1.
Angew Chem Int Ed Engl
; 58(34): 11826-11829, 2019 Aug 19.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31211522
RESUMO
The power of chemical light generation (chemiluminescence) is used to drive polymerization reactions. A biphasic reaction is developed such that light-generating reactions are confined to the organic phase and photopolymerization occurs in the aqueous phase. Well-defined RAFT-capped polymers are synthesized and the kinetics are shown to be dictated by light generation.