Surface Roughness Effects on the Vibration Characteristics of AT-Cut Quartz Crystal Plate.

With the miniaturization and high-frequency requirements of quartz crystal sensors, microscopic issues affecting operating performance, e.g., the surface roughness, are receiving more and more attention. In this study, the activity dip caused by surface roughness is revealed, with the physical mechanism clearly demonstrated. Firstly, the surface roughness is considered as a Gaussian distribution, and the mode coupling properties of an AT-cut quartz crystal plate are systematically investigated under different temperature environments with the aid of two-dimensional thermal field equations. The resonant frequency, frequency-temperature curves, and mode shapes of the quartz crystal plate are obtained through the partial differential equation (PDE) module of COMSOL Multiphysics software for free vibration analysis. For forced vibration analysis, the admittance response and phase response curves of quartz crystal plate are calculated via the piezoelectric module. The results from both free and forced vibration analyses demonstrate that surface roughness reduces the resonant frequency of quartz crystal plate. Additionally, mode coupling is more likely to occur in a crystal plate with a surface roughness, leading to activity dip when temperature varies, which decreases the stability of quartz crystal sensors and should be avoided in device fabrication.

Morphology of Mixed Langmuir and Langmuir-Schaefer Monolayers with Covered CdSe/CdS/ZnS Quantum Dots and Arachidic Acid.

The process of formation of a Langmuir-Schaefer (LS) matrix based on a mixed monolayer of arachidic acid (AA) and 8 nm CdSe/CdS/ZnS quantum dots (QDs) stabilized by molecules of trioctylphosphine oxide (TOPO) was investigated. The change in the morphology, monolayer compressibility, and area per elementary cell of the created mixed monolayers, depending on the ratio of the components, was studied. It is shown that the change in the morphology of Langmuir-Blodgett (LB) monolayers begins to occur at a ratio between the number of QDs and AA molecules of 1:24. Dendrimeric structures with a thickness of the order of 30-40 nm appear in the mixed monolayer when LB film deposition was carried out above the collapse surface pressure of a Langmuir film from only TOPO-covered QDs. Information on the dependence of the morphology of such structures on the molar ratio of the components is necessary for the production of ordered 2D nanostructures containing 0D and 1D objects with quantum bonds. Such nanostructures can be used in nanoelectronic and optoelectronic devices as a sensitive sensor element. The obtained results would be relevant for any type of spherical shape nanoparticles.

A Theoretical Model for Analyzing the Thickness-Shear Vibration of a Circular Quartz Crystal Plate With Multiple Concentric Ring Electrodes.

A dynamic model to analyze the thickness-shear vibration of a circular quartz crystal plate with multiple concentric ring electrodes on its upper and bottom surfaces is established with the aid of coordinate transformation. The theoretical solution is obtained, which can be written in a superposition form of Mathieu functions and modified Mathieu functions. The convergence of the solution is demonstrated, and the correctness is numerically validated via results from the finite element method (FEM). Subsequently, a systematic investigation is carried out to quantify the effect of the electrode size on the energy trapping phenomenon, i.e., the resonant frequency and mode shape, which reveals that the ring electrode has a great influence on the work performance of resonators. With the increase of the electrode inertia, i.e., the radius and mass ratio, new trapped modes emergence with the vibration mainly focused on the plate with partial electrodes. Besides, owing to the anisotropy, degenerated trapped modes have different resonant frequencies and the frequency discrepancy between them will become smaller for higher modes. Finally, the influence of multiple ring electrodes is investigated, and the qualitative analysis and quantitative results demonstrate that multiple ring electrodes will lead to a more uniform mass sensitivity compared with a single ring electrode. The outcome is widely applicable, which can provide theoretical guidance for the structural design and manufacturing of quartz resonators, as well as a thorough interpretation about the underlying physical mechanism.

Comparative Study of Electrochemical Sensors Based on Enzyme Immobilized into Polyelectrolyte Microcapsules and into Chitosan Gel.

The characteristics of an electrochemical biosensor based on a Prussian-blue screen-printed electrode containing glucose oxidase incorporated into polyelectrolyte microcapsules (PMC) are considered. PMC with the embedded enzyme were formed using sodium polystyrene sulfonate and poly(allylamine hydrochloride). The characteristics were compared with those of the enzyme immobilized in chitosan gel. We assessed the dependences of biosensor signals on the composition of the buffer solution, on the glucose concentration; the operational and long-term stabilities. The enzyme immobilized in PMC proved to be more sensitive to buffer molarity at a maximum within 35 - 40 mM. The apparent Michaelis constants were 1.5 and 4.1 mM at the immobilization in, respectively, chitosan and PMC. The developed biosensors were used to assay commercial juices. The biosensors' data on the glucose contents were shown to have a high correlation with the standard spectrophotometric assay (0.92 - 0.95%), which implies a possible application of the fabricated biosensors in foodstuff analysis.

