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1.
Sci Total Environ ; : 173145, 2024 May 18.
Artigo em Inglês | MEDLINE | ID: mdl-38768732

RESUMO

The COVID-19 pandemic has given a chance for researchers and policymakers all over the world to study the impact of lockdowns on air quality in each country. This review aims to investigate the impact of the restriction of activities during the lockdowns in the Asian Monsoon region on the main criteria air pollutants. The various types of lockdowns implemented in each country were based on the severity of the COVID-19 pandemic. The concentrations of major air pollutants, especially particulate matter (PM) and nitrogen dioxide (NO2), reduced significantly in all countries, especially in South Asia (India and Bangladesh), during periods of full lockdown. There were also indications of a significant reduction of sulfur dioxide (SO2) and carbon monoxide (CO). At the same time, there were indications of increasing trends in surface ozone (O3), presumably due to nonlinear chemistry associated with the reduction of oxides of nitrogens (NOX). The reduction in the concentration of air pollutants can also be seen in satellite images. The results of aerosol optical depth (AOD) values followed the PM concentrations in many cities. A significant reduction of NO2 was recorded by satellite images in almost all cities in the Asian Monsoon region. The major reductions in air pollutants were associated with reductions in mobility. Pakistan, India, Bangladesh, Myanmar, Vietnam, and Taiwan had comparatively positive gross domestic product growth indices in comparison to other Asian Monsoon nations during the COVID-19 pandemic. A positive outcome suggests that the economy of these nations, particularly in terms of industrial activity, persisted during the COVID-19 pandemic. Overall, the lockdowns implemented during COVID-19 suggest that air quality in the Asian Monsoon region can be improved by the reduction of emissions, especially those due to mobility as an indicator of traffic in major cities.

2.
Chemosphere ; 356: 141874, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38575079

RESUMO

Organophosphate esters (OPEs) have received considerable attention in environmental research due to their extensive production, wide-ranging applications, prevalent presence, potential for bioaccumulation, and associated ecological and health concerns. Low efficiency of OPE removal results in the effluents of wastewater treatment plants emerging as a significant contributor to OPE contamination. Their notable solubility and mobility give OPEs the potential to be transported to coastal ecosystems via river discharge and atmospheric deposition. Previous research has indicated that OPEs have been widely detected in the atmosphere and water bodies. Atmospheric deposition across air-water exchange is the main input route for OPEs into the environment and ecosystems. The main processes that contribute to air-water exchange is air-water diffusion, dry deposition, wet deposition, and the air-water volatilization process. The present minireview links together the source, occurrence, and exchange of OPEs in water and air, integrates the occurrence and profile data, and summarizes their air-water exchange in the environment.


Assuntos
Monitoramento Ambiental , Ésteres , Organofosfatos , Poluentes Químicos da Água , Ésteres/análise , Organofosfatos/análise , Poluentes Químicos da Água/análise , Poluentes Atmosféricos/análise , Ar/análise , Água/química , Águas Residuárias/química , Atmosfera/química , Ecossistema
3.
Heliyon ; 9(11): e21737, 2023 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-38027659

RESUMO

Phytoremediation is one of the green technologies that is friendly to nature, utilizes fewer chemicals, and exhibits good performance. In this study, phytoremediation was used to treat diesel-contaminated sand using a local aquatic plant species, Scirpus mucronatus, by analyzing the amount of total petroleum hydrocarbons (TPHs). Optimization of diesel removal was performed according to Response Surface Methodology (RSM) using Box-Behnken Design (BBD) under pilot-scale conditions. The quadratic model showed the best fit to describe the obtained data. Actual vs. predicted values from BBD showed a total of 9.1 % error for the concentration of TPH in sand and 0 % error for the concentration of TPH in plants. Maximum TPH removal of 42.3 ± 2.1 % was obtained under optimized conditions at a diesel initial concentration of 50 mg/kg, an aeration rate of 0.48 L/min, and a retention time of 72 days. The addition of two species of rhizobacteria (Bacillus subtilis and Bacillus licheniformis) at optimum conditions increased the TPH removal to 51.9 ± 2.6 %. The obtained model and optimum condition can be adopted to treat diesel-contaminated sand within the same TPH range (50-3000 mg/kg) in sand.

