Topological Metamaterials.

The topological properties of an object, associated with an integer called the topological invariant, are global features that cannot change continuously but only through abrupt variations, hence granting them intrinsic robustness. Engineered metamaterials (MMs) can be tailored to support highly nontrivial topological properties of their band structure, relative to their electronic, electromagnetic, acoustic and mechanical response, representing one of the major breakthroughs in physics over the past decade. Here, we review the foundations and the latest advances of topological photonic and phononic MMs, whose nontrivial wave interactions have become of great interest to a broad range of science disciplines, such as classical and quantum chemistry. We first introduce the basic concepts, including the notion of topological charge and geometric phase. We then discuss the topology of natural electronic materials, before reviewing their photonic/phononic topological MM analogues, including 2D topological MMs with and without time-reversal symmetry, Floquet topological insulators, 3D, higher-order, non-Hermitian and nonlinear topological MMs. We also discuss the topological aspects of scattering anomalies, chemical reactions and polaritons. This work aims at connecting the recent advances of topological concepts throughout a broad range of scientific areas and it highlights opportunities offered by topological MMs for the chemistry community and beyond.

Beyond Bounds on Light Scattering with Complex Frequency Excitations.

Light scattering is one of the most established wave phenomena in optics, lying at the heart of light-matter interactions and of crucial importance for nanophotonic applications. Passivity, causality, and energy conservation imply strict bounds on the degree of control over scattering from small particles, with implications on the performance of many optical devices. Here, we demonstrate that these bounds can be surpassed by considering excitations at complex frequencies, yielding extreme scattering responses as tailored nanoparticles reach a quasi-steady-state regime. These mechanisms can be used to engineer light scattering of nanostructures beyond conventional limits for noninvasive sensing, imaging, and nanoscale light manipulation.

Coherent full polarization control based on bound states in the continuum.

Bound states in the continuum (BICs) are resonant modes of open structures that do not suffer damping, despite being compatible with radiation in terms of their momentum. They have been raising significant attention for their intriguing topological features, and their opportunities in photonics to enhance light-matter interactions. In parallel, the coherent excitation of optical devices through the tailored interference of multiple beams has been explored as a way to enhance the degree of real-time control over their response. Here, we leverage the combination of these phenomena, and exploit the topological features of BICs in the presence of multiple input beams to enable full polarization control on the entire Poincaré sphere in a photonic crystal slab only supporting a symmetry-protected BIC, experimentally demonstrating highly efficient polarization conversion controlled in real time through the superposition of coherent excitations. Our findings open exciting opportunities for a variety of photonic and quantum optics applications, benefitting from extreme wave interactions and topological features around BICs combined with optical control through coherent interference of multiple excitations.

Electrically driven reprogrammable phase-change metasurface reaching 80% efficiency.

Phase-change materials (PCMs) offer a compelling platform for active metaoptics, owing to their large index contrast and fast yet stable phase transition attributes. Despite recent advances in phase-change metasurfaces, a fully integrable solution that combines pronounced tuning measures, i.e., efficiency, dynamic range, speed, and power consumption, is still elusive. Here, we demonstrate an in situ electrically driven tunable metasurface by harnessing the full potential of a PCM alloy, Ge2Sb2Te5 (GST), to realize non-volatile, reversible, multilevel, fast, and remarkable optical modulation in the near-infrared spectral range. Such a reprogrammable platform presents a record eleven-fold change in the reflectance (absolute reflectance contrast reaching 80%), unprecedented quasi-continuous spectral tuning over 250 nm, and switching speed that can potentially reach a few kHz. Our scalable heterostructure architecture capitalizes on the integration of a robust resistive microheater decoupled from an optically smart metasurface enabling good modal overlap with an ultrathin layer of the largest index contrast PCM to sustain high scattering efficiency even after several reversible phase transitions. We further experimentally demonstrate an electrically reconfigurable phase-change gradient metasurface capable of steering an incident light beam into different diffraction orders. This work represents a critical advance towards the development of fully integrable dynamic metasurfaces and their potential for beamforming applications.

Observation of localized magnetic plasmon skyrmions.

