1.
Chem Commun (Camb)
; 53(42): 5733-5736, 2017 May 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-28492626
RESUMO
Alkynyl sulfoxides are shown to act as α-sulfinyl metallocarbene synthons under oxidative gold catalysis, enabling reactions that are not available from diazo-precursors. This strategy is exemplified in the synthesis of fused α-sulfinyl cyclopropanes.