A thematic review on livestock manure treatment strategies focusing on thermochemical conversion.

Livestock manure (LSM) management is emerging as a challenge due to increasing livestock consumption. Owing to the decreased agricultural land area, it is necessary to ensure LSM utilization in non-agricultural fields. LSM can be a valuable resource if managed as a circulating resource. This study discusses research trends based on a literature review and classifies LSM treatments. The analysis of each treatment is presented according to research trends, and implications for the future LSM processing are discussed. "Biological treatment" accounted for the largest portion at 48%, "manure management," which suggests improvement in manure treatment through systematic thinking or LSM management practices, accounted for 16%, and "thermochemical conversion" accounted for 11%. In addition, "life cycle assessment (LCA) research," "solid-liquid separation approach," and "nutrient-recovery/losses" were derived. Studies on biological treatments are increasing. Although anaerobic digestion (AD) is the most used method, it has the disadvantages of long processing time and waste generation after processing. As a key supplement, thermochemical conversion (TCC) technology, which could overcome the disadvantages of AD, was reviewed.

Identifying the socioeconomic determinants of industrial hazardous waste generation: South Korea as a case study.

The South Korean government has set an ambitious target to reduce industrial hazardous waste (IHW) as part of its transition towards a circular economy. Moreover, effective management of IHW within the country has become crucial, given that IHW trade is regulated by the Basel Convention. Despite the urgent need for well-founded environmental policies, there is a lack of essential information on the characteristics and determinants of IHW generation, which hinders the effectiveness of existing IHW policies. To address this information gap, this study developed a South Korean extended IHW input-output model for 2008 and 2018 to characterize IHW generation and applied structural decomposition analysis to identify the socioeconomic determinant of change of IHW generation. The results reveal that consumption, export, and direct IHW intensity change of 'Chemical', 'Electronic and electrical equipment', 'Basic metal', and 'Other service' emerge as dominant determinants for IHW growth. Conversely, technology change, including technological structure change and direct IHW intensity change, of 'Basic metal' and 'Other service' is the key driver for IHW reduction. In addition, an intriguing aspect of the study relates to the supply chain's influence on IHW generation. The indirect growth of IHW resulting from expanding exports and consumption contributes nearly twice as much to the overall increase in IHW as direct IHW growth. These valuable insights pave the way for the South Korean government to establish holistic and customized environmental policies regarding IHW. It emphasizes the importance of considering expanded global system boundaries, technological advancements, and purchasers' consumption patterns as dominant factors in formulating these policies. Furthermore, this study not only provides crucial guidance for the government's decision-making but also suggests strengthening environmental management and monitoring practices.

Monitoring of air pollutants using plants and co-located soil-Egypt: characteristics, pollution, and toxicity impact.

The present work was conducted to evaluate the air quality in terms of inorganic pollutants and toxicity impact using two evergreen tree leaves, Eucalyptus globulus Labill (E. globulus) and Ficus microcarpa L.f., Suppl. Pl. 442 (1782) (F. microcarpa) as biomonitors. Thirty tree leaves and an equal number of co-located soil samples from different regions of Egypt (urban Greater Cairo Metropolitan (GC) and rural Menoufia Governorate (MG)) were collected. The concentrations of 34 and 40 elements were determined using instrumental neutron activation analysis (INNA) and atomic absorption spectrometry (AAS) in tree leaves and soils, respectively. Bivariate and multivariate statistical analyses were implemented. The air pollution was assessed using enrichment factor, pollution load index, potential ecological risk, and risk index. In addition, human and ecotoxicity were evaluated based on the ReCiPe method. The mean concentration values of the obtained elements in tree leave in urban Greater Cairo and rural Menoufia Governorate show that the major elements are slightly higher in F. microcarpa than in E. globulus. Likewise, the mean values of elements in soil from GC and MG show no significant difference except for major elements (Fe, Al, Mg, K, Na, and Ti) in MG. The normalized concentrations of tree leave and soil show that the accumulated elements by F. macrocarpa are slightly higher than in E. globulus in GC and MG. While in terms of the investigated area, the concentrations of elements in MG are considerably higher than in GC. Pollution load index (PLI) spatial distribution over investigated areas showed that despite high population density, heavy traffic, and urban pollution, the Cairo samples exhibit significantly lower values as compared to those from Menoufia, which is most likely due to the uncontrolled industrial and domestic waste disposal outside Cairo. Potential ecological risk (PER) was significant for As in soil and for As and Cd in tree species. Human toxicity shows higher values in urban locations. Contrariwise, in the terrestrial ecotoxicity aspect, the rural locations are much higher than in urban ones.

