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1.
Environ Sci Pollut Res Int ; 29(42): 64192-64204, 2022 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-35471761

RESUMO

This study refers to the development of hybrid briquettes using centrifuged sludge from the wastewater treatment of poultry and sawdust from furniture industry. The aim was to evaluate the performance of briquettes as a source of thermal energy, mitigating the risks of the current elimination and reducing the operational costs of their destination. To know the oxidizing characteristics of the briquettes and their mechanical resistance, superior calorific power, ash content, volatile materials, fixed carbon, and resistance to axial compression were evaluated. Thermogravimetric and differential exploratory calorimetry analyses were performed. Statistical treatments were carried out to verify the most significant factors to produce briquettes, the best proportions of the raw materials, and to evaluate whether there is interference from moisture and glue flour used as a binder. The best condition of the sludge-sawdust mixture was 15% and 85%, respectively, with 6.0% moisture. The best-case treatment had 23.82-MPa mechanical resistance, a calorific value of 17.20 MJ kg-1, and a density of 1374.15 kg m-3.


Assuntos
Matadouros , Esgotos , Animais , Biomassa , Carbono , Aves Domésticas
2.
Environ Technol ; 43(14): 2177-2189, 2022 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-33357113

RESUMO

During the poultry industrialization process the so-called sludge oil, a residual chicken fat, is recovered in the wastewater treatment plant and its use presents potential as raw material for biodiesel production. Thus, the aim of the study was to prepare blends of sludge oil with soybean oil to obtain fatty acid methyl esters (FAME) through the homogeneous alkaline transesterification reaction. To perform this study, a simple pre-treatment process - heating and subsequent filtration - was used, allowing sludge oil to be mixed with soybean oil to compose blends, without the need to use more sophisticated pre-treatment processes. After this step, blends ranging from 5% to 90% (m/m) of sludge oil mixed with soybean oil were prepared. The results showed that the molar ratio (1:6 oil blend:methanol), catalyst concentration 0.5% NaOH (mcat/moil), at 65 °C for 60 min yielded FAME above 99.0 and 90.0% (m/m) for blends with up to 5 and 15% sludge oil, respectively. By increasing the temperature to 70 °C, under the same selected parameters, the blend with 10% sludge oil provided yield above 99.0% (m/m), presenting appropriate physicochemical properties, within the parameters required by National Agency of Petroleum, Natural Gas and Biofuels (ANP). These findings show the great potential sludge oil provides to reduce Brazil's dependency on soybean oil for biodiesel production.Highlights Sludge oil, a waste raw material for biodiesel production, is not yet explored in Brazil.A procedure for biodiesel production using soybean oil and sludge oil blends was proposed.The best reaction condition was 1:6 oil blend:MeOH molar ratio; 0.5% NaOH (mcat/moil), at 70 °C for 60 min.Biodiesel yield was higher than 99% (m/m) under optimal reaction conditions.Sludge oil represents a promising waste raw material for biodiesel production.


Assuntos
Biocombustíveis , Óleo de Soja , Matadouros , Animais , Biocombustíveis/análise , Brasil , Catálise , Esterificação , Ácidos Graxos/química , Óleos de Plantas , Aves Domésticas , Esgotos , Hidróxido de Sódio , Óleo de Soja/química , Resíduos
3.
Braz. arch. biol. technol ; 61(spe): e18000015, 2018. graf
Artigo em Inglês | LILACS | ID: biblio-974135

RESUMO

ABSTRACT Sludge oil derived from the effluent generated in poultry abattoirs offers a promising biomass for the production of biodiesel. In this work, determination was made of its physicochemical characteristics, including acidity, density at 20ºC, peroxide index, moisture content, and saponification index, together with evaluation of a route for its conversion to biodiesel.


Assuntos
Biocombustíveis , Matadouros , Biomassa , Energia Renovável
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