Super high sensitive plate acoustic wave humidity sensor based on graphene oxide film.

The changes of density and elastic modules due to water vapor adsorption are measured for graphene oxide film at room temperature. Dominant mechanism for acoustic wave humidity sensing by the film is shown to be related with variation of its electric conductivity. Basing on the data, super high sensitive humidity sensor employing high-order Lamb wave with large coupling constant, standard lithium niobate plate, and graphene oxide sorbent film is developed. The minimal detectable level of the sensor is as low 0.03% RH, response times are 60/120s, and reproducibility is ±2.5%. The sensor is completely selective towards H2, CO, CH4, NO, O2.

Gasoline identifier based on SH0 plate acoustic waves.

The present paper is devoted to the development of gasoline identifier based on zero order shear-horizontal (SH0) acoustic wave propagating in piezoelectric plate. It has been found that the permittivity of gasoline is increased when its octane number rises. The development of such identifier is experimentally demonstrated to be possible.

Liquid sensor based on a piezoelectric lateral electric field-excited resonator.

The influence of viscous and conducting liquid on the characteristics of a piezoelectric lateral electric field-excited resonator based on the X-cut lithium niobate plate has been investigated. It has been found that the contact of a free surface of such resonator with conducting or viscous liquid leads to the substantial variation of its electrical impedance/admittance. The analysis has shown the modulus of electrical impedance or admittance at any frequency near the parallel or series resonance to be a parameter unambiguously associated with the conductivity or the viscosity. This parameter is more sensitive to the variation of the liquid conductivity or viscosity as compared to the widely used for this purpose resonant frequency whose variation area is essentially smaller. By this means the liquid conductivity and viscosity affects unambiguously on the change of electrical impedance and admittance modulus whose measurement at a fixed frequency should present no problem in practice. Consequently, the lateral field excited resonator we have described may be employed as a liquid conductivity and viscosity meter with an appropriate graduation.

Acoustic waves in a structure containing two piezoelectric plates separated by an air (vacuum) gap.

This paper presents experimental results for the characteristics of acoustic waves propagating in a structure containing two parallel piezoelectric plates (I and II) separated by an air gap. Plate I, made of Y-X lithium niobate, contained two interdigital transducers that excited and received an acoustic wave with shear-horizontal polarization. Piezoelectric plate II, made of lithium niobate, was placed above and between the transducers, separated by a fixed gap. For its certain orientation, the amplitude-frequency characteristic showed sharply defined resonant attenuation peaks, which were situated at an equidistant separation from each other. The depth of the peaks was observed to decrease with a wider gap between the plates. It has been stated that these peaks are associated with the resonant reflections of a slot acoustic wave across the width of plate II. Experimentally determined phase velocities and electromechanical coupling coefficient for the slot wave in the structure under study are in a good agreement with theoretical values for various crystallographic orientations of plate II. A comparison between the experimental and theoretical results has allowed us to state two conditions for the slot wave to exist. The structures described may be employed for noncontact excitation of acoustic waves in the plates and for the development of various liquid, gas, and temperature sensors.

Biological sensor based on a lateral electric field-excited resonator.

This paper describes a biological sensor based on a lateral electric field-excited resonator using an X-cut lithium niobate plate. Its potential was shown through the example of biological interaction between bacterial cells and specific bacteriophages. The detection was based on the analysis of the measured real and imaginary parts of electrical impedance for a resonator loaded by the biological suspension under study. It has been shown that the sensor is sensitive to specific interactions between bacterial cells and specific bacteriophages in a pure state as well as in the presence of extraneous microflora. The degree of electrical impedance variation resulting from the biological interaction depends on the numbers of phage particles and bacteria cells. The sensor may be used not only for the qualitative analysis of bacteria but also for their quantitative detection.

Elastic and viscous properties of nanocomposite films based on low-density polyethylene.

The physical properties of nanocomposite materials which contain nanoparticles of metals and their compounds stabilized within a polymeric dielectric matrix are currently being studied. These materials show a low acoustic impedance, resulting in their use as low-perturbing substrates for thin piezoelectric plates, as well as matching and damping layers for bulk acoustic wave devices. Mechanical properties of the materials which contain various Fe and Fe2O3 nanoparticle concentrations are experimentally defined in the paper. It has been shown that the acoustic impedance of the materials under study may be varied by more than 30% and 40% for longitudinal and shear acoustic waves, respectively, within the same technological procedure. The velocities of bulk longitudinal and shear acoustic waves can be purposefully changed by more than 40% and 29%, respectively.

The power flow angle of acoustic waves in thin piezoelectric plates.