4.
Environ Sci Pollut Res Int ; 30(58): 121306-121337, 2023 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-37993649

RESUMO

This comprehensive paper conducts an in-depth review of personal exposure and air pollutant levels within the microenvironments of Asian city transportation. Our methodology involved a systematic analysis of an extensive body of literature from diverse sources, encompassing a substantial quantity of studies conducted across multiple Asian cities. The investigation scrutinizes exposure to various pollutants, including particulate matters (PM10, PM2.5, and PM1), carbon dioxide (CO2), formaldehyde (CH2O), and total volatile organic compounds (TVOC), during transportation modes such as car travel, bus commuting, walking, and train rides. Notably, our review reveals a predominant focus on PM2.5, followed by PM10, PM1, CO2, and TVOC, with limited attention given to CH2O exposure. Across the spectrum of Asian cities and transportation modes, exposure concentrations exhibited considerable variability, a phenomenon attributed to a multitude of factors. Primary sources of exposure encompass motor vehicle emissions, traffic dynamics, road dust, and open bus doors. Furthermore, our findings illuminate the influence of external environments, particularly in proximity to train stations, on pollutant levels inside trains. Crucial factors affecting exposure encompass ventilation conditions, travel-specific variables, seat locations, vehicle types, and meteorological influences. The culmination of this rigorous review underscores the need for standardized measurements, enhanced ventilation systems, air filtration mechanisms, the adoption of clean energy sources, and comprehensive public education initiatives aimed at reducing pollutant exposure within city transportation microenvironments. Importantly, our study contributes to the growing body of knowledge surrounding this subject, offering valuable insights for policymakers and researchers dedicated to advancing air quality standards and safeguarding public health.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Dióxido de Carbono/análise , Poluentes Atmosféricos/análise , Material Particulado/análise , Poluição do Ar/análise , Emissões de Veículos/análise , Meios de Transporte , Exposição Ambiental/análise , Monitoramento Ambiental/métodos
5.
Sci Total Environ ; 901: 166430, 2023 Nov 25.
Artigo em Inglês | MEDLINE | ID: mdl-37607626

RESUMO

Climate change is thought to influence the composition of atmospheric air, but little is known about the direct relationship between these variables, especially in a hot tropical climate like that of Malaysia. This work summarizes and analyzes the climate state and air quality of Peninsular Malaysia based on selected ground-based observations of the temperature, precipitation, relative humidity, wind speed, wind direction and concentrations of PM10, O3, CO, NO2, and SO2 over the last 20 years (2000-2019). The relationship between the climate state and air quality is analyzed using the Pearson correlation and canonical correlation analysis (CCA) methods is employed to predict the degree of change in the future air quality under different warming scenarios. It is found that the Peninsular Malaysia mainly experienced strong precipitation in the central and mountainous regions, while air pollutants are primarily concentrated in densely populated areas. Throughout the period of study (interannual, monthly, and diurnal time series analyses), Peninsular Malaysia became warmer and drier, with a significant increase in temperature (+4.2 %), decrease in the relative humidity (-4.5 %), and greater fluctuation in precipitation amount. The pollution conditions have worsened; there has been an increase in the PM10 (+16.4 %), O3 (+39.5 %), and NO2 (+2.1 %) concentration over the last 20 years. However, the amount of SO2 (-53.6 %) and CO (-20.6 %) decreased significantly. The analysis of the monthly variation shows a strong bimodality of the PM10 and O3 concentrations that corresponds to the monsoon transition. Intensive diurnal fluctuations and correlations are observed for all the variables in this study. According to the CCA, the air quality factors are strongly correlated with meteorological factors; in particular, the CO, O3, and PM10 concentrations interact strongly with the air temperature. These findings show that the future air quality in Peninsular Malaysia has high possibility to deteriorate under warming condition.

