A Review of Recent Progresses on Olive Oil Chemical Profiling, Extraction Technology, Shelf-life, and Quality Control.

Olive oil (OO) is widely recognized as a main component in the Mediterranean diet owing to its unique chemical composition and associated health-promoting properties. This review aimed at providing readers with recent results on OO physicochemical profiling, extraction technology, and quality parameters specified by regulations to ensure authentic products for consumers. Recent research progress on OO adulteration were outlined through a bibliometric analysis mapping using Vosviewer software. As revealed by bibliometric analysis, richness in terms of fatty acids, pigments, polar phenolic compounds, tocopherols, squalene, sterols, and triterpenic compounds justify OO health-promoting properties and increasing demand on its global consumption. OO storage is a critical post-processing operation that must be optimized to avoid oxidation. Owing to its great commercial value on markets, OO is a target to adulteration with other vegetable oils. In this context, different chemometric tools were developed to deal with this problem. To conclude, increasing demand and consumption of OO on the global market is justified by its unique composition. Challenges such as oxidation and adulteration stand out as the main issues affecting the OO market.

Spent coffee grounds: A sustainable approach toward novel perspectives of valorization.

Coffee is one of the most popular and preferred drinks in the world, being consumed for its refreshing and energizing properties. As a result, the consumption of coffee generates millions of tons of waste, in particular, spent coffee grounds (SCG). On the contrary, food waste recovery is an incredibly sustainable and convenient solution to the growing need for materials, fuels, and chemicals. SCG has been developed as a precious resource of several high value-added products (oil, proteins, minerals, fatty acids, sterols….). Thus, a transformative pathway to a circular economy that involves the valorization of coffee wastes and by-products is currently attracting the attention of researchers worldwide. The potential growth of scientific papers and publications promotes a comprehensive review to determine the research hotspots, knowledge structure, and to consider future avenues and challenges. Therefore, in this paper, we conducted a systematic review based on 275 indexed papers on the composition and valorization of SCG as a prospective environmental source. PRACTICAL APPLICATIONS: SCG can be applied in agro-food industries.

Mineral Profiling of Twenty Wild and Cultivated Aromatic and Medicinal Plants Growing in Morocco.

Aromatic and medicinal plants (AMPs) have attracted a considerable attention owing to their medicinal and nutritional value. The main research focus in AMPs is devoted to bioactive compounds and related biological activities; however, little is known about their mineral profiling, hence the novelty of this work, which aims at investigating the mineral composition of 20 species of AMPs belonging to 10 botanical families growing in Morocco. Mineral profiling was determined using an inductively coupled plasma optical emission spectrometer in various plant parts depending on each species. Wide variations were found in mineral content among the studied plants. Major elements were K (3987.49 ± 319.01-36,707.01 ± 2936.56 mg/kg), Ca (862.54 ± 69.86-32,836.15 ± 2626.89 mg/kg), P (1065.77 ± 86.33-6328.83 ± 506.32 mg/kg), Mg (986.96 ± 79.66-4935.41 ± 394.82 mg/kg), and Na (28.21 ± 2.23-5792.26 ± 463.38 mg/kg). Fe (62.09 ± 4.96-1636.24 ± 130.89 mg/kg), Mn (10.63 ± 0.85-124.72 ± 9.85 mg/kg), B (5.64 ± 0.45-71.33 ± 5.71 mg/kg), Zn (8.94 ± 0.72-47.01 ± 3.76 mg/kg), and Cu (2.06 ± 0.14-15.12 ± 1.20 mg/kg) were detected at minor levels. Most of the investigated plants were shown to be good sources of minerals. Important correlations were found among different minerals. These outcomes were confirmed by principal component analysis, which separate among studied plants and minerals through the first two principal components. According to obtained results, the studied plants could provide a new promising source of necessary minerals for human diet as well as other various applications.

High thiabendazole fungicide uptake using Cellana tramoserica shells modified by copper: characterization, adsorption mechanism, and optimization using CCD-RSM approach.

In this paper, Cellana tramoserica (CT) shells were modified by copper and used as an adsorbent to remove thiabendazole (TBZ) from aqueous media. The removal efficiency of TBZ onto CT shells and modified Cellana tramoserica (CT-Cu) shells was investigated by considering the following parameters: initial pesticide concentration, solution pH, agitation time, temperature, and adsorbent mass. The experimental results show that the pseudo-first-order and Langmuir models well describe the adsorption process. The maximum adsorption amount for CT and CT-Cu is 319.68 mg/g and 376.12 mg/g, respectively. CT-Cu showed higher TBZ removal efficiency than CT, explained by the ligand exchange between the water and the pesticide molecules in the metal coordination sphere. Response surface methodology combined with central composite design (RSM-CCD) was used to optimize the adsorption conditions. Optimized values were obtained at 5 for pH, 50 ppm, 120 min, and 20 mg of CT-Cu adsorbent. Under these optimal conditions, 91% of TBZ was removed by adsorption onto CT-Cu. Graphical abstract.

Efficient removal of p-nitrophenol from water using montmorillonite clay: insights into the adsorption mechanism, process optimization, and regeneration.

The present research highlights the use of a montmorillonite clay to remove p-nitrophenol (PNP) from aqueous solution. The montmorillonite clay was characterized using powder X-ray diffraction, Fourier-transformed infrared spectroscopy, scanning electron microscopy, X-ray fluorescence, Brunauer-Emmett-Teller analyses, and zero point charge in order to establish the adsorption behavior-properties relationship. The physiochemical parameters like pH, initial PNP concentration, and adsorbent dose as well as their binary interaction effects on the PNP adsorption yield were statistically optimized using response surface methodology. As a result, 99.5% removal of PNP was obtained under the optimal conditions of pH 2, adsorbent dose of 2 g/l, and PNP concentration of 20 mg/l. The interaction between adsorbent dose and initial concentration was the most influencing interaction on the PNP removal efficiency. The mass transfer of PNP at the solution/adsorbent interface was described using pseudo-first-order and intraparticle diffusion. Langmuir isotherm well fitted the experimental equilibrium data with a satisfactory maximum adsorption capacity of 122.09 mg/g. The PNP adsorption process was thermodynamically spontaneous and endothermic. The regeneration study showed that the montmorillonite clay exhibited an excellent recycling capability. Overall, the montmorillonite clay is very attractive as an efficient, low-cost, eco-friendly, and recyclable adsorbent for the remediation of hazardous phenolic compounds in industrial effluents.