Microplastics distribution, ecological risk and outflows of rivers in the Bohai Rim region of China - A flux model considering small and medium-sized rivers.

Microplastics (MPs) pollution and its ecological risks have attracted increasing global attention. The Bohai Rim region (BRR), as the economic and population center of the entire northern China, still lacks a precise assessment of MPs pollution. Although current attention on MPs pollution mainly focuses on large rivers, small and medium-sized rivers are more numerous and more closely connected to human activities. In this study, measurement data of MPs from 11 estuaries in the BRR was collected to understand MPs distribution and ecological risk. The results indicate that the overall MPs pollution in these estuaries is still at a low level, with an average abundance of 1254.3 particles m-3. While the pollution load index (1.85) is relatively low, the potential ecological risk of PVC in some area (S8, EPVC = 1433.78, III) warrants further attention. Then we integrated data from 22 relevant rivers (covering all size rivers) in this region from the literature to fit a MPs flux model and assessed the MPs outflow from the four provinces and cities in the region. A strong correlation is achieved between modeled estimates and field measurements (r2 = 0.74), which can well estimate the river MPs outflows in northern China such as the Nanfei River. The MPs outflow from the four provinces (cities) is calculated to be 123.235 (range 44.415-242.314) T year-1, of which Shandong accounted for >80 % (104.066 T year-1). The small and medium-sized rivers accounted for 47 % (58.08 T year-1), whose contribution to MPs outflows should not be underestimated. This study can help us to accurately assess MPs pollution in different coastal areas in northern China, benefiting the formulation of precise control measures and policies for marine MPs pollution.

Microfluidic sensors for the detection of emerging contaminants in water: A review.

In recent years, numerous emerging contaminants have been identified in surface water, groundwater, and drinking water. Developing novel sensing methods for detecting diverse emerging pollutants in water is urgently needed, as even at low concentrations, these pollutants can pose a serious threat to human health and environmental safety. Traditional testing methods are based on laboratory equipment, which is highly sensitive but complex to operate, costly, and not suitable for on-site monitoring. Microfluidic sensors offer several benefits, including rapid evaluation, minimal sample usage, accurate liquid manipulation, compact size, automation, and in-situ detection capabilities. They provide promising and efficient analytical tools for high-performance sensing platforms in monitoring emerging contaminants in water. In this paper, recent research advances in microfluidic sensors for the detection of emerging contaminants in water are reviewed. Initially, a concise overview is provided about the various substrate materials, corresponding microfabrication techniques, different driving forces, and commonly used detection techniques for microfluidic devices. Subsequently, a comprehensive analysis is conducted on microfluidic detection methods for endocrine-disrupting chemicals, pharmaceuticals and personal care products, microplastics, and perfluorinated compounds. Finally, the prospects and future challenges of microfluidic sensors in this field are discussed.

Microalgae Film-Derived Water Evaporation-Induced Electricity Generator with Negative Carbon Emission.

Water evaporation-induced electricity generators (WEGs) are regarded as one of the most promising solutions for addressing the increasingly severe environmental pollution and energy crisis. Owing to the potential carbon emission in the preparation process of WEGs, whether WEG represents a clean electricity generation technology is open to question. Here, a brand-new strategy is proposed for manufacturing negative carbon emission WEG (CWEG). In this strategy, the microalgae film is used as the electricity generation interface of WEG, which achieves a stable open-circuit voltage (Voc) of 0.25 V and a short-circuit current (Isc) of 3.3 µA. Since microalgae can capture carbon dioxide during its growing process, CWEG holds great promise to generate electricity without carbon emissions in the full life cycle compared with other WEGs. To the best of the author's knowledge, this is the first work using microalgae films to fabricate WEG. Therefore, it is believed that this work not only provides a new direction for designing high-efficiency and eco-friendly WEG but also offers an innovative approach to the resource utilization of microalgae.

Evaporation Driven Hydrovoltaic Generator Based on Nano-Alumina-Coated Polyethylene Terephthalate Film.

Collecting energy from the ambient environment through green and sustainable methods is highly expected to alleviate pollution and energy problems worldwide. Here, we report a facile and flexible hydrovoltaic generator capable of utilizing natural water evaporation for sustainable electricity production. The generator was fabricated by coating nano-Al2O3 on a twistable polyethylene terephthalate film. An open circuit voltage of 1.7 V was obtained on a piece of centimeter-sized hydrovoltaic generator under ambient conditions. The supercapacitor charged by the hydrovoltaic device can power a mini-motor efficiently. Moreover, by expanding the size or connecting it in series/parallel, the energy output of the generator can be further improved. Finally, the influence factors and the mechanism for power generation were primarily investigated. Electrical energy is produced by the migration of water through charged capillary channels. The environmental conditions, the properties of the solution and the morphology of the film have important effects on the electrical performance. This study is anticipated to offer enlightenment into designing novel hydrovoltaic devices, providing diverse energy sources for various self-powered devices and systems.