6.
Sci Total Environ ; 902: 166153, 2023 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-37562616

RESUMO

Atmospheric microplastic transport is an important delivery pathway with the deposition of microplastics to ecologically important regions raising environmental concerns. Investigating atmospheric delivery pathways and their deposition rates in different ecosystems is necessary to understanding its global impact. In this study, atmospheric deposition was collected at three sites in Malaysia, two urban and one pristine, covering the Northeast and Southwest monsoons to quantify the role of this pathway in Southeast Asia. Air mass back trajectories showed long-range atmospheric transport of microplastics to all sites with atmospheric deposition varying from 114 to 689 MP/m2/day. For the east coast of Peninsular Malaysia, monsoonal season influenced microplastic transport and deposition rate with peak microplastic deposition during the Northeast monsoon due to higher wind speed. MP morphology combined with size fractionation and plastic type at the coastal sites indicated a role for long-range marine transport of MPs that subsequently provided a local marine source to the atmosphere at the coastal sites.

7.
Arch Environ Contam Toxicol ; 84(3): 347-367, 2023 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-37039904

RESUMO

In the present study, the researchers used an integrated approach composed of response surface analysis (RSM) and MPACT model to predict fatality rates caused by benzene emitted from floating-roof tanks. RSM scenarios were configured in Expert Design (version 7.0) software using the central composite design (CCD) method and five variables of wind speed, relative humidity, atmospheric temperature, failure diameter, and emission height were considered. Continuous Pasquill-Gifford Gaussian model was used to estimate the results of the RSM scenarios. The response values were considered for exposure concentrations above 50 ppm (slight damages), 150 ppm (moderate damage), and 1000 ppm (high damage). The analysis of individual and social risks for each scenario was done using the MPACT model in SAFETI program (version 8.22) by providing two variables of population characteristics and the frequency of tank wall failure. The results showed that atmospheric temperature, wind speed, failure diameter, and emission height have positive effects on the dispersion of the cloud of toxic benzene vapor with a concentration of 1000 ppm. Intolerable individual risk distances were estimated to be lower for indoor environments than for outdoor. Maximum distances of intolerable individual risks for the worst-case scenarios were estimated up to 2500 m from the emission point, which resulted from exposure to a concentration of 1000-ppm benzene. Results regarding the estimation of social risks showed that over 1600 fatalities should be expected under the worst-case scenarios. The three factors of high temperature, low wind speed, and low emission height play a major role in the occurrence of scenarios with the highest fatalities. High wind speed and high emission height were the most important factors in most scenarios with zero fatalities rate. Generally, the findings of this study show the necessity to provide an emergency response plan in the studied industry in both autumn and winter due to low wind speed. However, the coupling of the developed statistical models based on regional meteorological conditions with the MPACT model can help researchers to design an emergency response plan to deal with leakage incidents in petrochemical industries.


Assuntos
Poluentes Atmosféricos , Poluentes Atmosféricos/análise , Monitoramento Ambiental/métodos , Benzeno/análise , Vento , Estações do Ano
8.
Environ Sci Pollut Res Int ; 30(24): 65351-65363, 2023 May.
Artigo em Inglês | MEDLINE | ID: mdl-37081368

RESUMO

Dissolved oxygen is an ecologically critical variable with the prevalence of hypoxia one of the key global anthropogenic issues. A study was carried out to understand the causes of low dissolved oxygen in Brunei Bay, northwest Borneo. Hypoxia was widespread in bottom waters in the monsoonal dry season with dissolved oxygen < 2 mg/L throughout the coastal zone. This was a result of riverine nutrient input primarily from the Padas river driving excess primary production and its subsequent sinking into stratified bottom water where its decomposition consumed oxygen. Despite higher riverine nutrient input in the wet season hypoxia was less extensive due to the combination of turbidity reducing coastal primary production, the intrusion of oxygen-rich water from the South China Sea into offshore bottom layer waters and horizontal flushing increase advection of phytoplankton biomass out of the bay. Future investigation of hypoxia in shallow tropical regions therefore needs to consider the role of monsoonal season.