Characteristics of industrial hazardous waste generation in South Korea from 2008 to 2018 based on decoupling and decomposition analysis.

The industrial hazardous waste (IHW) generation to meet consumption is steadily increasing, resulting in environmental, health, and social problems around the world. To address IHW at the source, it is critical to understand the generation characteristics and key drivers on industrial hazardous waste generation (IHWG). This study analysed the generation characteristics of IHW of South Korea from 2008 to 2018 by decoupling and index decomposition analysis using Log Mean Divisia Index (LMDI) model. South Korea presented unstable decoupling of IHWG from economic growth, so more effective waste management regulations are needed to support a stable decoupling. One most critical finding was that the factors of industrial output and industrial characteristic of IHWG-to-energy were major driving factors influencing the increase of IHWG, whereas those of industrial structure and energy efficiency affect to the decrease of IHWG in most industries. In addition, the result clearly confirmed that the contribution of driving factors affecting the IHWG differs by industry. These results provide significant policy insights that the South Korean government needs institutional improvement and refinement of customised IHW management according to the characteristics of IHWG.

Disruption in Circularity? Impact analysis of COVID-19 on ship recycling using Weibull tonnage estimation and scenario analysis method.

The sustainability of the ship recycling industry strongly linked with the global shipping market and international commodity flows. More than 80% of the End of Life (EoL) ships are dismantled in South Asian countries, namely Bangladesh, India, and Pakistan. Due to measures taken to minimize the propagation of the Coronavirus disease (COVID-19), an international supply chain is broken to a historic low, except for certain medical-related urgencies. Due to the disruption of global supply chains, the industry may submerge into uncertainty due to, perhaps, lack of adequate labor force to dismantle increased EoL ships and due to disturbances of vessel transportation to the recycling nations amid strong precautionary measures. Our estimate suggests that about 300 million Gross Tonnage (GT) available for demolition in the next five years and the inability to get them recycled would cost about 20 billion dollars. More importantly, South Asian recycling nations would suffer from economic losses and employment opportunities. In this study, we also apply a scenario analysis technique to understand the impact range of COVID-19 in the short term and in the long term. The disruption is viewed through a circular economy framework, identifying a critical lack of 'global scale' acknowledgment in the circular economy framework. This article suggests that a formalized global scale, paralleled with favorable policies, may reduce supply chain disruption and improve sustainable development in the receiving nations.

Resourcing the Fairytale Country with Wind Power: A Dynamic Material Flow Analysis.

Wind energy is key to addressing the global climate challenge, but its development is subject to potential constraints of finite primary materials. Prior studies on material demand forecasting of wind power development are often limited to a few materials and with low technological resolution, thus hindering a comprehensive understanding of the impact of microengineering parameters on the resource implications of wind energy. In this study, we developed a component-by-component and stock-driven prospective material flow analysis model and used bottom-up data on engineering parameters and wind power capacities to characterize the materials demand and secondary supply potentials of wind energy development in Denmark, a pioneering and leading country in wind power. We also explicitly addressed the uncertainties in the prospective modeling by the means of statistical estimation and sensitivity analysis methods. Our results reveal increasing challenges of materials provision and end-of-life (EoL) management in Denmark's ambitious transition toward 100% renewable energy in the next decades. Harnessing potential secondary resource supply from EoL and extending lifetime could curtail the primary material demand, but they could not fully alleviate the material supply risk. Such a model framework that considers bottom-up engineering parameters with increased precision could be applied to other emerging technologies and help reveal synergies and trade-offs of relevant resource, energy, and climate strategies in the future renewable energy and climate transition.

