Pre-enrichment of radioactive cesium in muddy water separated into suspended and dissolved substances for trace analysis.

A new in-situ pre-enrichment system was developed for trace analysis of radioactive Cs in environmental water such as rivers, ponds, and seas, where the radioactive Cs is separated into suspended substances (SS) and dissolved substances (DS). The SS component was collected as the enrichment slurry by cross-flow filtration, thereby compact systems were realized. The DS component was collected in a small cartridge filled with a non-woven fiber with immobilized adsorbent nanoparticles. The recovery rate was estimated at around 95%. The size distribution of the SS and the concentration of radioactive Cs after enrichment were the same as that of the raw water before enrichment. The condensed SS can be used for other evaluations such as ignition loss. From the field test at a pond in the Fukushima-area, the Cs concentration of the SS was found to be 4-5 times higher than that of the sediment in the same pond. The organic content estimated by ignition loss was also three times higher.

Inversion analysis on vertical radiocesium distribution in pond sediment from γ-ray count measurement.

Evaluation of vertical distribution of radiocesium in bottom sediment by measuring vertical γ-ray count profile was discussed. A stable inversion formula was derived based on the maximum entropy method. Efficiency of the formula was confirmed by using a low-cost apparatus composed of an array of PIN photodiodes and a single board computer with real-time inversion code. In-door experiment by using five model sediment disks showed good reproducibility of vertical radiocesium profile. On-site experiment was also carried out at a pond in Fukushima to confirm the efficiency. It was suggested that combination of the simple apparatus and MEM inversion formula gave reasonable estimates on vertical radiocesium distribution in bottom sediment of 1 kBq/kg-wet level within about 10 min.

Radiocesium removal system for environmental water and drainage.

With the development of the nuclear power generation, it is expected that severe pollution of environmental water by radiocesium (r-Cs) may occur. We developed a r-Cs removal system with a continuous stirring tank reactor (CSTR) and r-Cs adsorbent of non-woven fiber immobilizing Prussian blue nanoparticles (PBN). Results confirmed that this system can remove r-Cs from environmental water with a removal rate higher than 80% at processing speed of 2 m3/h. In this study, the processing speed and processing capacity of this system were confirmed using kinetic and equilibrium analyses of Cs adsorption behavior on PBN. The equilibrium of Cs adsorption was analyzed using a Langmuir equation. Results show that the maximum adsorption capacity was 160 mg/g (PBN). The kinetic data were well fitted using a pseudo-first order kinetic model. This rate constant was correlated to the PBN/liquid ratio in the system.