Assuntos
Baías , Hipóxia , Humanos , Brunei , Oxigênio/análise , Estações do Ano , Água , Monitoramento Ambiental
9.
Sci Total Environ ; 878: 163129, 2023 Jun 20.
Artigo em Inglês | MEDLINE | ID: mdl-37001671

RESUMO

Polycyclic aromatic hydrocarbons (PAHs) in the atmospheric particles constitute a topic of growing health concern. This study aims to calculate PAH concentrations, identify the source, assess the health risk from exposure to carcinogenic PAHs, and the respiratory deposition flux. PM10 and PM2.5 were collected in September 2019 in the urban, semi-urban, and semi-urban-industrial areas of Kuala Lumpur, Batu Pahat, and Bukit Rambai, respectively. A total of 18 PAHs from PM10 and 17 PAHs from PM2.5 were extracted using dichloromethane and determined using gas chromatography coupled with a flame ionization detector (GC-FID). The health risk assessment (HRA) calculated included B[a]P equivalent (B[a]Peq), lifetime lung cancer risk (LLCR), incremental lifetime cancer risk (ILCR), and respiratory deposition dose (RDD). The results show PAHs in PM10 recorded in Kuala Lumpur (DBKL), Batu Pahat (UTHM), and Bukit Rambai are 9.91, 8.45, and 9.57 ng/m3, respectively. The average PAHs in PM2.5 at the three sampling sites are 11.65, 9.68, and 9.37 ng/m3, respectively. The major source of PAHs obtained from the DRs indicates pyrogenic activities for both particle sizes. For PM10, the total B[a]Peq in DBKL, UTHM, and Bukit Rambai were 1.97, 1.82, and 2.32 ng/m3, respectively. For PM2.5 samples, the total B[a]Peq in DBKL, UTHM, and Bukit Rambai were 2.80, 2.33, and 2.57 ng/m3, respectively. The LLCR and ILCR show low to moderate risk for all age groups. The RDD of adults and adolescents is highest in both PM10 and PM2.5, followed by children, toddlers, and infants. Overall, we perceive that adults and adolescents living in the urban area of Kuala Lumpur are at the highest risk for respiratory health problems because of prolonged exposure to PAHs in PM10 and PM2.5, followed by children, toddlers, and infants.


Assuntos
Poluentes Atmosféricos , Neoplasias Pulmonares , Hidrocarbonetos Policíclicos Aromáticos , Adolescente , Adulto , Humanos , Poluentes Atmosféricos/análise , China , Monitoramento Ambiental/métodos , Material Particulado/análise , Hidrocarbonetos Policíclicos Aromáticos/análise , Medição de Risco , Estações do Ano , Lactente , Pré-Escolar , Criança
10.
Sci Total Environ ; 872: 162071, 2023 May 10.
Artigo em Inglês | MEDLINE | ID: mdl-36775179

RESUMO

Biomass burning (BB) has significant impacts on air quality and climate change, especially during harvest seasons. In previous studies, levoglucosan was frequently used for the calculation of BB contribution to PM2.5, however, the degradation of levoglucosan (Lev) could lead to large uncertainties. To quantify the influence of the degradation of Lev on the contribution of BB to PM2.5, PM2.5-bound biomass burning-derived markers were measured in Changzhou from November 2020 to March 2021 using the thermal desorption aerosol gas chromatography-mass spectrometry (TAG-GC/MS) system. Temporal variations of three anhydro-sugar BB tracers (e.g., levoglucosan, mannosan (Man), and galactosan (Gal)) were obtained. During the sampling period, the degradation level of air mass (x) was 0.13, indicating that ~87 % of levoglucosan had degraded before sampling in Changzhou. Without considering the degradation of levoglucosan in the atmosphere, the contribution of BB to OC were 7.8 %, 10.2 %, and 9.3 % in the clean period, BB period, and whole period, respectively, which were 2.4-2.6 times lower than those (20.8 %-25.9 %) considered levoglucosan degradation. This illustrated that the relative contribution of BB to OC could be underestimated (~14.9 %) without considering degradation of levoglucosan. Compared to the traditional method (i.e., only using K+ as BB tracer), organic tracers (Lev, Man, Gal) were put into the Positive Matrix Factorization (PMF) model in this study. With the addition of BB organic tracers and replaced K+ with K+BB (the water-soluble potassium produced by biomass burning), the overall contribution of BB to PM2.5 was enhanced by 3.2 % after accounting for levoglucosan degradation based on the PMF analysis. This study provides useful information to better understand the effect of biomass burning on the air quality in the Yangtze River Delta region.