Hydrogen fluoride (HF) substance flow analysis for safe and sustainable chemical industry.

In this study, the chemical substance flow of hydrogen fluoride (hydrofluoric acid, HF) in domestic chemical industries in 2014 was analyzed in order to provide a basic material and information for the establishment of organized management system to ensure safety during HF applications. A total of 44,751 tons of HF was made by four domestic companies (in 2014); import amount was 95,984 tons in 2014 while 21,579 tons of HF was imported in 2005. The export amount of HF was 2180 tons, of which 2074 ton (China, 1422 tons, U.S. 524 tons, and Malaysia, 128 tons) was exported for the manufacturing of semiconductors. Based on the export and import amounts, it can be inferred that HF was used for manufacturing semiconductors. The industries applications of 161,123 tons of HF were as follows: manufacturing of basic inorganic chemical substance (27,937 tons), manufacturing of other chemical products such as detergents (28,208 tons), manufacturing of flat display (24,896 tons), and manufacturing of glass container package (22,002 tons). In this study, an analysis of the chemical substance flow showed that HF was mainly used in the semiconductor industry as well as glass container manufacturing. Combined with other risk management tools and approaches in the chemical industry, the chemical substance flow analysis (CSFA) can be a useful tool and method for assessment and management. The current CSFA results provide useful information for policy making in the chemical industry and national systems. Graphical abstract Hydrogen fluoride chemical substance flows in 2014 in South Korea.

Life cycle analysis of greenhouse gas emissions for fluorescent lamps in mainland China.

China is the world's largest emitter of carbon dioxide, and it is also one of the largest fluorescent lamp consuming and producing country in the world. However, there are few studies evaluating greenhouse gas (GHG) emissions of fluorescent lamps in China. This analysis compared GHG emissions of compact fluorescent lamps with linear fluorescent lamps using life cycle assessment method in China's national conditions. The GHG emissions of fluorescent lamps from their manufacture to the final disposal phase on the national level of China were also quantified. The results indicate that the use phase dominates the GHG emissions for both lamps. Linear fluorescent lamp is a better source of light compared to compact fluorescent lamp with respect to GHG emissions. The analysis found that in 2011, China generated around 710.90milliontons CO2-eq associated with fluorescent lamps. The raw material production and use phases accounted for major GHG emissions. More than half of GHG emissions during the domestic production were embodied in the exported lamps in recent years. This urges the government to take necessary measures that lead to more environmental friendly production, consumption and trade patterns.

Biological nitrogen removal from plating wastewater by submerged membrane bioreactor packed with granular sulfur.

Recent toughened water quality standards have necessitated improvements for existing sewer treatment facilities through advanced treatment processes. Therefore, an advanced treatment process that can be installed through simple modification of existing sewer treatment facilities needs to be developed. In this study, a new submerged membrane bioreactor process packed with granular sulfur (MBR-GS) was developed and operated to determine the biological nitrogen removal behaviors of plating wastewater containing a high concentration of NO3(-). Continuous denitrification was carried out at various nitrogen loading rates at 20 °C using synthetic wastewater, which was comprised of NO3(-) and HCO3(-), and actual plating wastewater, which was collected from the effluent water of a plating company called 'H Metals'. High-rate denitrification in synthetic plating wastewater was accomplished at 0.8 kg NO3(-)-N/m(3)·day at a nitrogen loading rate of 0.9 kg NO3(-)-N/m(3)·day. The denitrification rate further increased in actual plating wastewater to 0.91 kg NO3(-)-N/m(3)·day at a nitrogen loading rate of 1.11 kg NO3(-)-N/m(3)·day. Continuous filtration was maintained for up to 30 days without chemical cleaning with a transmembrane pressure in the range of 20 cmHg. Based on stoichiometry, SO4(2-) production and alkalinity consumption could be calculated theoretically. Experimental alkalinity consumption was lower than the theoretical value. This newly proposed MBR-GS process, capable of high-rate nitrogen removal by compulsive flux, is expected to be applicable as an alternative renovation technique for nitrogen treatment of plating wastewater as well as municipal wastewater with a low C/N ratio.

