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1.
Entropy (Basel) ; 25(1)2023 Jan 09.
Artigo em Inglês | MEDLINE | ID: mdl-36673275

RESUMO

Rotating-disc electrodes (RDEs) are favored technologies for analyzing electrochemical processes in electrically charged cells and other revolving machines, such as engines, compressors, gearboxes, and generators. The model is based on the concept of the nonlinear entropy convection-diffusion equations, which are constructed using semi-boundaries as an infinite notion. In this model, the surrogate solutions with different parameter values for the mathematical characterization of non-dimensional OH- and H+ ion concentrations at a rotating-disc electrode (RDE) are investigated using an intelligent hybrid technique by utilizing neural networks (NN) and the Levenberg-Marquardt algorithm (LMA). Reference solutions were calculated using the RK-4 numerical method. Through the training, validation, and testing sampling of reference solutions, the NN-BLMA approximations were recorded. Error histograms, absolute error, curve fitting graphs, and regression graphs validated the NN-BLMA's resilience and accuracy for the problem. Additionally, the comparison graphs between the reference solution and the NN-BLMA procedure established that our paradigm is reliable and accurate.

2.
Nanomaterials (Basel) ; 12(13)2022 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-35808108

RESUMO

This paper investigates the heat transfer of two-phase nanofluid flow between horizontal plates in a rotating system with a magnetic field and external forces. The basic continuity and momentum equations are considered to formulate the governing mathematical model of the problem. Furthermore, certain similarity transformations are used to reduce a governing system of non-linear partial differential equations (PDEs) into a non-linear system of ordinary differential equations. Moreover, an efficient stochastic technique based on feed-forward neural networks (FFNNs) with a back-propagated Levenberg-Marquardt (BLM) algorithm is developed to examine the effect of variations in various parameters on velocity, gravitational acceleration, temperature, and concentration profiles of the nanofluid. To validate the accuracy, efficiency, and computational complexity of the FFNN-BLM algorithm, different performance functions are defined based on mean absolute deviations (MAD), error in Nash-Sutcliffe efficiency (ENSE), and Theil's inequality coefficient (TIC). The approximate solutions achieved by the proposed technique are validated by comparing with the least square method (LSM), machine learning algorithms such as NARX-LM, and numerical solutions by the Runge-Kutta-Fehlberg method (RKFM). The results demonstrate that the mean percentage error in our solutions and values of ENSE, TIC, and MAD is almost zero, showing the design algorithm's robustness and correctness.

3.
Materials (Basel) ; 15(2)2022 Jan 17.
Artigo em Inglês | MEDLINE | ID: mdl-35057391

RESUMO

In this paper, a mathematical model for the rolling motion of ships in random beam seas has been investigated. The ships' steady-state rolling motion with a nonlinear restoring moment and damping effect is modeled by the nonlinear second-order differential equation. Furthermore, an artificial neural network (NN)-based, backpropagated Levenberg-Marquardt (LM) algorithm is utilized to interpret a numerical solution for the roll angle (x(t)), velocity (x'(t)), and acceleration (x''(t)) of the ship in random beam seas. A reference data set based on numerical examples of the mathematical model for a rolling ship for the LM-NN algorithm is generated by the numerical solver Runge-Kutta method of order 4 (RK-4). The LM-NN algorithm further uses the created data set for the validation, testing, and training of approximate solutions. The outcomes of the design paradigm are compared with those of the homotopy perturbation method (HPM), optimal homotopy analysis method (OHAM), and RK-4. Statistical analyses of the mean square error (MSE), regression, error histograms, proportional performance, and computational complexity further validate the worth of the LM-NN algorithm.

4.
Molecules ; 26(23)2021 Dec 02.
Artigo em Inglês | MEDLINE | ID: mdl-34885892

RESUMO

In this study, we have investigated the mathematical model of an immobilized enzyme system that follows the Michaelis-Menten (MM) kinetics for a micro-disk biosensor. The film reaction model under steady state conditions is transformed into a couple differential equations which are based on dimensionless concentration of hydrogen peroxide with enzyme reaction (H) and substrate (S) within the biosensor. The model is based on a reaction-diffusion equation which contains highly non-linear terms related to MM kinetics of the enzymatic reaction. Further, to calculate the effect of variations in parameters on the dimensionless concentration of substrate and hydrogen peroxide, we have strengthened the computational ability of neural network (NN) architecture by using a backpropagated Levenberg-Marquardt training (LMT) algorithm. NNs-LMT algorithm is a supervised machine learning for which the initial data set is generated by using MATLAB built in function known as "pdex4". Furthermore, the data set is validated by the processing of the NNs-LMT algorithm to find the approximate solutions for different scenarios and cases of mathematical model of micro-disk biosensors. Absolute errors, curve fitting, error histograms, regression and complexity analysis further validate the accuracy and robustness of the technique.


Assuntos
Técnicas Biossensoriais , Enzimas Imobilizadas/química , Algoritmos , Biocatálise , Técnicas Biossensoriais/instrumentação , Difusão , Cinética , Modelos Biológicos
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