Assuntos
Poluentes Atmosféricos , Humanos , Poluentes Atmosféricos/análise , Material Particulado/análise , Biomassa , Monitoramento Ambiental/métodos , China , Estações do Ano , Aerossóis/análise
11.
Chemosphere ; 317: 137914, 2023 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-36682637

RESUMO

Heavy metals (HMs) are a vital elements for investigating the pollutant level of sediments and water bodies. The Murray-Darling river basin area located in Australia is experiencing severe damage to increased crop productivity, loss of soil fertility, and pollution levels within the vicinity of the river system. This basin is the most effective primary production area in Australia where agricultural productivity is increased the gross domastic product in the entire mainland. In this study, HMs contaminations are examined for eight study sites selected for the Murray-Darling river basin where the inverse Distance Weighting interpolation method is used to identify the distribution of HMs. To pursue this, four different pollution indices namely the Geo-accumulation index (Igeo), Contamination factor (CF), Pollution load index (PLI), single-factor pollution index (SPLI), and the heavy metal pollution index (HPI) are computed. Following this, the Pearson correlation matrix is used to identify the relationships among the two HM parameters. The results indicate that the conductivity and N (%) are relatively high in respect to using Igeo and PLI indexes for study sites 4, 6, and 7 with 2.93, 3.20, and 1.38, respectively. The average HPI is 216.9071 that also indicates higher level pollution in the Murray-Darling river basin and the highest HPI value is noted in sample site 1 (353.5817). The study also shows that the levels of Co, P, Conductivity, Al, and Mn are mostly affected by HMs and that these indices indicate the maximum HM pollution level in the Murray-Darling river basin. Finally, the results show that the high HM contamination level appears to influence human health and local environmental conditions.


Assuntos
Metais Pesados , Solo , Humanos , Monitoramento Ambiental/métodos , Rios , Metais Pesados/análise , Austrália , Análise Espacial , Medição de Risco , China , Sedimentos Geológicos
12.
PLoS One ; 17(9): e0274433, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-36107927

RESUMO

Smoke haze due to vegetation and peatland fires in Southeast Asia is a serious public health concern. Several approaches have been applied in previous studies; however, the concepts and interpretations of these approaches are poorly understood. In this scoping review, we addressed issues related to the application of epidemiology (EPI), health burden estimation (HBE), and health risk assessment (HRA) approaches, and discussed the interpretation of findings, and current research gaps. Most studies reported an air quality index exceeding the 'unhealthy' level, especially during smoke haze periods. Although smoke haze is a regional issue in Southeast Asia, studies on its related health effects have only been reported from several countries in the region. Each approach revealed increased health effects in a distinct manner: EPI studies reported excess mortality and morbidity during smoke haze compared to non-smoke haze periods; HBE studies estimated approximately 100,000 deaths attributable to smoke haze in the entire Southeast Asia considering all-cause mortality and all age groups, which ranged from 1,064-260,000 for specified mortality cause, age group, study area, and study period; HRA studies quantified potential lifetime cancer and non-cancer risks due to exposure to smoke-related chemicals. Currently, there is a lack of interconnection between these three approaches. The EPI approach requires extensive effort to investigate lifetime health effects, whereas the HRA approach needs to clarify the assumptions in exposure assessments to estimate lifetime health risks. The HBE approach allows the presentation of health impact in different scenarios, however, the risk functions used are derived from EPI studies from other regions. Two recent studies applied a combination of the EPI and HBE approaches to address uncertainty issues due to the selection of risk functions. In conclusion, all approaches revealed potential health risks due to smoke haze. Nonetheless, future studies should consider comparable exposure assessments to allow the integration of the three approaches.


