Electrocatalytic coupled biofilter for treating cyclohexanone-containing wastewater: Degradation, mechanism and optimization.

Electrocatalytic coupled biofilter (EBF) technology organically integrates the characteristics of electrochemistry and microbial redox, providing ideas for effectively improving biological treatment performance. In this study, an EBF system was developed for enhanced degradation of cyclohexanone in contaminated water. Experimental results show that the system can effectively remove cyclohexanone in contaminated water. Under the optimal parameters, the removal rates of cyclohexanone, TP, NH4+-N and TN were 97.61 ± 1.31%, 76.31 ± 1.67%, 94.14 ± 2.13% and 95.87 ± 1.01% respectively. Degradation kinetics studies found that electrolysis, adsorption, and biodegradation pathways play a major role in the degradation of cyclohexanone. Microbial community analysis indicates that voltage can affect the structure of the microbial community, with the dominant genera shifting from Acidovorax (0 V) to Brevundimonas (0.7 V). Additionally, Acidovorax, Cupriavidus, Ralstonia, and Hydrogenophaga have high abundance in the biofilm and can effectively metabolize cyclohexanone and its intermediates, facilitating the removal of cyclohexanone. In summary, this research can guide the development and construction of highly stable EBF systems and is expected to be used for advanced treatment of industrial wastewater containing cyclohexanone.

Boron-doped reduced graphene oxide as an efficient cathode in microbial fuel cells for biological toxicity detection.

Electrodes with superior stability and sensitivity are highly desirable in advancing the toxicity detection efficiency of microbial fuel cells (MFCs). Herein, boron-doped reduced graphene oxide (B-rGO) was synthesized and utilized as an efficient cathode candidate in an MFCs system for sensitive sodium dodecylbenzene sulfonate (SDBS) detection. Boron doping introduces additional defects and improves the dispersibility and oxygen permeability, thereby enhancing the oxygen reduction reaction (ORR) efficiency. The B-rGO-based cathode has demonstrated significantly improved output voltage and power density, marking improvements of 75 % and 58 % over their undoped counterparts, respectively. Furthermore, it also exhibited remarkable linear sensitivity to SDBS concentrations across a broad range (0.2-15 mg/L). Notably, the cathode maintained excellent stability within the test range and showed significant reversibility for SDBS concentrations between 0.2 and 3 mg/L. The highly sensitive and stable B-rGO-based cathode is inspiring for developing more practical and cost-effective toxicant sensing devices.