Optical skyrmions have recently been constructed by tailoring vectorial near-field distributions through the interference of multiple surface plasmon polaritons, offering promising features for advanced information processing, transport and storage. Here, we provide experimental demonstration of electromagnetic skyrmions based on magnetic localized spoof plasmons (LSP) showing large topological robustness against continuous deformations, without stringent external interference conditions. By directly measuring the spatial profile of all three vectorial magnetic fields, we reveal multiple π-twist target skyrmion configurations mapped to multi-resonant near-equidistant LSP eigenmodes. The real-space skyrmion topology is robust against deformations of the meta-structure, demonstrating flexible skyrmionic textures for arbitrary shapes. The observed magnetic LSP skyrmions pave the way to ultra-compact and robust plasmonic devices, such as flexible sensors, wearable electronics and ultra-compact antennas.

Enhanced light-matter interaction in two-dimensional transition metal dichalcogenides.

Two-dimensional (2D) transition metal dichalcogenide (TMDC) materials, such as MoS2, WS2, MoSe2, and WSe2, have received extensive attention in the past decade due to their extraordinary electronic, optical and thermal properties. They evolve from indirect bandgap semiconductors to direct bandgap semiconductors while their layer number is reduced from a few layers to a monolayer limit. Consequently, there is strong photoluminescence in a monolayer (1L) TMDC due to the large quantum yield. Moreover, such monolayer semiconductors have two other exciting properties: large binding energy of excitons and valley polarization. These properties make them become ideal materials for various electronic, photonic and optoelectronic devices. However, their performance is limited by the relatively weak light-matter interactions due to their atomically thin form factor. Resonant nanophotonic structures provide a viable way to address this issue and enhance light-matter interactions in 2D TMDCs. Here, we provide an overview of this research area, showcasing relevant applications, including exotic light emission, absorption and scattering features. We start by overviewing the concept of excitons in 1L-TMDC and the fundamental theory of cavity-enhanced emission, followed by a discussion on the recent progress of enhanced light emission, strong coupling and valleytronics. The atomically thin nature of 1L-TMDC enables a broad range of ways to tune its electric and optical properties. Thus, we continue by reviewing advances in TMDC-based tunable photonic devices. Next, we survey the recent progress in enhanced light absorption over narrow and broad bandwidths using 1L or few-layer TMDCs, and their applications for photovoltaics and photodetectors. We also review recent efforts of engineering light scattering, e.g., inducing Fano resonances, wavefront engineering in 1L or few-layer TMDCs by either integrating resonant structures, such as plasmonic/Mie resonant metasurfaces, or directly patterning monolayer/few layers TMDCs. We then overview the intriguing physical properties of different van der Waals heterostructures, and their applications in optoelectronic and photonic devices. Finally, we draw our opinion on potential opportunities and challenges in this rapidly developing field of research.

Interface nano-optics with van der Waals polaritons.

Polaritons are hybrid excitations of matter and photons. In recent years, polaritons in van der Waals nanomaterials-known as van der Waals polaritons-have shown great promise to guide the flow of light at the nanoscale over spectral regions ranging from the visible to the terahertz. A vibrant research field based on manipulating strong light-matter interactions in the form of polaritons, supported by these atomically thin van der Waals nanomaterials, is emerging for advanced nanophotonic and opto-electronic applications. Here we provide an overview of the state of the art of exploiting interface optics-such as refractive optics, meta-optics and moiré engineering-for the control of van der Waals polaritons. This enhanced control over van der Waals polaritons at the nanoscale has not only unveiled many new phenomena, but has also inspired valuable applications-including new avenues for nano-imaging, sensing, on-chip optical circuitry, and potentially many others in the years to come.

Directional Modulation of Exciton Emission Using Single Dielectric Nanospheres.

Coupling emitters with nanoresonators is an effective strategy to control light emission at the subwavelength scale with high efficiency. Low-loss dielectric nanoantennas hold particular promise for this purpose, owing to their strong Mie resonances. Herein, a highly miniaturized platform is explored for the control of emission based on individual subwavelength Si nanospheres (SiNSs) to modulate the directional excitation and exciton emission of 2D transition metal dichalcogenides (2D TMDs). A modified Mie theory for dipole-sphere hybrid systems is derived to instruct the optimal design for desirable modulation performance. Controllable forward-to-backward intensity ratios are experimentally validated in 532 nm laser excitation and 635 nm exciton emission from a monolayer WS2 . Versatile light emission control is achieved for different emitters and excitation wavelengths, benefiting from the facile size control and isotropic shape of SiNSs. Simultaneous modulation of excitation and emission via a single SiNS at visible wavelengths significantly improves the efficiency and directionality of TMD exciton emission and leads to the potential of multifunctional integrated photonics. Overall, the work opens promising opportunities for nanophotonics and polaritonic systems, enabling efficient manipulation, enhancement, and reconfigurability of light-matter interactions.

