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1.
Org Biomol Chem ; 18(42): 8746, 2020 Nov 04.
Artigo em Inglês | MEDLINE | ID: mdl-33084714

RESUMO

Correction for 'A multi-component reaction for the synthesis of pyrido [1,2-b] isoquinoline derivatives via the [3 + 2] cycloaddition reaction between alkynes and in situ generated isoquinolinium ylides' by Sundar S. Shinde et al., Org. Biomol. Chem., 2019, 17, 4121-4128, DOI: 10.1039/C9OB00560A.

2.
Org Biomol Chem ; 17(16): 4121-4128, 2019 04 17.
Artigo em Inglês | MEDLINE | ID: mdl-30968921

RESUMO

An efficient and one-pot tandem procedure for the synthesis of fused ethanopyrido [1,2-b] isoquinoline derivatives from ninhydrin, proline and alkynes has been developed. This strategy exhibits an unprecedented [3 + 2] cycloaddition reaction between alkynes and isoquinolinium ylide (1,3 dipole) generated in situ from proline and ninhydrin. This newly developed methodology features simple operation and is metal free. In this methodology overall three new C-C bonds, two C-N bonds, and three new rings are formed in a single step process.

3.
J Org Chem ; 74(12): 4608-11, 2009 Jun 19.
Artigo em Inglês | MEDLINE | ID: mdl-19518151

RESUMO

Herein we present magnetically recoverable and reusable copper ferrite nanoparticles for asymmetric hydrosilylation of several ketones. Up to 99% enantiometric excess was obtained at room temperature using polymethylhydrosiloxane as the stoichiometric reducing agent. The copper ferrite nanoparticles were magnetically separated, and the efficiency of the catalyst remains almost unaltered up to three cycles.

4.
Org Lett ; 10(14): 2979-82, 2008 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-18563909

RESUMO

A catalyst system consisting of a copper-aluminum hydrotalcite-chiral diphosphine ligand effects asymmetric hydrosilylation of several ketones, using polymethylhydrosiloxane (PMHS) as the stoichiometric reducing agent at room temperature, with moderate-to-excellent enantioselectivities. The catalyst is recovered by simple centrifugation, and the efficiency of the catalyst remains almost unaltered even after several cycles.

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