E-waste management and resources recovery in France.

There are various issues of concern regarding electronic waste management, such as the toxicity of hazardous materials and the collection, recycling and recovery of useful resources. To understand the fate of electronic waste after collection and recycling, a products and materials flow analysis should be performed. This is a critical need, as material resources are becoming increasingly scarce and recycling may be able to provide secondary sources for new materials in the future. In this study, we investigate electronic waste systems, specifically the resource recovery or recycling aspects, as well as mapping electronic waste flows based on collection data in France. Approximately 1,588,453 t of new electrical and electronic equipment were sold in the French market in 2010. Of this amount, 430,000 t of electronic waste were collected, with the remaining 1,128,444 t remaining in stock. Furthermore, the total recycled amounts were 354,106 t and 11,396 t, respectively. The main electronic waste materials were ferrous metals (37%), plastic (22%), aluminium (12%), copper (11%) and glass (7%). This study will contribute to developing sustainable electronic waste and resource recycling systems in France.

Integration of life cycle assessment and regional emission information in agricultural systems.

BACKGROUND: Life cycle assessment (LCA) is a compilation and evaluation of the input energy and materials, output emissions and the potential environmental impacts of a product, service or system throughout its life cycle. While methodological issues of LCA are still being developed, much research is being conducted worldwide in order to improve them. One of the important advances in LCA is a regionalised LCA, i.e. the development of regionalised databases, inventories, and impact assessment methods and models. RESULTS: Regional emission information (REI) was developed and integrated with the characterisation results in LCA of an agricultural product in the study area. Comparison of outcomes obtained with LCA characterisation results that did not include REI shows that the characterisation results taking REI into account are much higher as regards human toxicity, from 0.02% to 0.18%, freshwater ecotoxicity from 89% to 99% and terrestrial ecotoxicity from 8.006% to 26.177%. CONCLUSION: Results of current LCA studies on agricultural products and systems that do not include REI are under-estimating the life cycle environmental impact. For the LCA of agricultural products and systems, the REI as well as regionalised life cycle inventory data should be developed and integrated into the current LCA approach.

Modeling cumulative effects in life cycle assessment: the case of fertilizer in wheat production contributing to the global warming potential.

This paper aims at presenting a dynamic indicator for life cycle assessment (LCA) measuring cumulative impacts over time of greenhouse gas (GHG) emissions from fertilizers used for wheat cultivation and production. Our approach offers a dynamic indicator of global warming potential (GWP), one of the most used indicator of environmental impacts (e.g. in the Kyoto Protocol). For a case study, the wheat production in France was selected and considered by using data from official sources about fertilizer consumption and production of wheat. We propose to assess GWP environmental impact based on LCA method. The system boundary is limited to the fertilizer production for 1 ton of wheat produced (functional unit) from 1910 to 2010. As applied to wheat production in France, traditional LCA shows a maximum GWP impact of 500 kg CO2-eq for 1 ton of wheat production, whereas the GWP impact of wheat production over time with our approach to dynamic LCA and its cumulative effects increases to 18,000 kg CO2-eq for 1 ton of wheat production. In this paper, only one substance and one impact assessment indicator are presented. However, the methodology can be generalized and improved by using different substances and indicators.

Replacing gasoline with corn ethanol results in significant environmental problem-shifting.