Suppressing material loss in the visible and near-infrared range for functional nanophotonics using bandgap engineering.

All-dielectric nanostructures have recently opened exciting opportunities for functional nanophotonics, owing to their strong optical resonances along with low material loss in the near-infrared range. Pushing these concepts to the visible range is hindered by their larger absorption coefficient, thus encouraging the search for alternative dielectrics for nanophotonics. Here, we employ bandgap engineering to synthesize hydrogenated amorphous Si nanoparticles (a-Si:H NPs) offering ideal features for functional nanophotonics. We observe significant material loss suppression in a-Si:H NPs in the visible range caused by hydrogenation-induced bandgap renormalization, producing strong higher-order resonant modes in single NPs with Q factors up to ~100 in the visible and near-IR range. We also realize highly tunable all-dielectric meta-atoms by coupling a-Si:H NPs to photochromic spiropyran molecules. ~70% reversible all-optical tuning of light scattering at the higher-order resonant mode under a low incident light intensity is demonstrated. Our results promote the development of high-efficiency visible nanophotonic devices.

Coherent Perfect Diffraction in Metagratings.

Metasurfaces are 2D engineered structures with subwavelength granularity, offering a wide range of opportunities to tailor the impinging wavefront. However, fundamental limitations on their efficiency in wave transformation, associated with their deeply subwavelength thickness, challenge their implementation in practical application scenarios. Here, it is shown how the coherent control of metagratings through multiple wave excitations can provide new opportunities to achieve highly reconfigurable broadband metasurfaces with large diffraction efficiency, beyond the limitations of conventional approaches. Remarkably, energy distribution between the 0th and higher diffraction orders can be continuously tuned by changing the relative phase difference between two excitation waves, enabling coherent control, with added benefits of enhanced efficiency and bandwidth. This concept is demonstrated for a thin electric metagrating operating at terahertz frequencies, showing that coherent control can overcome several of the limitations of single-layer ultrathin metastructures, and extend their feasibility in various practical scenarios.

Topological polaritons and photonic magic angles in twisted α-MoO3 bilayers.

Twisted two-dimensional bilayer materials exhibit many exotic electronic phenomena. Manipulating the 'twist angle' between the two layers enables fine control of the electronic band structure, resulting in magic-angle flat-band superconductivity1,2, the formation of moiré excitons3-8 and interlayer magnetism9. However, there are limited demonstrations of such concepts for photons. Here we show how analogous principles, combined with extreme anisotropy, enable control and manipulation of the photonic dispersion of phonon polaritons in van der Waals bilayers. We experimentally observe tunable topological transitions from open (hyperbolic) to closed (elliptical) dispersion contours in bilayers of α-phase molybdenum trioxide (α-MoO3), arising when the rotation between the layers is at a photonic magic twist angle. These transitions are induced by polariton hybridization and are controlled by a topological quantity. At the transitions the bilayer dispersion flattens, exhibiting low-loss tunable polariton canalization and diffractionless propagation with a resolution of less than λ0/40, where λ0 is the free-space wavelength. Our findings extend twistronics10 and moiré physics to nanophotonics and polaritonics, with potential applications in nanoimaging, nanoscale light propagation, energy transfer and quantum physics.

Virtual Parity-Time Symmetry.

Parity-time (PT) symmetry has recently been opening exciting directions in photonics, yet the required careful balance of loss and gain has been hindering its widespread applicability. Here, we propose a gain-free route to PT symmetry by extending it to complex-frequency excitations that can mimic gain in passive systems. Based on the concept of virtual absorption, extended here to implement also virtual gain, we implement PT symmetry in the complex-frequency plane and realize its landmark effects, such as broken phase transitions, anisotropic transmission resonances, and laser-absorber pairs, in a fully passive, hence inherently stable, system. These results open a path to establish PT symmetry and non-Hermitian physics in passive platforms.

Moiré Hyperbolic Metasurfaces.