Assuntos
Poluentes Atmosféricos , Incêndios , Poluentes Atmosféricos/análise , Poluentes Atmosféricos/toxicidade , Sudeste Asiático/epidemiologia , Saúde Pública , Medição de Risco
13.
Environ Monit Assess ; 194(9): 629, 2022 Aug 02.
Artigo em Inglês | MEDLINE | ID: mdl-35918614

RESUMO

Bacteria in a hospital environment potentially cause hospital-acquired infections (HAIs), particularly in immunocompromised individuals. Treatments of HAIs with antibiotics, however, are ineffective due to the emergence of antibiotic-resistant bacteria (ARB). This study aims to identify airborne bacteria in a tertiary hospital in Malaysia and screen for their resistance to commonly used broad-spectrum antibiotics. Airborne bacteria were sampled using active sampling at the respiratory ward (RW), physician clinic (PC) and emergency department (ED). Physical parameters of the areas were recorded, following the Industry Code of Practice on Indoor Air Quality 2010 (ICOP IAQ 2010). Bacterial identification was based on morphological and biochemical tests. Antibiotic resistance screening was carried out using the Kirby-Bauer disk diffusion method. Results showed that the highest bacterial population was found in the highest density occupancy area, PC (1024 ± 54 CFU/m3), and exceeded the acceptable limit. Micrococcus spp., Staphylococcus aureus, α- and ß-Streptococcus spp., Bacillus spp. and Clostridium spp. colonies were identified at the sampling locations. The antibiotic resistance screening showed a vast percentage of resistance amongst the bacterial colonies, with resistance to ampicillin observed as the highest percentage (Micrococcus spp.: 95.2%, S. aureus: 100%, Streptococcus spp.: 75%, Bacillus spp.: 100% and Clostridium spp.: 100%). This study provides awareness to healthcare practitioners and the public on the status of the emergence of ARB in a hospital environment. Early detection of bacterial populations and good management of hospital environments are important prevention measures for HAI.


Assuntos
Infecção Hospitalar , Staphylococcus aureus , Antagonistas de Receptores de Angiotensina/farmacologia , Inibidores da Enzima Conversora de Angiotensina/farmacologia , Antibacterianos/farmacologia , Bactérias , Farmacorresistência Bacteriana , Resistência Microbiana a Medicamentos , Monitoramento Ambiental , Hospitais , Humanos
14.
Urban Clim ; 45: 101238, 2022 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-35855931

RESUMO

Volatile organic compounds (VOCs) such as benzene, toluene, ethylbenzene and xylene (BTEX) are air pollutants that harm human health. This study aims to identify BTEX concentrations before the lockdown known as the Movement Control Order was imposed (BMCO), during the implementation of the Movement Control Order (MCO), and then during the Conditional Movement Control Order (CMCO). These orders were introduced during the COVID-19 pandemic in Malaysia. The study utilised data measured by the continuous monitoring of BTEX using online gas chromatography instruments located at three urban area stations. The results showed that the BTEX concentrations reduced by between -38% and -46% during the MCO compared to the BMCO period. The reduction of human mobility during the MCO and CMCO influenced the lower BTEX concentrations recorded at a station within the Kuala Lumpur area. The results of the BTEX diagnostic ratios and principal component analysis showed that the major source of BTEX, especially during the BMCO and CMCO periods, was motor vehicle emissions. Further investigation, using correlation analysis and polar plots, showed that the BTEX concentrations were also influenced by meteorological variables such as wind speed, air temperature and relative humidity.

15.
Environ Monit Assess ; 194(8): 531, 2022 Jun 27.
Artigo em Inglês | MEDLINE | ID: mdl-35760953

RESUMO

Volatile organic compounds (VOCs) form ozone (O3) and secondary organic aerosols (SOAs) in the atmosphere under favourable conditions. Biogenic VOC levels in the marine atmosphere are significantly lower compared with levels in the atmosphere above terrestrial ecosystems. However, much less is known about the marine biogenic VOC sea-to-air flux, specifically at the sea surface level. Therefore, here we describe a newly developed and cost-effective floating chamber system that has the capacity to measure the VOC sea-to-air flux near the sea surface (< 1 m). The floating chamber is coupled with adsorbent cartridges, and samples were analysed in the laboratory using commercial thermal desorption and gas chromatography mass spectrometry (TD-GC-MS). The structural performance of the floating flux chamber was evaluated, and it was shown to have the capacity to stay continuously afloat for up to 72 h in various conditions (e.g., rainy, windy) and with wave heights up to approximately 1 m in coastal waters. Preliminary measurements of isoprene (3-Methyl-1,2-butadiene) (C5H8) sea-to-air flux using the floating flux chamber in the coastal waters off the east coast of Peninsular Malaysia found values in the region of 107 molecules/cm2/s, comparable with most published values based on various flux measurement techniques. We suggest the proposed floating chamber system could serve as a cost-effective VOC flux technique that allows measurements near the sea surface.


