Evaluation of the prediction of micropollutant elimination during bromide ion-containing industrial wastewater ozonation using the ROH, O3 value.

The composition of the wastewater matrix influences the oxidation potential of ozonation, a technique widely recognized efficient removal of micropollutants. Here, we developed a chemical kinetic model to determine the ozone dose required to minimize bromate production in wastewater containing bromine ions while achieving target removal rates. In wastewater ozonation, ozone decomposition comprises instantaneous ozone consumption and subsequent decomposition at first-order reaction rates. Under the injection condition of 1.5 g O3/g dissolved organic carbon (DOC), the instantaneous ozone demand was 62.7% of the injection concentration, and it increased proportionally with increasing injected ozone concentration. Ozone and hydroxyl radical exposures were proportional to the initial ozone dose, while hydroxyl radical exposure was proportional to ozone exposure, and the deviation was relatively high at 1.0-1.5 g O3/g DOC. The calculated hydroxyl radical exposure was 3.0 × 10-10 to 5.3 × 10-10 M s. Ozone and hydroxyl radicals are highly correlated with the ratio of ozone dose to organic matter concentration. Therefore, a trace substance removal rate evaluation model combined with the ROH, O3 model and a bromate generation model were also considered. For ibuprofen, the ozone dose for achieving the target removal rate of 80% while maintaining the bromate concentration below 50 µg L-1 was suitable in the operating range of 0.86 g O3/g DOC or more. The proposed method provides a practical operation strategy to calculate the appropriate ozone dose condition from the target compound removal rate prediction and bromate generation models considering the ratio of ozone dose to organic matter concentration in the incoming wastewater.

Electronic tongue for the simple and rapid determination of taste and odor compounds in water.

Taste and odor (T&O) compounds present in natural water bodies could originate from algae. In this study, alga-generated compounds that can cause T&O issues in water, such as geosmin (GE), 2-Methylisoborneol (MIB), 2,4,6-Trichloroanisole (TCA), 2-Methylbenzofuran (MB), 2-Isopropyl-3-methoxypyrazine (IPMP), 2-Isobutyl-3-methoxypyrazine (IBMP), cis-3-Hexenyl acetate (HA), trans,trans-2,4-Heptadienal (HD), trans,cis-2,6-Nonadienal (ND), and trans-2-Decenal (DN), were determined through solid-phase microextraction coupled with gas chromatography/mass spectrometry (HS-SPME GC/MS) and electronic tongue (E-tongue), and the results from the two techniques were compared. Although HS-SPME GC/MS facilitates the detection and quantification of T&O compounds with high precision and accuracy, the sample preparation and handling is difficult and the analysis time (1 h) is longer than those of other analytical methods. E-tongue can be used as an alternative analytical method for water quality analysis and risk management because it enables controlled and rapid analysis (3 min) of T&O compounds in water at a low cost. Notably, principal component analysis indicated that E-tongue can discriminate and quantify eight T&O compounds at as low as 0.02 µg L-1 concentration. Further, partial least squares analysis confirmed that the sensor exhibits high sensitivity to concentration changes. The sensors with the highest variable importance in projection scores were determined to be SCS (1.39 and 1.38) for GE and MIB, CTS (1.34) for IPMP, CPS (1.33) for IBMP, AHS (1.42) for HA, ANS (1.22) for HD, and NMS (1.14 and 1.19) for ND and DN.

Fluorescence excitation-emission matrix spectroscopy coupled with parallel factor analysis to determine chlorine decay constants in urban water distribution system.

This study applied a method for estimating chlorine decay constant (k) in urban water distribution systems using fluorescence excitation-emission matrix spectroscopy-parallel factor analysis (FEEM-PARAFAC), considering that it accounts for the influence of organic matter in the target area. The simultaneous impacts of seasonal variations on chlorine consumption and dissolved organic matter (DOM) composition were investigated for a year in three full-scale water distribution systems in I city (areas S, K, and G). Bulk decay constants (kb) were obtained through bottle tests, and the kb value was observed to differ by season and significantly affected by temperature. It exhibited its highest value, 0.794 d-1, in summer at area G. As a result of analyses through F-EEM-PARAFAC, it was determined that the components of the target raw water were humic-like and tryptophan-like. The quantitative analysis of organic substances through PARAFAC revealed that area G had the highest score (C1+C2) than other areas. 11.568, 10.578, and 11.771 in summer at areas S, K, and G, respectively. The model equations were derived such that the significant (R2 = 0.85-0.95) correlation between the C1 and C2 model scores and total chlorine decay constants (kt) verified via PARAFAC analysis of the target raw water was considered. Furthermore, a method for obtaining the wall decay constants at a target point based on the correlation equation was investigated.

