Review of per- and poly-fluoroalkyl treatment in combustion-based thermal waste systems in the United States.

Per- and poly-fluoroalkyl substances (PFAS) are a class of synthetic chemicals known for their widespread presence and environmental persistence. Carbon-fluorine (C-F) bonds are major components among PFAS and among the strongest organic bonds, thus destroying PFAS may present significant challenge. Thermal treatment such as incineration is an effective and approved method for destroying many halogenated organic chemicals. Here, we present the results of existing studies and testing at combustion-based thermal treatment facilities and summarize what is known regarding PFAS destruction and mineralization at such units. Available results suggest the temperature and residence times reached by some thermal treatment systems are generally favorable to the destruction of PFAS, but the possibility for PFAS or fluorinated organic byproducts to escape destruction and adequate mineralization and be released into the air cannot be ruled out. Few studies have been conducted at full-scale operating facilities, and none to date have attempted to characterize possible fluorinated organic products of incomplete combustion (PICs). Further, the ability of existing air pollution control (APC) systems, designed primarily for particulate and acid gas control, to reduce PFAS air emissions has not been determined. These data gaps remain primarily due to the previous lack of available methods to characterize PFAS destruction and PIC concentrations in facility air emissions. However, newly developed stack testing methods offer an improved understanding of the extent to which thermal waste treatment technologies successfully destroy and mineralize PFAS in these waste streams.

A critical review of perfluoroalkyl and polyfluoroalkyl substances (PFAS) landfill disposal in the United States.

Landfills manage materials containing per- and polyfluoroalkyl substances (PFAS) from municipal solid waste (MSW) and other waste streams. This manuscript summarizes state and federal initiatives and critically reviews peer-reviewed literature to define best practices for managing these wastes and identify data gaps to guide future research. The objective is to inform stakeholders about waste-derived PFAS disposed of in landfills, PFAS emissions, and the potential for related environmental impacts. Furthermore, this document highlights data gaps and uncertainties concerning the fate of PFAS during landfill disposal. Most studies on this topic measured PFAS in liquid landfill effluent (leachate); comparatively fewer have attempted to estimate PFAS loading in landfills or other effluent streams such as landfill gas (LFG). In all media, the reported total PFAS heavily depends on waste types and the number of PFAS included in the analytical method. Early studies which only measured a small number of PFAS, predominantly perfluoroalkyl acids (PFAAs), likely report a significant underestimation of total PFAS. Major findings include relationships between PFAS effluent and landfill conditions - biodegradable waste increases PFAS transformation and leaching. Based on the results of multiple studies, it is estimated that 84% of PFAS loading to MSW landfills (7.2 T total) remains in the waste mass, while 5% leaves via LFG and 11% via leachate on an annual basis. The environmental impact of landfill-derived PFAS has been well-documented. Additional research is needed on PFAS in landfilled construction and demolition debris, hazardous, and industrial waste in the US.

A field study to estimate the vertical gas diffusivity and permeability of compacted MSW using a barometric pumping analytical model.

The measurement of vertical gas diffusivity and permeability of compacted municipal solid waste (MSW) using an analytical gas flow and transport model was evaluated. A series of pressure transducers were buried in a MSW landfill and in situ pressures were modelled using an algorithm that predicts soil-gas pressures based on field-measured barometric pressure data and vertical diffusivity. The vertical gas diffusivity that represented the best-fit of the measured pressures was estimated at 20 locations and ranged from 0.002 to 0.052 m2 s(-1). The vertical gas permeability ranged from 3.3 × 10(-14) to 4.5 × 10(-12) m2 for the upper-most 3 to 6 m of compacted MSW. The shortfalls of applying this method to landfill conditions are also discussed.