Trace element contamination status of surface marine sediments of Greece: an assessment based on two decades (2001-2021) of data.

This study is a first attempt to assess the trace element contamination status in the surface sediments of the Hellenic Seas since the first environmental studies in the country commenced in the mid-1970s. All available trace element data from the last 20 years have been collected and assessed using sediment quality guidelines and application of single- and multielement pollution indices. Although Hellenic marine sediments initially appear as anthropogenically enriched in Cr and As, this enrichment is attributed to the natural background. Central Greece appears more polluted, followed by Northern Greece and lastly Southern Greece. The element pollution indices featured the influence of industrial activities such as mining, steel industry and chemical factories, shipyards, and secondarily the influence of port activities.

Chromium speciation, mobility, and Cr(VI) retention-release processes in ultramafic rocks and Fe-Ni lateritic deposits of Greece.

Water contamination by geogenic hexavalent chromium is an emerging issue in areas developed on ultramafic rocks and their weathering products. In this study, samples of serpentinites, soil, and laterites were collected and analyzed for the levels of Cr species, distribution into phases of different mobility, mineralogy, Cr oxidation capacity, and leaching of Cr(VI). Total chromium (2176-21,929 mg kg-1) was mainly found in Cr spinels (~ 50% wt as Cr2O3) and Fe (hydr)oxides (2.5% wt). Total Cr(VI) contents (0.49-11.5 mg kg-1) increased from the serpentinites to the soil and lateritic deposit, i.e., during the advanced stages of weathering, which were accompanied by increased Cr mobility. Batch experiments of 500-h duration showed that Cr(VI) released in water at rates of 0.25-1.20 nM h-1. Rates were higher in water of pH 5.7 rather than pH 8.5, because more Cr(VI) was formed during the experimental period. Asbolane-type Mn oxides and Mn-bearing crystalline Fe oxides were responsible for Cr(III) oxidation. Most of the generated Cr(VI) (52-79% of total Cr(VI)) remained solid-bound by adsorption and/or precipitation processes. Because all samples had a self-capacity to oxidize Cr(III), it seems that retention processes will ultimately define the extent of geogenic Cr(VI) contamination of aquatic systems.

Dataset on the major and trace elements contents and contamination in the sediments of Saronikos Gulf and Elefsis Bay, Greece.

Coastal marine sediments receive intensive stress from urbanization and industrialization, which is manifested by increased contents of heavy metals and organic pollutants. Saronikos Gulf and the small embayment of Elefsis, stretch along the coast of the greater Athens and Pireaus port, the most urbanized and industrialized areas in Greece. Here we present the data of a 20-year geochemical record on grain-size, organic carbon, and major and trace elements contents of the Saronikos Gulf sediments. A total of 216 sediment samples were collected within the period of 1999-2018 from the four sub-sectors of the gulf, namely, the Elefsis Bay, the Inner, Outer, and Western (Megara and Epidavros basin) Saronikos Gulf. Additionally, at least one core was obtained from each sub-sector. Sediments deposited at pre-industrial periods were recognized by 14C and 210Pb dating, and served for establishing regionalized background levels of metals. Factor analysis was conducted to reveal the inter-parametric relationships, thus their common sources, as well as transport and deposition pathways. Then, Enrichment Factors and the multi-elemental Modified Pollution Index (MPI) were calculated to assess the current environmental status of the sediments. Data of sampling sites with at least a five-year record, were assessed for temporal trends, to explore whether sustained, increasing or decreasing trends of the MPI are observed. The dataset and analyses presented here support the research article entitled Geochemistry of major and trace elements in surface sediments of the Saronikos Gulf (Greece): assessment of contamination between 1999 and 2018 [1].

Assessment of the physical impact of a short-term dredging operation on a semi-enclosed environment: South Euboean Gulf, Greece.

The potential influence of short-period (May-June 2012) dredging activities (for the installation of a submarine gas pipeline) on physical properties of the marine environment of two shallow-water sites in the Aliveri and Varnavas areas of South Euboean Gulf (Greece) has been evaluated. During the dredging operation in Varnavas, the induced dredge plume traveled up to ~ 750 m from the shoreline, featured by light attenuation coefficient (cp) maxima of 4.01-4.61 m-1 and suspended particulate matter (SPM) concentrations up to 6.01 mg L-1. After dredging the previous parameters reduced to the ambient seawater condition, ~ 0.45 m-1 and < 2.8 mg L-1 on average, respectively. Likewise in Aliveri, the dredging-associated sediment plume drifted offshore up to ~ 400 m from the shoreline, characterized by cp maxima of 2.11-4.86 m-1 and SPM concentrations up to 13.07 mg L-1. After the completion of the excavation and trenching activities, the cp and SPM values were restored to the pre-disturbance condition, ~ 0.6 m-1 and < 2.2 mg L-1 on average, respectively. The migration of the dredge plume in both dredging sites was accomplished through the formation of intermediate and benthic nepheloid layers, whose development and evolution were governed by seawater stratification and flow regime. The dredging-derived SPM levels appeared to increase within a distance of no more than 300 m from the shoreline (near-field zone). Based on data from the literature, this SPM enhancement together with the deposition of a post-dredging residual mud veneer in the near-field zone could deteriorate local marine biota, but in a reversible way.