Comparative evaluation of 2-isopropyl-3-methoxypyrazine, 2-isobutyl-3-methoxypyrazine, and 2,4,6-trichloroanisole degradation by ultraviolet/chlorine and ultraviolet/hydrogen peroxide processes.

2-Isopropyl-3-methoxypyrazine (IPMP), 2-Isobutyl-3-methoxypyrazine (IBMP), and 2,4,6-Trichloroanisole (TCA) are the primary emerging taste and odor (T&O) compounds in water systems with low thresholds (ng L-1). The selected T&O compounds are known to be difficult to remove using conventional water treatment processes. In this study, we compared the removal characteristics of the three T&O compounds using UV/Cl2 and UV/H2O2. The removal rates of the three compounds by direct photolysis at 254 nm were less than 10%, even at a high UV dose (approximately 1000 mJ cm-2). Under conditions of an oxidant injection volume of 5 mg L-1 and UV dose of 1000 mJ cm-2, the degradation rate of the target compounds in the UV/H2O2 process exceeded that of the UV/Cl2 process. Moreover, the results revealed that pH has a significant impact on the removal of the T&O compounds during the UV/Cl2 process. The IPMP, IBMP, and TCA were found to be more reactive with hydroxyl radicals than reactive chlorine species (RCS). A predictive tool was developed to determine the optimal operating condition using the generalized reduced gradient (GRG) nonlinear solver. In the UV/H2O2 process, the EED value for 90% removing rate was 0.156 kWh m-3 for the IPMP, 0.135 kWh m-3 for the IBMP, and 0.154 kWh m-3 for the TCA, respectively. In case of the UV/Cl2, the EED value for 50% removing rate was 0.174 kWh m-3 for the IPMP, 0.138 kWh m-3 for the IBMP, and 0.169 kWh m-3 for the TCA, respectively.

Hydroxyl radical scavenging factor measurement using a fluorescence excitation-emission matrix and parallel factor analysis in ultraviolet advanced oxidation processes.

The performance of the UV/H2O2 advanced oxidation process (AOP) is dependent on water quality parameters, including the UV absorbance coefficient at 254 nm and hydroxyl radical (•OH) water background demand (scavenging factor, s-1). The •OH scavenging factor represents the •OH scavenging rate of the background substances in the water matrix, and it is known to be one of the key parameters to predict the performance of the UV/H2O2 process. The •OH scavenging factor has been determined experimentally by using a probe compound such as pCBA and rhodamine B. The experimental method has been validated to accurately predict the micropollutants removal in the UV/H2O2 process, but there is a need for an easier and simple method of determining the OH scavenging factor. We evaluated the alternative method to analyze the •OH scavenging factor using fluorescence excitation-emission matrix and parallel factor analysis (F-EEM/PARAFAC). The correlation between •OH scavenging factor and the spectroscopic characteristics and structure of different organic matter types was evaluated. Organic matter was characterized using a fluorescence excitation-emission matrix, parallel factor analysis, and liquid chromatography-organic carbon detection. Second-order reaction rates of humic acid sodium salt, sodium alginate, Suwannee River humic acid and bovine serum albumin were calculated as 1.30 × 108 M-1 s-1, 1.39 × 108 M-1 s-1, 1.03 × 108 M-1 s-1, and 3.17 × 107 M-1 s-1, respectively. Results of PARAFAC analysis, the ratio of humic and fulvic fluorescence component 2 to terrestrial humic-like fluorescence component 1 (C2/C1), and •OH scavenging factor showed high linearity. A predictive model, which combines with the F-EEM/PARAFAC method, predicted the optimal UV and H2O2 dose to achieve target compound removal.