Application Scopes of Miniaturized MXene-Functionalized Electrospun Nanofibers-Based Electrochemical Energy Devices.

Exploring combinatorial materials, as well as rational device configuration design, are assumed to be the key strategies for deploying versatile electrochemical devices. MXene sheets have revealed a high hydrophilic surface with proper mechanical and electrical characteristics, rendering them supreme additive candidates to integrate in electrospun electrochemical power tools. The synergetic effects of MXene 2D layers with the nanofibrous networks can boost actuator responsive ability, battery capacity retention, fuel cell stability, sensor sensitivity, and supercapacitor areal capacitance. Their superior mechanical features can be endowed to the electrospun layers through the embedding of the MXene additive. In this review, the preparation and inherent features of the MXene configurations are briefly evaluated. The fabrication and overall performance of the MXene-loaded nanofibers applicable in electrochemical actuators, batteries, fuel cells, sensors, and supercapacitors are comprehensively figured out. Eventually, an outlook on the future development of MXene-based electrospun composites is presented. A substantial focus has been devoted to date to engineering conjugated MXene and electrospun fibrous frames. The potential performance of the MXene-decorated nanofibers presents a bright future of nanoengineering toward technological growth. Meanwhile, a balance between the pros and cons of the synthesized MXene composite layers is worthwhile to consider in the future.

Overlooked Promising Green Features of Electrospun Cellulose-Based Fibers in Lithium-Ion Batteries.

Lithium-ion batteries (LIBs) are accounted as promising power tools, applicable in a wide range of energy-based equipment, from portable devices to electric vehicles. Meanwhile, approaching a cost-effective, environmentally friendly, and safe LIB array has remained sluggish yet. In this regard, cellulose, as a nontoxic natural renewable polymer, has provided a stable and cohesive electrode structure with excellent mechanical stability and reduced electrode cracking or delamination during cycling. Additionally, the porous configuration of the cellulose allows for efficient and faster ion transport as a separator component. Miniaturizing cellulose and its derivatives have revealed more fabulous characteristics for the anode, cathode, and separator resulting from the increased surface-to-volume ratio and superior porosity, as well as their thin and lightweight architectures. The focal point of this review outlines the challenges relating to the extraction and electrospinning of cellulose-based nanofibers. Additionally, the efforts to employ these membranes as the LIBs' components are elucidated. Correspondingly, despite the great performance of cellulose-based LIB structures, a research gap is sensed in this era, possibly due to the difficulties in processing the electrospun cellulose fibers. Hence, this review can provide a source of recent advancements and innovations in cellulose-based electrospun LIBs for researchers who aim to develop versatile battery structures using green materials, worthwhile, and eco-friendly processing techniques.

Current trends and future perspectives of stroke management through integrating health care team and nanodrug delivery strategy.

Stroke is accounted as the second-most mortality and adult disability factor in worldwide, while causes the bleeding promptly and lifetime consequences. The employed functional recovery after stroke is highly variable, allowing to deliver proper interventions to the right stroke patient at a specific time. Accordingly, the multidisciplinary nursing team, and the administrated drugs are major key-building-blocks to enhance stroke treatment efficiency. Regarding the healthcare team, adequate continuum of care have been declared as an integral part of the treatment process from the pre-hospital, in-hospital, to acute post-discharge phases. As a curative perspective, drugs administration is also vital in surviving at the early step and reducing the probability of disabilities in later. In this regard, nanotechnology-based medicinal strategy is exorbitantly burgeoning. In this review, we have highlighted the effectiveness of current clinical care considered by nursing teams to treat stroke. Also, the advancement of drugs through synthesis of miniaturized nanodrug formations relating stroke treatment is remarked. Finally, the remained challenges toward standardizing the healthcare team and minimizing the nanodrugs downsides are discussed. The findings ensure that future works on normalizing the healthcare nursing teams integrated with artificial intelligence technology, as well as advancing the operative nanodrugs can provide value-based stroke cares.

Tailoring the performance of the LiNi0.8Mn0.1Co0.1O2 cathode using Al2O3 and MoO3 artificial cathode electrolyte interphase (CEI) layers through plasma-enhanced atomic layer deposition (PEALD) coating.

The Ni-rich layered oxide cathode has shown high energy density, proper rate capability, and longevity of the rechargeable battery, while poor stability and capacity fading are assumed to be its common cons. To address this obstacle, prospective cathode materials are synthesized by integrating the lithium transition metal oxides with an artificial cathode electrolyte interphase (CEI) layer. Herein, plasma-enhanced atomic layer deposition (PEALD) is employed to coat the LiNi0.8Mn0.1Co0.1O2 (NMC811) electrode with Al2O3 and MoO3. The combined results from morphological examinations revealed the formation of uniform Al2O3 and MoO3 sheets after 200 cycles of PEALD coating. Consistent results from the XRD analysis demonstrate that Al2O3 and MoO3 artificial CEIs can reduce Li-Ni mixing. The cyclic voltammetry tests show the oxidation-reduction kinetic. The modified NMC811 structures with Al2O3 and MoO3 represent a remarkable improvement in terms of capacity retention. The coated cathode with Al2O3 clearly outperforms the modified configuration with MoO3 concerning ionic conductivity, charge/discharge reversibility, and capacity retention. The promising results obtained in this study open the possibility of synthesizing Ni-rich cathodes with enhanced electrochemical performance.

The determinant role of fabrication technique in final characteristics of scaffolds for tissue engineering applications: A focus on silk fibroin-based scaffolds.

3D scaffolds are in the center of attention for tissue engineering applications. Whilst many studies have focused on the biological properties of scaffolds, less attention has been paid to meeting the biomechanics of the target tissues. In this work, we show how using the same original biomaterial, but different fabrication techniques can lead to a broad range of structural, mechanical, and biological characteristics. Starting with silk fibroin filament as our base biomaterial, we employed electrospinning, film casting, and weft knitting as different scaffold fabrication techniques. Among these three, the weft knit scaffold showed outstanding cell-scaffold interaction including full 3D cell attachment, complete cell coverage around individual filaments, and in-depth cell infiltration. Post-fabrication degumming of silk filament yarns resulted in more bulky and less open pores for the silk fibroin knit scaffold. The decreased pore size after degumming of knit scaffold alleviated the need to in-advance pore filling (a requisite for increasing cell adhesion in a typical knit scaffold having big pores). From a mechanical viewpoint, the weft knit scaffold shows the highest mechanical strength alongside with far better extensibility. Interestingly, the silk filament weft knit scaffold (in the course direction) was 100 and 1000 times more compliant than silk fibroin film and electrospun web, respectively. The observed effect of material type and fabrication technique highlights the suitability of silk fibroin weft-knit scaffolds for the regeneration of load-bearing soft tissues such as urine bladder.