Assuntos
Ozônio , Compostos Orgânicos Voláteis , Atmosfera , Ecossistema , Monitoramento Ambiental/métodos , Ozônio/análise , Compostos Orgânicos Voláteis/análise
16.
Sci Rep ; 12(1): 7630, 2022 05 10.
Artigo em Inglês | MEDLINE | ID: mdl-35538095

RESUMO

To understand the characteristics of particulate matter (PM) in the Southeast Asia region, the spatial-temporal concentrations of PM10, PM2.5 and PM1 in Malaysia (Putrajaya, Bukit Fraser and Kota Samarahan) and Thailand (Chiang Mai) were determined using the AS-LUNG V.2 Outdoor sensor. The period of measurement was over a year from 2019 to 2020. The highest concentrations of all sizes of PM in Putrajaya, Bukit Fraser and Kota Samarahan were observed in September 2019 while the highest PM10, PM2.5 and PM1 concentrations in Chiang Mai were observed between March and early April 2020 with 24 h average concentrations during haze days in ranges 83.7-216 µg m-3, 78.3-209 µg m-3 and 57.2-140 µg m-3, respectively. The average PM2.5/PM10 ratio during haze days was 0.93 ± 0.05, which was higher than the average for normal days (0.89 ± 0.13) for all sites, indicating higher PM2.5 concentrations during haze days compared to normal days. An analysis of particle deposition in the human respiratory tract showed a higher total deposition fraction value during haze days than on non-haze days. The result from this study indicated that Malaysia and Thailand are highly affected by biomass burning activity during the dry seasons and the Southwest monsoon.


Assuntos
Poluentes Atmosféricos , Material Particulado , Poluentes Atmosféricos/análise , Sudeste Asiático , Biomassa , Monitoramento Ambiental , Humanos , Tamanho da Partícula , Material Particulado/análise , Estações do Ano
17.
Chemosphere ; 302: 134852, 2022 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-35533940

RESUMO

This study aims to determine the trends of volatile organic compound (VOC) concentrations and their potential contribution to O3 formation. The hourly data (August 2017 to July 2018) for 29 VOCs were obtained from three Malaysian Department of Environment continuous air quality monitoring stations with different urban backgrounds (Shah Alam, Cheras, Seremban). The Ozone Formation Potential (OFP) was calculated based on the individual Maximum Incremental Reactivity (MIR) and VOC concentrations. The results showed that the highest mean total VOC concentrations were recorded at Cheras (148 ± 123 µg m-3), within the Kuala Lumpur urban environment, followed by Shah Alam (124 ± 116 µg m-3) and Seremban (86.4 ± 89.2 µg m-3). VOCs such as n-butane, ethene, ethane and toluene were reported to be the most abundant species at all the selected stations, with overall mean concentrations of 16.6 ± 11.9 µg m-3, 12.1 ± 13.3 µg m-3, 10.8 ± 11.9 µg m-3 and 9.67 ± 9.00 µg m-3, respectively. Alkenes (51.3-59.1%) and aromatic hydrocarbons (26.4-33.5%) have been identified as the major contributors to O3 formation in the study areas based on the overall VOC measurements. Relative humidity was found to influence the concentrations of VOCs more than other meteorological parameters. Overall, this study will contribute to further understanding of the distribution of VOCs and their contribution to O3 formation, particularly in the tropical urban environment.


Assuntos
Poluentes Atmosféricos , Ozônio , Compostos Orgânicos Voláteis , Poluentes Atmosféricos/análise , China , Monitoramento Ambiental/métodos , Ozônio/análise , Tolueno/análise , Compostos Orgânicos Voláteis/análise
18.
Artigo em Inglês | MEDLINE | ID: mdl-35206377