Mobile underwater in situ gamma-ray spectroscopy to localize groundwater emanation from pockmarks in the Eckernförde bay, Germany.

Eckernförde Bay in the Baltic Sea is well-known for the pockmarks areas which are located in the centre and off the southern shore-line of the bay emanating groundwater in a non-continuous but episodic way. Mobile underwater in situ gamma-ray spectroscopy is exploited proving that both 214Bi and 40K are efficient radiotracers for localization of seepage areas whenever either sediment is in mixture with the emanating fluid or resuspension of surface sediment occurs as a side effect of the fluid emanation.

Cupriavidus metallidurans biomineralization ability and its application as a bioconsolidation enhancer for ornamental marble stone.

Bacterially induced calcium carbonate precipitation of a Cupriavidus metallidurans isolate was investigated to develop an environmentally friendly method for restoration and preservation of ornamental stones. Biomineralization performance was carried out in a growth medium via a Design of Experiments (DoE) approach using, as design factors, the temperature, growth medium concentration, and inoculum concentration. The optimum conditions were determined with the aid of consecutive experiments based on response surface methodology (RSM) and were successfully validated thereafter. Statistical analysis can be utilized as a tool for screening bacterial bioprecipitation as it considerably reduced the experimental time and effort needed for bacterial evaluation. Analytical methods provided an insight to the biomineral characteristics, and sonication tests proved that our isolate could create a solid new layer of vaterite on marble substrate withstanding sonication forces. C. metallidurans ACA-DC 4073 provided a compact vaterite layer on the marble substrate with morphological characteristics that assisted in its differentiation. The latter proved valuable during spraying minimum amount of inoculated media on marble substrate under conditions close to an in situ application. A sufficient and clearly distinguishable layer was identified.

In-situ radionuclide characterization of a submarine groundwater discharge site at Kalogria Bay, Stoupa, Greece.

In-situ underwater gamma-ray spectrometer KATERINA was used for continuous measurements of radon progenies ((214)Pb, (214)Bi), thoron progeny ((208)Tl) and (40)K in submarine groundwater discharge (SGD) sites at Kalogria Bay, SW Peloponnesus (Greece). The spectrometer was deployed attached on measuring platform along with two conductivity - temperature data loggers while underwater battery packs supplied the system for acquisition periods up to 25 days. The radionuclide time series together with salinity data were obtained for spring (wet) and summer (dry) seasons. The (40)K activity concentrations correlated well with salinity of the emanating groundwater. Although the (214)Bi and (208)Tl activities showed usually similar trends anticorrelating with salinity, in some cases (208)Tl did not follow the (214)Bi record due to changes in the dynamics of the groundwater aquifer. As the half-life of (220)Rn is very short (55.6 s), its concentration in SGD may depend on the distance from its origin to the monitoring point. The observed temporal variations of (214)Bi and (208)Tl confirmed advantages of continuous in-situ monitoring of SGD in coastal areas.

Impact of 100-year human interventions on the deltaic coastal zone of the Inner Thermaikos Gulf (Greece): a DPSIR framework analysis.

The Axios River delta and the Inner Thermaikos Gulf coastal zone have experienced a long period of human interventions during the past 100 years. A post-evaluation of long run coastal zone changes under the Drivers-Pressures-State-Impacts-Response (DPSIR) conceptual framework is presented. The DPSIR approach is then used to project out into possible futures in order to connect with policy and management options proposed for the improvement of the current conditions and the achievement of sustainable development, in the coastal zone. Socio-economic driving forces with their origins in the end of the 19th century have generated numerous pressures in the coastal environment that changed the state of the environment. In the first part of the last century, there was no coupling between change of state and policy. Due to increasing environmental awareness, a coupling became more apparent over the last thirty years. Human interventions include river route realignment, extensive drainage of the plains, irrigation network, roads and dam constructions. The consequences were positive for the economic development of the area, human health, and navigation for the port of Thessaloniki. In contrast, the manipulation and over-use of natural resources has led to a reduction of wetlands, biodiversity loss, stress on freshwater supplies, and subsidence of coastal areas, aquifer salinization, and rapid coastal erosion. Three plausible future scenarios are utilised in order to investigate the implications of this environmental change process and possible socio-economic consequences.