Advancements in Bipolar Membrane Electrodialysis Techniques for Carbon Capture.

Bipolar membrane electrodialysis (BMED) is a promising technology for the capture of carbon dioxide (CO2) from seawater, offering a sustainable solution to combat climate change. BMED efficiently extracts CO2 while generating valuable byproducts like hydrogen and minerals, contributing to the carbon cycle. The technology relies on ion-exchange membranes and electric fields for efficient ion separation and concentration. Recent advancements focus on enhancing water dissociation in bipolar membranes (BPMs) to improve efficiency and durability. BMED has applications in desalination, electrodialysis, water splitting, acid/base production, and CO2 capture and utilization. Despite the high efficiency, scalability, and environmental friendliness, challenges such as energy consumption and membrane costs exist. Recent innovations include novel BPM designs, catalyst integration, and exploring direct air/ocean capture. Research and development efforts are crucial to unlocking BMED's full potential in reducing carbon emissions and addressing environmental issues. This review provides a comprehensive overview of recent advancements in BMED, emphasizing its role in carbon capture and sustainable environmental solutions.

Novel ionic separation mechanisms in electrically driven membrane processes.

Electromembrane processes including electrodialysis (ED) and related processes are usually limited by diffusion transport of ions from a bulk solution to ion exchange membranes. The diffusion limited current (DLC) occurs when the concentration at membrane surfaces vanishes and approaches zero. Increasing the applied potential difference above this point has no substantial effect on ion transport and causes operational problems such as low current efficiency, high energy consumption, and mineral scaling. However, it is evident from numerous studies that operating at overlimiting current (OLC) is possible and allows one to enhance the mass transfer of an electromembrane process. While OLC is sometimes possible by electrochemical means, such as water splitting or current induced membrane discharge, it has been found that exotic ion transport mechanisms, such as ion concentration polarization in micro/nanofluidic system, deionization shock waves, and ionic bridges, can provide novel electrokinetic means of achieving OLC. In this paper, these novel ionic separation mechanisms and their role in enhanced current transfer are reviewed in the context of emerging electromembrane processes, such as shock ED and electrodeionization (EDI).

Extractive membrane bioreactor (EMBR): Recent advances and applications.

Combining bioreactor and membrane, known as a membrane bioreactor (MBR), has been considered as an attractive strategy to solve the limitations of conventional activated sludge process, such as biological instability, poor sludge quality, and low concentration of mixed liquor suspended solid. Unlike the other MBRs, extractive membrane bioreactor (EMBR) focuses on enhancing the efficiency of wastewater treatment through toxic compounds extraction by using a selective membrane. Even though EMBR has been successfully demonstrated in wastewater and waste gas treatment by several studies, it still faces some obstacles such as biofilm formation and low selectivity of the membrane towards a specific component. Appropriate biofilm formation control strategies and membrane with high selectivity are needed to solve those problems. This paper reviews EMBR including its potential applications in wastewater treatment, denitrification process, and waste gas treatment. In addition, challenges and outlook of EMBR are discussed.