RESUMO

This study aimed to investigate the association between particulate PAHs exposure and DNA damage in Malaysian schoolchildren in heavy traffic (HT) and low traffic (LT) areas. PAH samples at eight schools were collected using a low volume sampler for 24 h and quantified using Gas Chromatography-Mass Spectrometry. Two hundred and twenty-eight buccal cells of children were assessed for DNA damage using Comet Assay. Monte-Carlo simulation was performed to determine incremental lifetime cancer risk (ILCR) and to check the uncertainty and sensitivity of the estimated risk. Total PAH concentrations in the schools in HT area were higher than LT area ranging from 4.4 to 5.76 ng m-3 and 1.36 to 3.79 ng m-3, respectively. The source diagnostic ratio showed that PAHs in the HT area is pyrogenic, mainly from diesel emission. The 95th percentile of the ILCR for children in HT and LT area were 2.80 × 10-7 and 1.43 × 10-7, respectively. The degree of DNA damage was significantly more severe in children in the HT group compared to LT group. This study shows that total indoor PAH exposure was the most significant factor that influenced the DNA damage among children. Further investigation of the relationship between PAH exposure and genomic integrity in children is required to shed additional light on potential health risks.


Assuntos
Poluentes Atmosféricos , Hidrocarbonetos Policíclicos Aromáticos , Poluentes Atmosféricos/análise , Poluentes Atmosféricos/toxicidade , Criança , Dano ao DNA , Monitoramento Ambiental/métodos , Humanos , Malásia/epidemiologia , Mucosa Bucal , Hidrocarbonetos Policíclicos Aromáticos/análise , Hidrocarbonetos Policíclicos Aromáticos/toxicidade , Medição de Risco
19.
Artigo em Inglês | MEDLINE | ID: mdl-35162543

RESUMO

The low-cost and easy-to-use nature of rapidly developed PM2.5 sensors provide an opportunity to bring breakthroughs in PM2.5 research to resource-limited countries in Southeast Asia (SEA). This review provides an evaluation of the currently available literature and identifies research priorities in applying low-cost sensors (LCS) in PM2.5 environmental and health research in SEA. The research priority is an outcome of a series of participatory workshops under the umbrella of the International Global Atmospheric Chemistry Project-Monsoon Asia and Oceania Networking Group (IGAC-MANGO). A literature review and research prioritization are conducted with a transdisciplinary perspective of providing useful scientific evidence in assisting authorities in formulating targeted strategies to reduce severe PM2.5 pollution and health risks in this region. The PM2.5 research gaps that could be filled by LCS application are identified in five categories: source evaluation, especially for the distinctive sources in the SEA countries; hot spot investigation; peak exposure assessment; exposure-health evaluation on acute health impacts; and short-term standards. The affordability of LCS, methodology transferability, international collaboration, and stakeholder engagement are keys to success in such transdisciplinary PM2.5 research. Unique contributions to the international science community and challenges with LCS application in PM2.5 research in SEA are also discussed.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Poluentes Atmosféricos/análise , Poluição do Ar/análise , Poluição do Ar/prevenção & controle , Ásia , Sudeste Asiático , Monitoramento Ambiental/métodos , Material Particulado/análise , Pesquisa
20.
Environ Sci Pollut Res Int ; 29(11): 15380-15390, 2022 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-34988826

RESUMO

Terrestrial anionic surfactants (AS) enter the marine environment through coastal region. Despite that, in general limited knowledge is available on the coastal AS transfer pathway. This paper aims to assess the distributions and exchange of AS in the Peninsular Malaysia coastal environments, adjacent to the southern waters of South China Sea and Strait of Malacca. An assessment case study was conducted by a review on the available data from the workgroup that span between the year 2008 and 2019. The findings showed that AS dominated in the sea surface microlayer (SML, 57%) compared to subsurface water (SSW, 43 %). AS were also found to have dominated in fine mode (FM, 71 %) compared to coarse mode (CM, 29 %) atmospheric aerosols. SML AS correspond to the SSW AS (p < 0.01); however, highest enrichment factor (EF) of the SML AS was not consistent with highest SSW AS. Direct AS exchange between SML and FM and CM was not observed. Furthermore, the paper concludes AS mainly located in the SML and FM and could potentially be the main transfer pathway in the coastal environment.


Assuntos
Tensoativos , Poluentes Químicos da Água , Aerossóis/análise , Monitoramento Ambiental , Malásia , Água do Mar , Tensoativos/análise , Poluentes Químicos da Água/análise
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