The curves of slowness and power flow angle (PFA) of quasi-antisymmetric (A(0)) and quasi-symmetric (S(0)) Lamb waves as well as quasi-shear-horizontal (SH(0)) acoustic waves in thin plates of lithium niobate and potassium niobate of X-,Y-, and Z-cuts for various propagation directions and the influence of electrical shorting of one plate surface on these curves and PFA have been theoretically investigated. It has been found that the group velocity of such waves does not coincide with the phase velocity for the most directions of propagation. It has been also shown that S(0) and SH(0) wave are characterized by record high values of PFA and its change due to electrical shorting of the plate surface in comparison with surface and bulk acoustic waves in the same material. The most interesting results have been verified by experiment. As a whole, the results obtained may be useful for development of various devices for signal processing, for example, electrically controlled acoustic switchers.

The peculiarities of energy characteristics of acoustic waves in piezoelectric materials and structures.

This paper is devoted to detailed theoretical investigation of energy density and power flow of homogeneous (bulk) and inhomogeneous (surface and plate) plane acoustic waves in piezoelectric materials and structures. The analysis of these waves in different materials of various crystallographic orientations allowed us to establish some energy regularities. These regularities are the same for instantaneous energy characteristics of homogeneous waves and for time-average energy characteristics on unit of aperture of inhomogeneous waves if the electrical energy and power flow in vacuum are taken into account. It has been shown that, for strong piezoactive waves, the electric energy density may exceed the mechanical energy density more than three times.

New method of change in temperature coefficient delay of acoustic waves in thin piezoelectric plates.

As is well-known, the development of high-effective and thermostable acoustic devices assumes using the acoustic waves with high coefficient of electromechanical coupling (K2) and low temperature coefficient of delay (TCD). At present, it also is well-known that fundamental shear horizontal (SH0) acoustic waves in thin piezoelectric plates possess by significantly more electromechanical coupling compared to surface acoustic waves (SAW) in the same material. However, although the value of TCD of SH0 waves is insignificantly less than for SAW, this is not enough for development of thermostable devices. This paper suggests a new way of decreasing TCD of SH0 waves in piezoelectric plates at a high level of electromechanical coupling. This way assumes to use the structure containing the piezoelectric plate and liquid with the special dependence of permittivity on temperature. Theoretical and experimental investigation showed that, for SH0 wave in YX LiNbO3 plate at hf = 700 m/s (h = plate thickness, f = wave frequency) the presence of butyl acetate can decrease the value of TCD by six times at K2 = 30%. In a whole the obtained results open the wide prospect of using SH0 wave in thin piezoelectric plate for development of high effective and thermo-stable acoustic devices.

Transmission of surface acoustic waves through the interface based on discontinuity of electrical boundary conditions on surface of potassium niobate.

This paper presents theoretical investigation of the propagation of surface acoustic waves (SAWs) across the boundary between metallized (electrically shorted) and unmetallized (electrically open) regions on the surface of potassium niobate crystals. Potassium niobate is a very strong piezoelectric material and has the interesting property that only one type of SAW, namely a Rayleigh wave, can exist on unmetallized surface, where as two types of SAWs, namely Rayleigh and Bleustein-Gulyaev (BG), can exist on a metallized surface. Analysis shows that the Rayleigh wave propagates through the interface with very little change in amplitude or polarization. On the other hand, almost total reflection of the BG wave is expected. Details of the theoretical analysis and calculated results will be presented.

The energy density and power flow of acoustic waves propagating in piezoelectric materials.

It is shown that, for plane bulk acoustic wave propagating in arbitrary piezoelectric media, the densities of mechanoelectrical and electromechanical energies are always equal in absolute value and have opposite signs. However, in general, the mechanoelectrical and electromechanical power flows of such wave calculated by traditional expression for Poynting vector do not compensate each other, although the total density of these energies is always equal to zero. Discovered discrepancy based on the dissymmetry of piezoelectric constants with respect to the electrical and mechanical indexes may cause difficulties for calculation of important parameters for practical applications such as energy transport velocity of acoustic waves in piezoelectric materials.

Reflection of plate acoustic waves produced by a periodic array of mechanical load strips or grooves.

The reflection of fundamental acoustic waves propagating in a thin piezoelectric plate by a periodic array of conducting strips of finite thickness or grooves has been theoretically and experimentally investigated. The analysis has shown that electrical shorting and mass loading affect the relationship of neighboring region impedances in a contrary manner. In some cases, these effects are comparable, and there exists a certain strip thickness for each piezoactive fundamental plate mode at which the reflection coefficient can become zero. A high efficiency of grooved reflector for plate acoustic waves was theoretically revealed. Experimental results for mass loading and grooved reflections, which have been obtained for an SH0 wave propagating in the Y-X lithium niobate plate, are in a good agreement with the theory. They show a high efficiency of such reflectors and confirm an opportunity of using a model based on equivalent circuit for the analysis of their operation. Investigations indicate that nearly 100% reflection of the SH0 wave in the lithium niobate plate can be obtained with the use of a mass loading reflector containing 10 silver strips of thickness d/h = 0.08 or a grooved reflector containing eight grooves of depth d/h = 0.25. Here h is the plate thickness and d is the reflector thickness or depth.