Investigation of the effect of the water to powder ratio on hydraulic cement properties.

OBJECTIVE: The use of rheological properties to determine the optimal water: powder ratio of tricalcium silicate-based prototype materials incorporating alternative radiopacifiers and fillers. Determination of how the proportion of water incorporated affected the physicochemical behaviour of the materials. METHODS: Endodontic cements replaced with 30% radiopacifier, and additions of calcium phosphate and micro-silica were tested. The unmodified cements were mixed with a 0.35 water: powder ratio which served as control. At this water: powder ratio, unmodified Portland cement without any addition had an adequate consistency and furthermore it has been well characterized. Assessment of material rheological properties enabled adjustment of the water: powder ratio in each material to provide comparable viscosity values to those of the pure cement. The flowability, phase analysis and calcium release were measured for both viscosity-matched and the standard 0.35 water: powder ratio blends. The prototype materials with the adjusted water: powder ratios were also characterized by scanning electron microscopy, energy-dispersive spectroscopy and evaluated for radio-opacity. RESULTS: The use of the 0.35 water: powder ratio is not appropriate when changing the radiopacifier and incorporating additives. Zirconium oxide did not vary the water: powder ratio but tantalum oxide and calcium tungstate resulted in an increase and decrease in water demand respectively. Using the standard 0.35 ratio when the mixture had a low water demand resulted in higher flowability values and calcium release in solution. Micro-silica and calcium phosphate altered the hydration of the materials. All materials were adequately radiopaque. SIGNIFICANCE: Rheological assessment is an easy reproducible way to determine the water: powder ratios of materials with varying amounts of additives and radiopacifiers during development. Modifications to the water: powder ratio affects material properties.

Freshwater vulnerability under high end climate change. A pan-European assessment.

As freshwater availability is crucial for securing a sustainable, lower­carbon future, there is a critical connection between water management and climate policies. Under a rapidly changing climate, it is more important than ever to estimate the degree of future water security. This is a challenging task as it depends on many different variables: the degree of warming and its consequent effects on hydrological resources, the water demand by different sectors, and the possible ameliorations or deteriorations of the effects due to climate change adaptation and mitigation strategies. A simple and transparent conceptual framework has been developed to assess the European vulnerability to freshwater stress under the present hydro-climatic and socioeconomic conditions, in comparison to projections of future vulnerability for different degrees of global warming (1.5°C, 2°C and 4°C), under the high-rate warming scenario (RCP8.5). Different levels of adaptation to climate change are considered in the framework, by employing various relevant pathways of socioeconomic development. A spatially detailed pan-European map of vulnerability to freshwater shortage has been developed at the local administrative level, making this approach extremely useful for supporting regional level policymaking and implementation and strategic planning against future freshwater stress.

The threat of soil salinity: A European scale review.

Soil salinisation is one of the major soil degradation threats occurring in Europe. The effects of salinisation can be observed in numerous vital ecological and non-ecological soil functions. Drivers of salinisation can be detected both in the natural and man-made environment, with climate and the foreseen climate change also playing an important role. This review outlines the state of the art concerning drivers and pressures, key indicators as well as monitoring, modeling and mapping methods for soil salinity. Furthermore, an overview of the effect of salinisation on soil functions and the respective mechanism is presented. Finally, the state of salinisation in Europe is presented according to the most recent literature and a synthesis of consistent datasets. We conclude that future research in the field of soil salinisation should be focused on among others carbon dynamics of saline soil, further exploration of remote sensing of soil properties and the harmonization and enrichment of soil salinity maps across Europe within a general context of a soil threat monitoring system to support policies and strategies for the protection of European soils.