranes Spectacular.

In order to enhance salt rejection level and high pressure mechanical integrity, functionalized nanokaolin decorated multiwall carbon nanotubes (FNKM, 0-5 wt % loading) were incorporated into a cellulose acetate (CA) matrix using high temperature solution mixing methodology. Scanning electron microscopy (SEM), X-ray diffraction technique (XRD), thermo-gravimetric analyzer (TGA) and Fourier transform infrared spectrometer (FTIR) were used to characterize the prepared membranes. The obtained results revealed that with increasing FNKM concentration in the host polymeric matrix, composite membrane's structural, functional, thermal, water permeation/flux and salt rejection characteristics were also modified accordingly. Percent enhancement in salt rejection was increased around threefold by adding 5 wt % FNKM in CA.