MOFs/Ketjen Black-Coated Filter Paper for Spontaneous Electricity Generation from Water Evaporation.

Metal-organic frameworks (MOFs) have the advantages of tunable pore sizes and porosity and have demonstrated unique advantages for various applications. This study synthesized composite MOF nanomaterials by modifying MOF801 or AlOOH with UIO66. The composite nanomaterials, UIO66/MOF801 and UIO66/AlOOH showed increased Zeta potential than their pristine form, AlOOH, UIO66 and MOF801. For the first time, the composite MOFs were used to fabricate filter paper-based evaporation-driven power generators for spontaneous electricity generation. The MOFs-KBF membrane was constructed by coating filter paper (10 × 50 mm) with composite MOFs and conductive Ketjen Black. The UIO66/MOF801 decorated device achieved a maximum open circuit voltage of 0.329 ± 0.005 V and maximum output power of 2.253 µW. The influence of salt concentration (0.1-0.5 M) on power generation was also analyzed and discussed. Finally, as a proof-of-concept application, the device was employed as a salinity sensor to realize remote monitoring of salinity. This work demonstrated the potential of flexible MOF composites for spontaneous power generation from water evaporation and provides a potential way to enhance the performance of evaporation-driven power generators.

Slower antibiotics degradation and higher resistance genes enrichment in plastisphere.

Microplastics (MPs) are increasingly entering the urban aquatic ecosystems, and the environmental significance and health risks of plastisphere, a special biofilm on MPs, have received widespread attention. In this study, MPs of polylactic acid (PLA) and polyvinyl chloride (PVC) and quartzite were incubated in an urban water environment, and the tetracycline (TC) degradation ability was compared. Approximatedly 24% of TC biodegraded in 28 d in the water-quartzite system, which is significantly higher than that in the water-PLA (17.3%) and water-PVC systems (16.7%). Re-incubation of microorganisms in biofilms affirmed that quartzite biofilm has a higher TC degradation capacity than the plastisphere. According to high-throughput sequencing of 16S rRNA and metagenomic analysis, quartzite biofilm contained more abundant potential TC degrading bacteria, genes related to TC degradation (eutG, aceE, and DLAT), and metabolic pathways related to TC degradation. An oligotrophic environment on the quartzite surface might lead to the higher metabolic capacity of quartzite biofilm for unconventional carbons, e.g., TC. It is also found that, compared with quartzite biofilm, the distinct microbes in the plastisphere carried more antibiotic resistance genes (ARGs). Higher affinity of MPs surface to antibiotics may lead to higher antibiotics stress on the plastisphere, which further amplify the carrying capacity for ARGs of microorganisms in the plastisphere. Compared to the nondegradable PVC MPs, surface of the biodegradable PLA plastics harbored significantly higher amounts of biomass and ARGs. Compared to the mineral particles, the capability of plastisphere has lower ability to degrade unconventional carbon sources such as the refractory organic pollutants, due to the abundance of carbon sources (adsorbed organic carbon and endogenous organic carbon) on the MPs surface. Meanwhile, the stronger adsorption capacity for pollutants also leads to higher pollutant stress (such as antibiotic stress) in plastisphere, which in turn affects the microbiological characteristics of the plastisphere itself, such as carrying more ARGs.

Microbial fuel cell system: a promising technology for pollutant removal and environmental remediation.

The microbial fuel cell (MFC) system is a promising environmental remediation technology due to its simple compact design, low cost, and renewable energy producing. MFCs can convert chemical energy from waste matters to electrical energy, which provides a sustainable and environmentally friendly solution for pollutant degradations. In this review, we attempt to gather research progress of MFC technology in pollutant removal and environmental remediation. The main configurations and pollutant removal mechanism by MFCs are introduced. The research progress of MFC systems in pollutant removal and environmental remediation, including wastewater treatment, soil remediation, natural water and groundwater remediation, sludge and solid waste treatment, and greenhouse gas emission control, as well as the application of MFCs in environmental monitoring have been reviewed. Subsequently, the application of MFCs in environmental monitoring and the combination of MFCs with other technologies are described. Finally, the current limitations and potential future research has been demonstrated in this review.