Nanocomposites Based on Thermoplastic Acrylic Resin with the Addition of Chemically Modified Multi-Walled Carbon Nanotubes.

The main goal of this work was an improvement in the mechanical and electrical properties of acrylic resin-based nanocomposites filled with chemically modified carbon nanotubes. For this purpose, the surface functionalization of multi-walled carbon nanotubes (MWCNTs) was carried out by means of aryl groups grafting via the diazotization reaction with selected aniline derivatives, and then nanocomposites based on ELIUM® resin were fabricated. FT-IR analysis confirmed the effectiveness of the carried-out chemical surface modification of MWCNTs as new bands on FT-IR spectra appeared in the measurements. TEM observations showed that carbon nanotube fragmentation did not occur during the modifications. According to the results from Raman spectroscopy, the least defective carbon nanotube structure was obtained for aniline modification. Transmission light microscopy analysis showed that the neat MWCNTs agglomerate strongly, while the proposed modifications improved their dispersion significantly. Viscosity tests confirmed, that as the nanofiller concentration increases, the viscosity of the mixture increases. The mixture with the highest dispersion of nanoparticles exhibited the most viscous behaviour. Finally, an enhancement in impact resistance and electrical conductivity was obtained for nanocomposites containing modified MWCNTs.

Structural Health Monitoring of Chemical Storage Tanks with Application of PZT Sensors.

Chemical pressure storage tanks are containers designed to store fluids at high pressures, i.e., their internal pressure is higher than the atmospheric pressure. They can come in various shapes and sizes, and may be fabricated from a variety of materials. As aggressive chemical agents stored under elevated pressures can cause significant damage to both people and the environment, it is essential to develop systems for the early damage detection and the monitoring of structural integrity of such vessels. The development of early damage detection and condition monitoring systems could also help to reduce the maintenance costs associated with periodic inspections of the structure and unforeseen operational breaks due to unmonitored damage development. It could also reduce the related environmental burden. In this paper, we consider a hybrid material composed of glass-fiber-reinforced polymers (GFRPs) and a polyethylene (PE) layer that is suitable for pressurized chemical storage tank manufacturing. GFRPs are used for the outer layer of the tank structure and provides the dominant part of the construction stiffness, while the PE layer is used for protection against the stored chemical medium. The considered damage scenarios include simulated cracks and an erosion of the inner PE layer, as these can be early signs of structural damage leading to the leakage of hazardous liquids, which could compromise safety and, possibly, harm the environment. For damage detection, PZT sensors were selected due to their widely recognized applicability for the purpose of structural health monitoring. For sensor installation, it was assumed that only the outer GFRP layer was available as otherwise sensors could be affected by the stored chemical agent. The main focus of this paper is to verify whether elastic waves excited by PZT sensors, which are installed on the outer GFRP layer, can penetrate the GFRP and PE interface and can be used to detect damage occurring in the inner PE layer. The efficiency of different signal characteristics used for structure evaluation is compared for various frequencies and durations of the excitation signal as well as feasibility of PZT sensor application for passive acquisition of acoustic emission signals is verified.

A Wind Tunnel Experimental Study of Icing on NACA0012 Aircraft Airfoil with Silicon Compounds Modified Polyurethane Coatings.

Ice formation on the aerodynamic surfaces of an aircraft is regarded as a major problem in the aerospace industry. Ice accumulation may damage parts, sensors and controllers and alter the aerodynamics of the airplane, leading to a range of undesired consequences, including flight delays, emergency landings, damaged parts and increased energy consumption. There are various approaches to reducing ice accretion, one of them being the application of icephobic coatings. In this work, commercially available polyurethane-based coatings were modified and deposited on NACA 0012 aircraft airfoils. A hybrid modification of polyurethane (PUR) topcoats was adopted by the addition of nanosilica and three-functional spherosilicates (a variety of silsesqioxane compound), which owe their unique properties to the presence of three different groups. The ice accretion on the manufactured nanocomposites was determined in an icing wind tunnel. The tests were performed under three different icing conditions: glaze ice, rime ice and mixed ice. Furthermore, the surface topography and wetting behavior (static contact angle and contact angle hysteresis) were investigated. It was found that the anti-icing properties of polyurethane nanocomposite coatings strongly depend on the icing conditions under which they are tested. Moreover, the addition of nanosilica and spherosilicates enabled the reduction of accreted ice by 65% in comparison to the neat topcoat.

Push-Out Method for Micro Measurements of Interfacial Strength in Aluminium Alloy Matrix Composites.

The main goal of this work was the evaluation of the interfacial strength of the carbon fibres/aluminium matrix interface dependently on the utilised composite fabrication method, namely high pressure die casting and gas pressure infiltration. In addition, the influence of a Ni-P coating on the C-fibres was investigated. The proposed measurements of the interfacial strength were carried out by means of the "push-out" method. The interfacial strength of the samples fabricated using the high-pressure infiltration method average between 19.03 MPa and 45.34 MPa.