Recent advances in twistronics of low-dimensional materials, such as bilayer graphene and transition-metal dichalcogenides, have enabled a plethora of unusual phenomena associated with moiré physics. However, several of these effects require demanding manipulation of superlattices at the atomic scale, such as the careful control of rotation angle between two closely spaced atomic lattices. Here, we study moiré hyperbolic plasmons in pairs of hyperbolic metasurfaces (HMTSs), unveiling analogous phenomena at the mesoscopic scale. HMTSs are known to support confined surface waves collimated toward specific directions determined by the metasurface dispersion. By rotating two evanescently coupled HMTSs with respect to one another, we unveil rich dispersion engineering, topological transitions at magic angles, broadband field canalization, and plasmon spin-Hall phenomena. These findings open remarkable opportunities to advance metasurface optics, enriching it with moiré physics and twistronic concepts.

All-optical reconfigurable chiral meta-molecules.

Chirality is a ubiquitous phenomenon in the natural world. Many biomolecules without inversion symmetry such as amino acids and sugars are chiral molecules. Measuring and controlling molecular chirality at a high precision down to the atomic scale are highly desired in physics, chemistry, biology, and medicine, however, have remained challenging. Herein, we achieve all-optical reconfigurable chiral meta-molecules experimentally using metallic and dielectric colloidal particles as artificial atoms or building blocks to serve at least two purposes. One is that the on-demand meta-molecules with strongly enhanced optical chirality are well-suited as substrates for surface-enhanced chiroptical spectroscopy of chiral molecules and as active components in optofluidic and nanophotonic devices. The other is that the bottom-up-assembled colloidal meta-molecules provide microscopic models to better understand the origin of chirality in the actual atomic and molecular systems.

Dark-Exciton-Mediated Fano Resonance from a Single Gold Nanostructure on Monolayer WS2 at Room Temperature.

Strong spatial confinement and highly reduced dielectric screening provide monolayer transition metal dichalcogenides with strong many-body effects, thereby possessing optically forbidden excitonic states (i.e., dark excitons) at room temperature. Herein, the interaction of surface plasmons with dark excitons in hybrid systems consisting of stacked gold nanotriangles and monolayer WS2 is explored. A narrow Fano resonance is observed when the hybrid system is surrounded by water, and the narrowing of the spectral Fano linewidth is attributed to the plasmon-enhanced decay of dark K-K excitons. These results reveal that dark excitons in monolayer WS2 can strongly modify Fano resonances in hybrid plasmon-exciton systems and can be harnessed for novel optical sensors and active nanophotonic devices.

Nanophotonic engineering of far-field thermal emitters.

Thermal emission is a ubiquitous and fundamental process by which all objects at non-zero temperatures radiate electromagnetic energy. This process is often assumed to be incoherent in both space and time, resulting in broadband, omnidirectional light emission toward the far field, with a spectral density related to the emitter temperature by Planck's law. Over the past two decades, there has been considerable progress in engineering the spectrum, directionality, polarization and temporal response of thermally emitted light using nanostructured materials. This Review summarizes the basic physics of thermal emission, lays out various nanophotonic approaches to engineer thermal emission in the far field, and highlights several applications, including energy harvesting, lighting and radiative cooling.

Enhanced excitation and emission from 2D transition metal dichalcogenides with all-dielectric nanoantennas.

The recently emerged concept of all-dielectric nanophotonics based on optical Mie resonances in high-index dielectric nanoparticles has proven to be a promising pathway to boost light-matter interactions at the nanoscale. In this work, we discuss the opportunities enabled by the interaction of dielectric nanoresonators with 2D transition metal dichalcogenides (2D TMDCs), leading to weak and strong coupling regimes. We perform a comprehensive analysis of bright exciton photoluminescence (PL) enhancement from various 2D TMDCs, including WS2, MoS2, WSe2, and MoSe2 via their coupling to Mie resonances of a silicon nanoparticle. For each case, we find the system parameters corresponding to maximal PL enhancement taking into account excitation rate, Purcell factor and radiation efficiency. We demonstrate numerically that all-dielectric Si nanoantennas can significantly enhance the PL intensity from 2D TMDC by a factor of hundred through precise optimization of the geometrical and material parameters. Our results may be useful for high-efficiency 2D TMDC-based optoelectronic, nanophotonic, and quantum optical devices.