Previous studies on the life-cycle environmental impacts of corn ethanol and gasoline focused almost exclusively on energy balance and greenhouse gas (GHG) emissions and largely overlooked the influence of regional differences in agricultural practices. This study compares the environmental impact of gasoline and E85 taking into consideration 12 different environmental impacts and regional differences among 19 corn-growing states. Results show that E85 does not outperform gasoline when a wide spectrum of impacts is considered. If the impacts are aggregated using weights developed by the National Institute of Standards and Technology (NIST), overall, E85 generates approximately 6% to 108% (23% on average) greater impact compared with gasoline, depending on where corn is produced, primarily because corn production induces significant eutrophication impacts and requires intensive irrigation. If GHG emissions from the indirect land use changes are considered, the differences increase to between 16% and 118% (33% on average). Our study indicates that replacing gasoline with corn ethanol may only result in shifting the net environmental impacts primarily toward increased eutrophication and greater water scarcity. These results suggest that the environmental criteria used in the Energy Independence and Security Act (EISA) be re-evaluated to include additional categories of environmental impact beyond GHG emissions.

A dynamic agent-based analysis for the environmental impacts of conventional and novel book retailing.

The dynamics of an e-commerce market and the associated environmental impacts from a bottom-up perspective using an agent-based model is explored. A conceptual meta-theory from psychology is adopted to form the behavioral rules of artificial consumers choosing different methods of buying a book, including conventional bookstores, e-commerce, and a proposed self-pick-up option. Given the energy and emissions savings that result from a shift to e-commerce from bookstore purchase, it appears that reductions in environmental impacts are relatively probable. Additionally, our results suggest that the shift to e-commerce is mainly due to the growth of Internet users, which ties energy and emissions savings to Internet penetration. Moreover, under any scenario, the energy and emissions savings will be provided by the introduction of the proposed self-pick-up option. Our model thus provides insights into market behaviors and related environmental impacts of the growing use of e-commerce systems at the retail level, and provides a basis for the development and implementation of more sustainable policies and practices.

Designing and assessing a sustainable networked delivery (SND) system: hybrid business-to-consumer book delivery case study.

We attempted to design and assess an example of a sustainable networked delivery (SND) system: a hybrid business-to-consumer book delivery system. This system is intended to reduce costs, achieve significant reductions in energy consumption, and reduce environmental emissions of critical local pollutants and greenhouse gases. The energy consumption and concomitant emissions of this delivery system compared with existing alternative delivery systems were estimated. We found that regarding energy consumption, an emerging hybrid delivery system which is a sustainable networked delivery system (SND) would consume 47 and 7 times less than the traditional networked delivery system (TND) and e-commerce networked delivery system (END). Regarding concomitant emissions, in the case of CO2, the SND system produced 32 and 7 times fewer emissions than the TND and END systems. Also the SND system offer meaningful economic benefit such as the costs of delivery and packaging, to the online retailer, grocery, and consumer. Our research results show that the SND system has a lot of possibilities to save local transportation energy consumption and delivery costs, and reduce environmental emissions in delivery system.

Environmental, social, and economic implications of global reuse and recycling of personal computers.

Reverse supply chains for the reuse, recycling, and disposal of goods are globalizing. This article critically reviews the environmental, economic, and social issues associated with international reuse and recycling of personal computers. Computers and other e-waste are often exported for reuse and recycling abroad. On the environmental side, our analysis suggests that the risk of leaching of toxic materials in computers from well-managed sanitary landfills is very small. On the other hand, there is an increasing body of scientific evidence that the environmental impacts of informal recycling in developing countries are serious. On the basis of existing evidence informal recycling is the most pressing environmental issue associated with e-waste. Socially, used markets abroad improve access to information technology by making low-priced computers available. Economically, the reuse and recycling sector provides employment. Existing policies efforts to manage e-waste focus on mandating domestic recycling systems and reducing toxic content of processes. We argue that existing policy directions will mitigate but not solve the problem of the environmental impacts of informal recycling. There are many opportunities yet to be explored to develop policies and technologies for reuse/recycling systems which are environmentally safe, encourage reuse of computers, and provide jobs.